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Self-assembly of nanostructures with multiferroic components using nucleic acid linkers

Published online by Cambridge University Press:  28 December 2016

Ferman A. Chavez  and
Gopalan Srinivasan
Ferman A. Chavez*
Affiliation:
Department of Chemistry, Oakland University, Rochester, MI 48309-4401, USA
Gopalan Srinivasan*
Affiliation:
Department of Physics, Oakland University, Rochester, MI 48309-4401, USA
*
Address all correspondences to either F. A. Chavez at chavez@oakland.edu or G. Srinivasan at srinivas@oakland.edu
Address all correspondences to either F. A. Chavez at chavez@oakland.edu or G. Srinivasan at srinivas@oakland.edu
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Abstract

Self-assembly of multiferroic oxide composites by chemical and biochemical methodology is discussed. The approach involves covalently attaching organic functional groups or oligomeric DNA/RNA to the nanoparticles (NPs). The organic functional groups are only reactive toward functional groups located on different NPs. Using oligomeric DNA/RNA, one could program NPs to only interact with particles possessing complementary DNA/RNA. We have applied both concepts to the assembly of nanostructures with ferrites for the ferromagnetic phase and barium titanate for the ferroelectric phase. The assembled core–shell particles and superstructures obtained in a magnetic field show evidence for strong interactions between the magnetic and ferroelectric subsystems.

Type
Functional Oxides Prospective Articles
Information
MRS Communications , Volume 7 , Issue 1 , March 2017 , pp. 20 - 26
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Copyright
Copyright © Materials Research Society 2016 

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