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Defects and Strain in GexSi1−x Layers Grown by Rapid Thermal Processing Chemical Vapor Deposition
Published online by Cambridge University Press: 25 February 2011
Abstract
We have grown single and multi-layer epitaxial GexSi1−x/Si structures by RTPCVD on (100)Si substrates using GeH4 and SiH2Cl2 at 900°C and 1000°C with SiH2Cl2:GeHH4 ratios of 14:1 to 95:1 at 5 Torr. Plane view TEM micrographs indicate misfit dislocation free layers were grown for Ge concentrations of up to 13%. Misfit dislocation networks aligned along <110> were formed at the interface of films with higher Ge concentrations. Plane view TEM micrographs also showed dislocation loops at the interface. When the SiH2C12:GeH4 ratio used was less than 25:1, the GexSil−x layer grew by three-dimensional nucleation, resulting in a high density of defects.
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