Hostname: page-component-586b7cd67f-vdxz6 Total loading time: 0 Render date: 2024-11-24T22:45:52.384Z Has data issue: false hasContentIssue false
  • English
  • Français

Growth and Studies of Li (Mn, Co) Oxides for Battery Electrodes

Published online by Cambridge University Press:  10 February 2011

S. Nieto-Ramos ,
M.S. Tomar  and
R.S. Katiyar
S. Nieto-Ramos
Affiliation:
Physics Department, University of Puerto Rico, Mayaguez, PR 00681-9016
M.S. Tomar
Affiliation:
Physics Department, University of Puerto Rico, Mayaguez, PR 00681-9016, e.mail: m_tomar@feynman.upr.clu.edu
R.S. Katiyar
Affiliation:
Physics Department, University of Puerto Rico, San Juan, PR 00931
Get access

Abstract

There is interest in lithium intercalation oxide materials for cathodes in rechargeable batteries. We have synthesized LiMOx, (where M = Mn, Co) by a less expensive solution route. Reagent grade acetates or hydroxides as precursors for lithium, manganese, and cobalt, respectively, with methoxy ethenol and acetic acid as solvents were used. Powders with different compositions were achieved at annealing temperature below 700 °C. Thin films were deposited by spin coating. X-ray diffraction, Raman spectroscopy, and impedance spectroscopic results are presented. These studies indicate that this synthetic route is suitable to produce good quality lithium-based oxides useful for cathode in lithium-ion rechargeable battery.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 606: Symposium NN – Chemical Processing of Dielectrics, Insulators & Electronic Ceramics , 1999 , 223
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Pereira-Ramos, J.P., Baffier, N., and Pistoia, G., in, Lithium Batteries, Pistoria, G., (Editor), Elsevier, New York, (1994), p. 281 Google Scholar
2 Ceder, G., Aydinol, M.K., and Kohan, A.E., Comput. Mater. Sci., 8, 161 (1996)Google Scholar
3 Gummow, R.J., Kock, A. De, and Thackeray, M.M., Solid State Ionics, 69, 59 (1994)Google Scholar
4 Livage, J., Henry, M., and Sanchez, C., Prog. Solid-State Chem. 18, 259 (1988)Google Scholar
5 Barboux, P., Tarascon, J.M, and Shokoohi, F., J. Solid-State Chem. 94, 209 (1991)Google Scholar
6 Kasbani, A., Tomar, M.S. and Dayalan, E., J. Mater. Res. 10, 2404 (1995)Google Scholar
7 West, K., Z-Christiansen, B., Jacobsen, T., and Skaarup, S., Electrochimica Acta, 38, 1213 (1993)Google Scholar
8 Chiang, Y-M, Jang, Y-I., Wong, H., Huang, B., Sadoway, D. R., and Ye, P., J. Electrochem. Soc. 145, 887 (1998)Google Scholar
9 Macdonald, J. Ross, Impedance Spectroscopy, Wiley, (1987)Google Scholar
10 Ohzuku, T., Ueda, A., Nagayama, M., Iwakoshi, Y., and Komori, H., Electrochimica Acta, 38, 1159 (1993)Google Scholar