Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-25T19:28:16.495Z Has data issue: false hasContentIssue false
  • English
  • Français

Corrosion Product Identification and Relative Rates of Corrosion of Candidate Metals in an Irradiated Air-Steam Environment

Published online by Cambridge University Press:  21 February 2011

Donald T. Reed ,
V. Swayambunathan ,
B. S. Tani  and
Richard A. Van Konynenburg
Donald T. Reed
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Il 60439
V. Swayambunathan
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Il 60439
B. S. Tani
Affiliation:
Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Il 60439
Richard A. Van Konynenburg
Affiliation:
Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, CA 94550
Get access

Abstract

Previously reported work by others indicates that dicopper trihydroxide nitrate, Cu2NO3(OH)3, forms on copper and copper alloys subjected to irradiated moist air near room temperature. We have performed experiments over a range of temperature and humidity, and have found that this species is formed at temperatures up to at least 150° C if low to intermediate relative humidities are present. At 150°C and 100% relative humidity, only Cu2O and CuO were observed. The relative general corrosion rates of the copper materials tested in 1-month experiments at dose rates of 0.7 and 2.0 kGy/h were Cu > 70/30 Cu-Ni > Al-bronze. High-nickel alloy 825 showed no observable corrosion.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 176: Symposium U – Scientific Basis for Nuclear Waste Management XIII , 1989 , 517
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Konynenburg, R.A. Van, “Radiation Doses in Granite Around Emplacement Holes in the Spent Fuel Test - Climax (Final Report),” Lawrence Livermore National Laboratory Report UCRL-53580, Livermore, CA, July 26, 1984.Google Scholar
2. Primak, W. and Fuchs, L.H., Physics Today 2., 15 (1954).Google Scholar
3. Shatalov, I.V. and Nikitina, V.A., Proceedings of the Second International Conference on Peaceful Uses of Atomic Energy, (United Nations, Geneva, 1958), Vol. 6, p.284.Google Scholar
4. Byalobzheskii, A.V., Radiation Corrosion, Izdatel' stvo “Nauka,” Moskva (1967) (translated by Israel Program for Scientific Translations, Jerusalem, 1970).Google Scholar
5. Hakepeace, C.E., Journal of Testing and Evaluation Z, 202 (1974).Google Scholar
6. Yunker, W.H., “Corrosion of Copper-Based Materials in Gamma Radiation,” Hanford Engineering Development Laboratory Report HEDL-7612, Richland, WA, 1986.Google Scholar
7. Yunker, W.H. and Glass, R.S., “Long-Term Corrosion Behavior of Copper-Base Materials in a Gamma-Irradiated Environment,” in Scientific Basis for Nuclear Waste Management X, edited by Bates, J. K. and Seefeldt, W. B. (Mater. Res. Soc. Proc. 84., Pittsburgh, PA 1987) pp.579–590.Google Scholar
8. Yunker, W.H., “Corrosion Behavior of Copper-Base Materials in a Gamma-Irradiated Environment - Final Report,”Westinghouse Hanford Co. Report WHC-EP-0188, Richland, WA, 1988.Google Scholar
9. Reed, D.T., Swayambunathan, V., Tani, B.S., and Konynenburg, R.A. Van, Lawrence Livermore National Laboratory Report UCRL-102597, Livermore, CA, November, 1989.Google Scholar