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Hybrid Organic-Inorganic Electrode-Membranes Based on Organo-Polysiloxane/Macrocycle Systems

Published online by Cambridge University Press:  10 February 2011

A. Jiménez-Morales ,
J.C. Galvan ,
P. Aránda  and
E. Ruiz-Hitzky
A. Jiménez-Morales
Affiliation:
Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, E-28049 Madrid, Spain, jcarlos@icmm.csic.es Universidad Carlos III de Madrid, E-289 11 Legands, Spain
J.C. Galvan
Affiliation:
Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, E-28049 Madrid, Spain, jcarlos@icmm.csic.es
P. Aránda
Affiliation:
Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, E-28049 Madrid, Spain, jcarlos@icmm.csic.es
E. Ruiz-Hitzky
Affiliation:
Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, E-28049 Madrid, Spain, jcarlos@icmm.csic.es
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Abstract

Specific complexing agents for alkaline ions such as some crown-ethers of different intramolecular cavity size (12-crown-4, 15-crown-5 and 18-crown-6) are incorporated into a organo-polyorganosiloxane network generated via the sol-gel process. The resulting xerogels embody macrocycle compounds with different ion-selectivity. These xerogels are deposited onto porous supports (borosilicate, polyacrylonitrile,…) to obtain new composite electrode- membranes. The electrochemical characterization of the membranes and the electrode- membranes by electrochemical impedance spectroscopy (EIS) shows information about the reversible behavior and the ion resistance of the membranes, which are a function of both, nature and content of the entrapped macrocycle as well as the salt solution concentration. The electrochemical response of these systems acting as electrode-membranes shows their sensitivity towards different metal ions at variable concentrations.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 211
Copyright
Copyright © Materials Research Society 1998

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