Published online by Cambridge University Press: 25 February 2011
A donor-like spectrum in Fe-doped silicon has been studied by means of high-resolution Zeeman spectroscopy. Previous work had unambigouosly identified the center as the interstitial iron impurity and the spectrum was interpreted as due to the transitions , where an electron is excited to shallow effective-masslike donor states. In this paper, we can, by studying the transitions in a magnetic field, verify the effective-mass-like character of the loosely bound electron. Furthermore, we also obtain information on the impurity core whose level structure is reflected in the observed superposition of donor-hke Rydeberg series and whose g values determines the Zeeman splitting pattern.