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Comparison of Impact of Virgin Polymer Structure on Properties of Irradiated Membranes – Hydrogen Ion Irradiation on Polyimide Isomers

Published online by Cambridge University Press:  11 February 2011

Xinglong Xu ,
Ling Hu  and
J. Ilconich
Xinglong Xu
Affiliation:
Maria Coleman, Univ. of Toledo, Dept. of Chemical & Environmental Engineering, Toledo, Ohio.
Ling Hu
Affiliation:
Maria Coleman, Univ. of Toledo, Dept. of Chemical & Environmental Engineering, Toledo, Ohio.
J. Ilconich
Affiliation:
Maria Coleman, Univ. of Toledo, Dept. of Chemical & Environmental Engineering, Toledo, Ohio.
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This study focused on the impact of virgin polymer structure and microstructure on the transport properties of irradiated polyimide. Two fluorine containing polyimide isomers (6FDA-6FpDA and 6FDA-6FmDA) that differ solely in the location of the linkage between the diamine and dianhydride residues were used for this study. While these polymers differ in the location of a single bond, the virgin transport properties are dramatically different. The para connected isomer (6FDA-6FpDA) has much higher permeabilities and lower selectivities than the meta connect isomer (6FDA-6FmDA). The pure gas permeabilities in polyimide-ceramic composite membranes following H+ ion irradiation over a wide range of doses will be compared for these polyimide isomers. In addition, the evolution in chemical structure was monitored using Fourier transform infrared spectroscopy (FTIR). These polymers exhibited different decay rate in chemical structure following ion irradiation. Interestingly, the evolution in gas transport properties of these polymers following H+ ion irradiation was also quite different. We will discuss how the microstructure would affect the gas permeation properties of ion beam modification of polymer.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 752: Symposium AA – Membranes–Preparation, Properties and Applications , 2002 , AA3.4
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCE

1. Davenas, J., Xu, X. L., Nucl. Instr. and Methods B71 33–38 (1992)Google Scholar
2. Xu, X. L., Dolveck, J.Y., Boiteux, G., Escoubes, M., Monchanin, M., Dupin, J.P., Davenas, J., J. of Appl. Polym. Sci., 55 99–107 (1995)Google Scholar
3. Xu, X. L., Dolveck, J. Y., Boiteux, G., Escoubes, M., Monchanin, M., Dupin, J. P. and Davenas, J., in Beam-Solid Interactions for Materials Synthesis and Processing, ed. Jacobson, Dale C., Luzzi, David E., Heinz, Tony F., and Iwaki, Masaya (Mater. Res. Soc. Proc. 354, Pittsburgh, PA, 1995) pp351–356 Google Scholar
4. Xu, X. L., Coleman, M. R., Myler, U., and Simpson, P. J., in “Post-Synthesis Method for Development of Membranes Using Ion Beam Irradiation of Polyimide Thin Films,” Membrane Formation and Modification, ed. Pinnau, I. and Freeman, B. D., (American Chemical Society Symposium Series 744, Washington, DC, 2000) pp 205∼227.Google Scholar
5. Xinglong, Xu, Coleman, M. R., in Microstructural Processes in Irradiated Materials, ed. Zinkle, S.J., Lucas, G., Ewing, R., Williams, J., (Mater. Res. Soc. Proc. 540, Pittsburgh, PA, 1999) pp255–260.Google Scholar
6. Xinglong, Xu, Coleman, M. R., Nucl‥ Instr. & Methods B 152 325–334 (1999)Google Scholar
7. Ilconich, J. B., Xinglong, Xu, and Coleman, Maria, J. Membrane Sci. in Press.Google Scholar
8. Coleman, M. R. and Koros, W. J., J. Membrane Sci. 50 285 (1990).Google Scholar
9. Coleman, M. R. and Koros, W. J., J. Polym Sci. B. 32 1915 (1994).Google Scholar
10. J Koros, W., and Chern, R.T., “Separation of gaseous mixtures using polymer membranes,” Handbook of Separation Process Technology, ed. Rousseau, R.W. (John Wiley and Sons, 1987).Google Scholar
11. Husk, G. R., Cassidy, P. E. and Gebert, K. L., Macromolecules 21 1234 (1988).Google Scholar