Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-30T10:34:32.988Z Has data issue: false hasContentIssue false
  • English
  • Français

Phase separation and transformation of binary immiscible systems in molten core-derived optical fibers

Published online by Cambridge University Press:  31 March 2020

Matthew Tuggle ,
Thomas W. Hawkins ,
Courtney Kucera ,
Nathaniel Huygen ,
Artis Brasovs ,
Konstantin Kornev  and
John Ballato
Matthew Tuggle
Affiliation:
Center for Optical Materials Science and Engineering Technologies (COMSET), Clemson University, 91 Technology Drive, Anderson, SC, 29625, USA Department of Materials Science and Engineering, Clemson University, 295 Sirrine Hall, Clemson, SC29634, USA
Thomas W. Hawkins
Affiliation:
Center for Optical Materials Science and Engineering Technologies (COMSET), Clemson University, 91 Technology Drive, Anderson, SC, 29625, USA Department of Materials Science and Engineering, Clemson University, 295 Sirrine Hall, Clemson, SC29634, USA
Courtney Kucera
Affiliation:
Center for Optical Materials Science and Engineering Technologies (COMSET), Clemson University, 91 Technology Drive, Anderson, SC, 29625, USA Department of Materials Science and Engineering, Clemson University, 295 Sirrine Hall, Clemson, SC29634, USA
Nathaniel Huygen
Affiliation:
Department of Materials Science and Engineering, Clemson University, 295 Sirrine Hall, Clemson, SC29634, USA National Brick Research Center, Clemson University, 91 Technology Drive, Anderson, SC, 29625, USA
Artis Brasovs
Affiliation:
Department of Materials Science and Engineering, Clemson University, 295 Sirrine Hall, Clemson, SC29634, USA
Konstantin Kornev
Affiliation:
Department of Materials Science and Engineering, Clemson University, 295 Sirrine Hall, Clemson, SC29634, USA
John Ballato*
Affiliation:
Center for Optical Materials Science and Engineering Technologies (COMSET), Clemson University, 91 Technology Drive, Anderson, SC, 29625, USA Department of Materials Science and Engineering, Clemson University, 295 Sirrine Hall, Clemson, SC29634, USA
*
Address all correspondence to John Ballato at jballat@clemson.edu
Get access

Abstract

This work studies phase-separated fibers in the CaO–SiO2 and NiO–SiO2 systems. The nature of the phase-separated microstructures and underlying phase equilibria are discussed, including dimensionality, composition, and phase formation as well as the realization of ferrimagnetic behavior in the NiO–SiO2 fibers based on the formation of metallic Ni inclusions. In addition to understanding the composition/processing relationships in these systems, the work represents a step forward toward novel magneto-optic fibers. It is important to understand the underlying materials science in order to advance the properties of novel optical fibers possessing engineered heterogeneities in the core.

Type
Research Letters
Information
MRS Communications , Volume 10 , Issue 2 , June 2020 , pp. 298 - 304
Copyright
Copyright © Materials Research Society 2020

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Peacock, A.C., Gibson, U.J., and Ballato, J.: Silicon optical fibres—past, present, and future. Adv. Phys.-X 1, 114–127 (2016).Google Scholar
2.Faugas, B., Hawkins, T., Kucera, C., Bohnert, K., and Ballato, J.: Molten core fabrication of bismuth germanium oxide Bi4Ge3O12 crystalline core fibers. J. Am. Ceram. Soc. 101, 4340–4349 (2018).CrossRefGoogle Scholar
3.Abouraddy, A.F., Bayindir, M., Benoit, G., Hart, S.D., Kuriki, K., Orf, N., Shapira, O., Sorin, F., Temelkuran, B., and Fink, Y.: Towards multimaterial multifunctional fibres that see, hear, sense and communicate. Nat. Mater. 6, 336–347 (2007).CrossRefGoogle ScholarPubMed
4.Orelma, H., Hokkanen, A., Leppanen, I., Kammiovirta, K., Kapulainen, M., and Harlin, A.: Optical cellulose fiber made from regenerated cellulose and cellulose acetate for water sensor applications. Cellulose 27, 1543–1553 (2019).CrossRefGoogle Scholar
5.Veber, A., Lu, Z., Vermillac, M., Pigeonneau, F., Blanc, W., and Petit, L.: Nano-structured optical fibers made of glass-ceramics, and phase separated and metallic particle-containing glasses. Fibers 7, 1–29 (2019).CrossRefGoogle Scholar
6.Knight, J.C., Birks, T.A., Russell, P.S.J., and Atkin, D.M.: All-silica single-mode optical fiber with photonic crystal cladding. Opt. Lett. 12, 1547–1549 (1996).CrossRefGoogle Scholar
7.Mafi, A., Tuggle, M., Bassett, C., Mobini, E., and Ballato, J.: Advances in the fabrication of disordered transverse Anderson localizing optical fibers. Opt. Mater. Express 9, 2769–2774 (2019).CrossRefGoogle Scholar
8.Birks, T.A., Knight, J.C., and Russell, P. St. J.: Endlessly single-mode photonic crystal fiber. Opt. Lett. 22, 961–963 (1997).CrossRefGoogle ScholarPubMed
9.Karbasi, S., Frazier, R.J., Koch, K.W., Hawkins, T., Ballato, J., and Mafi, A.: Image transport through a disordered optical fibre mediated by transverse Anderson localization. Nat. Commun. 5, 3362 (2014).CrossRefGoogle ScholarPubMed
10.Issatayeva, A., Beisenova, A., Sovetov, S., Korganbayev, S., Jelbuldina, M., Ashikbayeva, Z., Blanc, W., Schena, E., Sales, S., Molardi, C., and Tosi, D.: Multiplexing of distributed temperature sensing achieved by nanoparticle-doped fibers. Proc. SPIE 11190, 111900H, 2019.CrossRefGoogle Scholar
11.Beisenova, A., Issatayeva, A., Iordachita, I., Blanc, W., Molardi, C., and Tosi, D.: Distributed fiber optics 3D shape sensing by means of high scattering NP-doped fibers simultaneous spatial multiplexing. Opt. Express 27, 22074–22087 (2019).CrossRefGoogle ScholarPubMed
12.Cavillon, M., Dragic, P., Greenberg, B., Garofalini, S.H., and Ballato, J.: Observation and practical implications of nano-scale phase separation in aluminosilicate glass optical fibers. J. Am. Ceram. Soc. 102, 879–883 (2019).Google Scholar
13.Ballato, J., Ebendorff-Heidepriem, H., Paul, M., and Petit, L.: Optical fiber materials: feature introduction. Opt. Mater. Express 9, 3565–3566 (2019).CrossRefGoogle Scholar
14.Cavillon, M.: Molten core fabrication of intrinsically low nonlinearity glass optical fibers. Ph.D. Dissertation, Department of Material Science and Engineering, Clemson University, Clemson, SC, 2018.Google Scholar
15.Hammel, J. and Mackenzie, J.; Method of forming microporous glass fibers. U.S. Patent No. 3,650,721, 1972.Google Scholar
16.Kerwawycz, J. and Tomozawa, M.: Light scattering from phase-separated glass. J. Am. Ceram. Soc. 57, 467–470 (1974).CrossRefGoogle Scholar
17.Takamori, T. and Tomozawa, M.: Viscosity and microstructure of phase-separate borosilicate glasses. J. Am. Ceram. Soc. 62, 373–377 (1979).CrossRefGoogle Scholar
18.Tomozawa, M. and Takamori, T.: Effect of phase separation on HF etch rate of borosilicate glasses. J. Am. Ceram. Soc. 60, 301–304 (1977).CrossRefGoogle Scholar
19.Ballato, J. and Peacock, A.C.: Perspective: molten core optical fiber fabrication—a route to new materials and applications. APL Photonics 3, 120903 (2018).CrossRefGoogle Scholar
20.Cavillon, M., Dragic, P., Faugas, B., Hawkins, T.W., and Ballato, J.: Insights and aspects to the modeling of the molten core method for optical fiber fabrication. Materials 12, 2898 (2019).CrossRefGoogle ScholarPubMed
21.Kim, S. and Sanders, T.: Thermodynamic modeling of the miscibility gaps and the metastable liquid in the MgO–SiO2, CaO–SiO2, and SrO–SiO2 systems. J. Am. Ceram. Soc. 82, 1901–1907 (1999).CrossRefGoogle Scholar
22.Seward, T.: Elongation and spheroidization of phase-separated particles in glass. J. Non-Cryst. Solids 15, 487–504 (1974).CrossRefGoogle Scholar
23.Seward, T.: Some unusual optical properties of elongated phases in glass. The Physics of Non-Crystalline Solids: 4th International Conference, 342–347 (1977).Google Scholar
24.Harman, C. and King, B.: Applications of nickel compounds in ceramics. Ind. Eng. Chem. 44, 1015–1017 (1952).CrossRefGoogle Scholar
25.NiO – SiO2: Data from TDnucl – Thermodata nuclear database. Available at: http://www.crct.polymtl.ca/fact/phase_diagram.php?file=NiO-SiO2.jpg&dir=TDnucl.Google Scholar
26.Oliveira, J.E., Correia, R.N., and Fernandes, M.H.V.: Formation of convoluted silica precipitates during amorphous phase separation in the Ca3(PO4)2–SiO2–MgO system. J. Am. Ceram. Soc. 83, 1296–1298 (2000).CrossRefGoogle Scholar
27.Ellingham, H.J.T.: Reducibility of oxides and sulphides in metallurgical processes. J. Soc. Chem. Ind. 63, 125–160 (1944).Google Scholar
28.Kondo, H. and Miyahara, S.: Magnetic properties of several orthosilicates with olivine structures. J. Phys. Soc. Jpn 21, 2193–2196 (1966).CrossRefGoogle Scholar
29.Cullity, B.D. and Graham, C.D.: Introduction to Magnetic Materials. 2nd ed. (John Wiley & Sons, Inc. Hoboken, NJ, 2009).Google Scholar
Supplementary material: File

Tuggle et al. supplementary material

Tuggle et al. supplementary material

Download Tuggle et al. supplementary material(File)
File 257.9 KB