Hostname: page-component-78c5997874-m6dg7 Total loading time: 0 Render date: 2024-11-16T18:23:28.766Z Has data issue: false hasContentIssue false
  • English
  • Français

Design of semi-interpenetrating networks based on poly(ethyl-2-cyanoacrylate) and oligo(ethylene glycol) diglycidyl ether

Published online by Cambridge University Press:  08 February 2012

Guiseppe Tripodo ,
C. Wischke  and
A. Lendlein
Guiseppe Tripodo
Affiliation:
Center for Biomaterial Development and Berlin-Brandenburg Center for Regenerative Therapies, Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Kantstrasse 55, 14513 Teltow, Germany.
C. Wischke
Affiliation:
Center for Biomaterial Development and Berlin-Brandenburg Center for Regenerative Therapies, Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Kantstrasse 55, 14513 Teltow, Germany.
A. Lendlein
Affiliation:
Center for Biomaterial Development and Berlin-Brandenburg Center for Regenerative Therapies, Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Kantstrasse 55, 14513 Teltow, Germany.
Get access

Abstract

The synthesis of semi-interpenetrating networks (SIPN) based on linear poly(ethyl 2-cyanoacrylate) (PECA) and oligo(ethylene glycol) diglycidyl ether (OEGDG) based polymer networks was motivated by the hypothesis that the brittleness of polycyanoacrylates may be overcome by incorporating them into a polymer network architecture. A sequential synthetic route was applied, in which first PECA was prepared by anionic polymerization. Subsequently, OEGDG was crosslinked with different anhydrides and curing catalysts to form networks with hydrolyzable ester bonds and interpenetrating PECA. These SIPNs showed a low water uptake compared to other polyether based networks. Some of the obtained materials were transparent and exhibited a great flexibility, which was maintained also after 24 h of immersion in water and subsequent drying. Such networks could be components of future stimuli-sensitive material systems.

Keywords

biomaterialpolymerfilm
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1403: Symposium V – Multifunctional Polymer-Based Materials , 2012 , mrsf11-1403-v12-23
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Melody, D.P., British Polymer Journal, 21, 175 (1989).Google Scholar
2. Tripodo, G., Wischke, C., and Lendlein, A., Macromolecular Symposia, 309/310, 49 (2011).Google Scholar
3. Wischke, C., Weigel, J., Neffe, A.T., and Lendlein, A., International Journal of Artificial Organs, 34, 243 (2011).Google Scholar
4. Neffe, A.T., Tronci, G., Alteheld, A., and Lendlein, A., Macromolecular Chemistry and Physics, 211, 182 (2010).Google Scholar
5. Tripodo, G., Pitarresi, G., Cavallaro, G., Palumbo, F.S., and Giammona, G., Macromolecular Bioscience, 9, 393 (2009).Google Scholar
6. Hofmann, D., Entrialgo-Castano, M., Kratz, K., and Lendlein, A., Advanced Materials, 21, 3237 (2009).Google Scholar
7. Zhu, J.M., Biomaterials, 31, 4639 (2010).Google Scholar
8. Aleman, J., Chadwick, A.V., He, J., Hess, M., Horie, K., Jones, R.G., Kratochvil, P., Meisel, I., Mita, I., Moad, G., Penczek, S., and Stepto, R.F.T., Pure and Applied Chemistry, 79, 1801 (2007).Google Scholar
9. Woo, E.M. and Seferis, J.C., Journal of Applied Polymer Science, 40, 1237 (1990).Google Scholar
10. Schut, J., Bolikal, D., Khan, I.J., Pesnell, A., Rege, A., Rojas, R., Sheihet, L., Murthy, N.S., and Kohn, J., Polymer, 48, 6115 (2007).Google Scholar
11. Chiellini, E., Solaro, R., Bemporad, L., Dantone, S., Giannasi, D., and Leonardi, G., Journal of Biomaterials Science-Polymer Edition, 7, 307 (1995).Google Scholar
12. Tognana, S., Salgueiro, W., and Somoza, A., Physica Status Solidi C - Current Topics in Solid State Physics, Vol 6, No 11, 6, 2423 (2009).Google Scholar
13. Yu, Y.F., Zhong, X.H., Su, H.H., and Serra, A., Polymer, 51, 1563 (2010).Google Scholar
14. Lukaszczyk, J. and Jaszcz, K., Reactive & Functional Polymers, 43, 25 (2000).Google Scholar
15. Garcia, F.G., Leyva, M.E., de Queiroz, A.A.A., and Higa, O.Z., Journal of Applied Polymer Science, 112, 1215 (2009).Google Scholar
16. Sperling, L.H., Journal of Polymer Science: Macromolecular Reviews, 12, 141 (1977).Google Scholar
17. Sperling, L.H. and Mishra, V., Polymers for Advanced Technologies, 7, 197 (1996).Google Scholar
18. Cai, L. and Wang, S.F., Biomacromolecules, 11, 304 (2010).Google Scholar