Hostname: page-component-745bb68f8f-hvd4g Total loading time: 0 Render date: 2025-01-12T07:54:34.850Z Has data issue: false hasContentIssue false
  • English
  • Français

Glass Structure and Glass Durability

Published online by Cambridge University Press:  21 February 2011

William B. White
William B. White*
Affiliation:
Materials Research Laboratory, The Pennsylvania State University, University Park, PA 16802
Get access

Abstract

The vibrational spectra of silicate glasses provide some clues on the structure and stability of the glass-forming network. Wavenumbers of Raman bands are related to the types of linkages within the network and Raman intensities to the “speciation” within the network. Absolute infrared intensities which can be obtained from deconvolution of specular reflectance spectra can be used to obtain dipole derivatives which in turn can be correlated with effective charges on bridging and non-bridging oxygens. IR and Raman spectra measured on a variety of silicate glasses are used to extract network polymerization and bond effective charges which in turn are related to the durability of the glasses.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 125: Symposium N – Materials Stability and Environmental Degradation , 1988 , 109
Copyright
Copyright © Materials Research Society 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Plodinec, M.J., Jantzen, C.M., and Wicks, G.G., Mat. Res. Soc. Symp. Proc. 26, 755 (1984).Google Scholar
2. Jantzen, C.M. and Plodinec, M.J., J. Non-Cryst. Solids 67, 207 (1984).CrossRefGoogle Scholar
3. White, W.B., Advances in Ceramics 20, 431 (1986).Google Scholar
4. Brawer, S.A. and White, W.B., J. Chem. Phys. 63, 2421 (1975).Google Scholar
5. Virgo, D., Mysen, B.O., and Kushiro, I., Science 208, 1371 (1980).Google Scholar
6. Furukawa, T., Fox, K.E., and White, W.B., J. Chem. Phys. 75, 3226 (1981).Google Scholar
7. Mysen, B.O., Virgo, D., and Seifert, F.A., Rev. Geophys. Space Phys. 20, 353 (1982).CrossRefGoogle Scholar