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Characterisation of Colloids and Gels

Published online by Cambridge University Press:  25 February 2011

John D.F. Ramsay*
Affiliation:
Chemistry Division, Harwell Laboratory, Oxfordshire OX11 ORA, UK
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Abstract

Sol-gel processes can provide a route to oxide ceramics with controlled microstructure and homogeneity. This feature can be exploited from an understanding of the inter-relationship between the characteristics of concentrated sols and the microstructure of the resultant gels produced on dehydration. Among several characterisation techniques employed (light scattering, incoherent neutron scattering, viscoelastic behaviour) neutron small angle scattering (SANS) has proved particularly powerful in the study of the mechanism of the sol to gel conversion process. Applications of SANS in the characterisation of sols containing (a) discrete particles (charge stabilised), (b) mixed oxide systems, and (c) particle aggregates, with fractal properties are illustrated.

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

See e.g. Better Ceramics through Chemistry II, edited Brinker, C.J., Clarke, D.E. and Ulrich, D.R. (Mater. Res. Soc. Proc. 73, Palo Alto, 1986).Google Scholar
2. See e.g. J. Non-Cryst. Solids, 82, Nos. 1–3 (1986).Google Scholar
3. Ramsay, J.D.F., Chem. Soc. Rev., 15, 335 (1986).CrossRefGoogle Scholar
4. Dickinson, E., in Colloid Science, Vol. 4, edited by Everett, D.H. (The Royal Society of Chemistry, London, 1983) p. 150.Google Scholar
5. See e.g. Faraday Discuss. Chem. Soc, ‘Concentrated Colloidal Dispersions’, 76 (1983).Google Scholar
6. See e.g. Faraday Discuss. Chem. Soc, ‘Brownian Motion’, 83 (1987).Google Scholar
7. Avery, R.G. and Ramsay, J.D.F., in Adsorption and Catalysis on Oxide Surfaces, Vol. 21, edited by Che, M. and Bond, G.C. (Elsevier, Amsterdam, 1985) p. 149.Google Scholar
8. Ramsay, J.D.F. and Avery, R.G., in Novel Ceramic Fabrication Processes and Applications, edited by Davidge, R.W. (Institute of Ceramics, Staffs, 1986), No. 38, p. 275.Google Scholar
9. Ramsay, J.D.F. and Scanlon, M., Colloids and Surfaces, 18, 207 (1986).CrossRefGoogle Scholar
10. See e.g. Colloidal Dispersions, edited by Goodwin, J.W. (Special Publication No. 43, Royal Society of Chemistry, London, 1982).Google Scholar
11. Lovesey, S.W., in Theory of Neutron Scattering from Condensed Matter, Vols. 1 and 2 (Clarendon Press, Oxford, 1984).Google Scholar
12. Conard, J., Szwarkopf, H.H., Poinsignon, C. and Dianoux, A.J., J. Phys. (Paris), 45, 169 (1984).Google Scholar
13. Ramsay, J.D.F. and Poinsignon, C., Langmuir, 3, 321 (1987).CrossRefGoogle Scholar
14. Ramsay, J.D.F., in Water and Aqueous Solutions, edited by Neilson, G.W. and Enderby, J.E. (Adam Hilger, Bristol, 1986), p.207.Google Scholar
15. Guinier, A. and Fournet, G., in Small Angle Scattering of X-rays, (Wiley, New York, 1955).Google Scholar
16. Ramsay, J.D.F. and Booth, B.O., J. Chem. Soc, Faraday Trans. 1, 79, 173 (1983).Google Scholar
17. Penfold, J. and Ramsay, J.D.F., J. Chem. Soc, Faraday Trans. 1, 81, 117 (1985).Google Scholar
18. Hayter, J.B., Faraday Discuss. Chem. Soc, 76, 7 (1983).CrossRefGoogle Scholar
19. Ramsay, J.D.F., Avery, R.G. and Benest, L., Faraday Discuss. Chem. Soc, 76, 53 (1983).CrossRefGoogle Scholar
20. Weitz, D.A., Huang, J.S., Lim, M.Y. and Sung, J., Phys. Rev. Lett., 53, 1657 (1984).CrossRefGoogle Scholar
21. Schaefer, D.W., Martin, J.E., Wiltzius, P. and Cannell, D.S., Phys. Rev. Lett., 52, 2371 (1984).CrossRefGoogle Scholar
22. Weitz, D.A. and Huang, J.S., in Kinetics of Aggregation and Gelation, edited by Family, F. and Landau, D. (North Holland, Amsterdam, 1984) p. 19.CrossRefGoogle Scholar
23. See e.g. On Growth and Form, Fractals and Non-Fractal Patterns in Physics, edited by Stanley, H.E. and Ostrowsky, N. (Martinus Nijhoff Publishers, Dordrecht, 1986).Google Scholar
24. Meakin, P., Phys. Rev. A, 27, 1495 (1983).CrossRefGoogle Scholar
25. Kolb, M., Botet, R. and Julien, R., Phys. Rev. Lett., 51, 1123 (1983).CrossRefGoogle Scholar
26. Kratky, O. and Porod, G., J. Colloid Soc, 4, 35 (1949).CrossRefGoogle Scholar
27. Bale, H.D. and Schmidt, P.W., Phys. Rev. Lett., 53, 596 (1983).CrossRefGoogle Scholar
28. Ramsay, J.D.F., Daish, S.R. and Wright, C.J., Faraday Discuss. Chem. Soc, 65, 65 (1978).CrossRefGoogle Scholar
29. Webman, I., in Physics of Finely Divided Matter, edited by Boceara, N. and Daoud, M. (Springer-Vertag, Heidelberg, 1985).Google Scholar