Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2024-12-26T12:35:48.141Z Has data issue: false hasContentIssue false

3D Small Angle X-Ray Scattering (SAXS) on deformed PVDF Foils

Published online by Cambridge University Press:  01 February 2011

Guenther Maier
Affiliation:
Materials Center Leoben & Erich Schmid Institute of Material Science, Jahnstrasse 12, 8700 Leoben, Austria
Gernot Wallner
Affiliation:
Institute of Materials Science and Testing of Plastics, University of Leoben, Franz-Josef-Str. 18, and Polymer Competence Center Leoben GmbH, Parkstr. 11, 8700 Leoben, Austria
Peter Fratzl
Affiliation:
Materials Center Leoben & Erich Schmid Institute of Material Science, Jahnstrasse 12, 8700 Leoben, Austria Max-Planck-Institute of Colloids and Interfaces, Department of Biomaterials, 14424 Potsdam, Germany
Get access

Abstract

3D Small Angle X-ray scattering (3D – SAXS) was applied to study the microstructure and the deformation mechanism in PVDF – foils (polyvinyhdene fluoride). SAXS is a powerful tool to investigate structural changes in deformed polymers to reveal morphology at the nanometer scale. When PVDF is strained the structure changes from spherohtic isotropie to a highly anisotropie fiber bundle structure, which requires a full three-dimensional analysis of the SAXS signal.

Type
Research Article
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Kepler, R.G., Anderson, R.A., Advances in Physics, Vol. 41, 1, 157 (1992)Google Scholar
[2] Lovinger, A.J., Developments in Crystalline Polymers 1, edited by Basse”, D.C., (London: Applied Science, 1982), p. 195 ffGoogle Scholar
[3] Sajkiewicz, P., Wasiak, A., Goclowski, Z., Europ. Polymer J. 35, 423429, (1999)Google Scholar
[4] Castagnet, S., Girault, S., Gacougnolle, J.L., Dang, P., Polymer 41, 75237530 (2000)Google Scholar
[5] Castagnet, S., Gacougnolle, J.L., Dang, P., Mat. SCI a. Eng A276, 152159 (2000)Google Scholar
[6] Andre-Castagnet, S., Tence-Girault, S., J.oM.Sci –B Physics, Vol. B41, Nos. 4–6, 927976 (2002)Google Scholar
[7] Glatter, O., Krátky, O., editors: Small Angle X-ray Scattering, Academic Press, London. (1982)Google Scholar
[8] Fratzl, P., J. Appi Cryst. 36, 397404 (2003)Google Scholar
[9] Brumberger, H., editor: Modern Aspects of Small-Angle Scattering, NATO ASI Series C 451, (Kluwer Academic, 1995)Google Scholar
[10] Fratzl, P., Langmayr, F., Pans, O., J. Appl. Cryst. 26, 820 – 826 (1993)Google Scholar
[11] Stróbl, G.R, Schneider, M., J. Polym. Sci. Polym. Phys. Ed. Vol.18, 1343 – 1359 (1980)Google Scholar
[12] Stróbl, G.R., Schneider, M. J., Voigt-Martin, I. G., J. Polym. Sci Polym. Phys. Ed. Vol.18, 13611381 (1980)Google Scholar
[13] Fratzl, P., Jakob, H., Rinnerthaler, S., Roschger, P., Klaushofer, K., JApplCryst. 30, 765769 (1997)Google Scholar
[14] Butler, M., Donald, A., Bras, W., Mant, G., Derbyshire, G., Ryan, A., Macromolecules, 18, 19, 63836393(1995)Google Scholar
[15] Pope, D., Keller, A., J. Polym. Sci. Polym. Phys. Ed, Vol.13, 533 – 540 (1975)Google Scholar