Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-28T10:18:08.376Z Has data issue: false hasContentIssue false

Hydrogen - Transporting Mixed Conductors

Published online by Cambridge University Press:  21 February 2011

Martha Schreiber
Affiliation:
Department of Materials Science & Engineering, Stanford University, Stanford, CA 94305
Robert A. Huggins
Affiliation:
Department of Materials Science & Engineering, Stanford University, Stanford, CA 94305
Get access

Abstract

Hydrogen has been found to exhibit high mobility in several classes of solids, which also have appreciable electronic conduction.

The structure and properties of such mixed -conductor materials will be dicussed. In addition, several types of applications, based upon their special properties, will be described.

Type
Research Article
Copyright
Copyright © Materials Research Society 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1) Faraday, M., in Experimental Researches in Electricity, Taylor and Francis, London (1839); see M.S. Whittingham, “Rapid Ionic Mobility in Solids; One Thread in the History of Solid State Electrochemistry”, in Proceedings of the Symposium on Selected Topics in the History of E c, ed. by G. Dubpernell and J.H. Westbrook, Electrochemical Society (1978), p. 329Google Scholar
2) Wagner, C., Z. phys. Chemie B21 42 (1933); Z. phys. Chemie B21, 469 (1934)Google Scholar
3) Chu, W.F., Rickert, H., and Weppner, W., in Fast Ion Transport in Solids, ed. by Gool, W. van, North -Holland (1973), p. 181 Google Scholar
4) Cartanjen, H.D., Phys. Status Solidi A 59 11 (1980)CrossRefGoogle Scholar
5) Puska, M.J. and Nieminen, R., Surf. Sci. 157 413 (1985)Google Scholar
6) Voelkl, J. and Alefeld, G. in “Diffusion in Solids. Recent Developments”. ed. by Novick, A.S. and Burton, J.J., Academic Press, New York (1975) p.231 Google Scholar
7) Norskov, J.K. and Besenbacher, F., J. Less-Common Met. 130. 475 (1987)Google Scholar
8) Huggins, R.A., “Ionically Conducting Solid-State Membranes”, in Advances in Electrochemistry and Electrochemical Engineering, Vol 10, ed. by Gerischer, H. and Tobias, C.W., John Wiley & Sons (1977), p. 323 Google Scholar
9) Weppner, W. and Huggins, R.A., “Electrochemical Methods for Determining Kinetic Properties of Solids”, in Annual Review of Materials Science, Vol. 8, ed. by Huggins, R.A., Annual Reviews (1978), p. 269 Google Scholar
10) Bloch, J., Swissa, E. and Mintz, M.H., “Effect of Vacuum Annealing on the Hydriding Kinetics of Uranium”, to be published in the Proceedings of the International Symposium on Metal - Hydrogen Systems, Stuttgart, W. Germany (1988)Google Scholar
11) Boes, N. and Zuechner, H., Z. Naturforsch. 31a. 754 (1976)CrossRefGoogle Scholar
12) Boes, N. and Zuechner, H., J. Less-Common Metals 49 223 (1976)CrossRefGoogle Scholar
13) Deublein, G. and Huggins, R.A., “Production of Hydrogen -Transparent Metal Surfaces by Use of Molten Salts With Very Low Oxygen and Water Activities”, presented at the meeting of the Electrochemical Society, San Diego (1986)Google Scholar
14) Gupta, M. and Schlapbach, L., in Topics in Applied Physics. “Hydrogen in Intermetallic Comunds I”, ed. by Schlapbach, L., Springer Verlag, Berlin (1988), p. 139 Google Scholar
15) Yvon, K. and Fischer, P., Topics in Applied Physics. Hydrogen in Metallic Compound I, ed. by Schlapbach, L., Springer Verlag, Berlin (1988), p.87 Google Scholar
16) Zolliker, P., Yvon, K., Jorgensen, J.D. and Rotella, F., Inorg. Chem. 25, 3590 (1986)CrossRefGoogle Scholar
17) Isenberg, I., Physic. Rev. 12, 736 (1950)Google Scholar
18) Schnabl, H., Ber. Bunsenges. Physik Chem. 68, 548 (1964)Google Scholar
19) San-Martin, A. and Manchester, F.D., Bull. Alloy Phase Diagrams 8, 30 (1987)Google Scholar
20) Halstead, T.K., J. Solid State Chem. 11 114 (1974)Google Scholar
21) Maly-Schreiber, M. and Huggins, R.A., “Thermodynamic and Kinetic Measurements on Titanium-Nickel Hydrides of Interest for Use in Rechargeable Batteries”, presented at meeting of the Electrochemical Society, Honolulu (1987)Google Scholar
22) Dickens, P.G., Crouch-Baker, S. and Weller, M.T., Solid State Ionics 18/19, 89 (1986)Google Scholar
23) Luedecke, C.M., Deublein, G., Huggins, R.A., J. Electrochem. Soc. 132, 52 (1985)Google Scholar
24) Rudman, P.S. and Sandrock, G.D., “Metallurgy of Rechargeable Hydrides”, in Annual Review of Materials Science, Vol. 12, ed. by Huggins, R.A., Annual Reviews (1982), p. 271 Google Scholar
25) Wiswall, R., “Hydrogen Storage in Metals”, in Topics in Applied Physics, Vol 29, Hydrogen in Metals II, ed. by Alefeld, G. and Voelkl, J., Springer-Verlag (1978), p. 201 Google Scholar
26) Wang, Qui-dong, Wu, Jing and Chen, Chang-pin, “Development of New Mischmetal-Nickel Hydrogen Storage Alloys According to the Specific Requirements of Different Applications”, to be published in the Proceedings of the International Symposium on Metal -Hydrogen Systems, Stuttgart, W. Germany (1988)Google Scholar
27) Bernauer, O., “Metal Hydride Storages”, to be published in the Proceedings of the International Symposium on Metal -Hydrogen Systems, Stuttgart, W. Germany (1988)Google Scholar
28) Zwart, R.L., “Hydrogen Purification with Metal Hydride Slurries”, to be published in the Proceedings of the International Symposium on Metal - Hydrogen Systems, Stuttgart, W. Germany (1988)Google Scholar
29) Reilly, J.J., Josephy, Y., and Johnson, R.J., to be published in the Proceedings of the International Symposium on Metal -Hydrogen Systems, Stuttgart, W. Germany (1988)Google Scholar
30) Fujitani, S., Yonezu, I. and Honda, N., “Development of Metal Hydrides for Heat Utilization Systems”, to be published in the Proceedings of the MRS Symposium on Hydrogen Absorbing Materials, Tokyo, Japan (1988)Google Scholar
31) Suda, S., “Energy Conversion Systems Using Metal Hydrides”, to be published in the Proceedings of the International Symposium on Metal -Hydrogen Systems, Stuttgart, W. Germany (1988)Google Scholar
32) Ron, M. and Josephy, Y., “Optimization of a Hydrogen Heat Pump”, to be published in the Proceedings of the International Symposium on Metal -Hydrogen Systems, Stuttgart, W. Germany (1988)Google Scholar
33) Supper, W., Groll, M. and Werner, R. “Dynamic Concentration-Pressure-Isotherms and their Impact on Metal Hydride Heat Pump Design” to be published in the Proceedings of the International Symposium on Metal -Hydrogen Systems, Stuttgart, W. Germany (1988)Google Scholar
34) Zijlstra, H. and Westendorp, F.F., Solid State Comm. 7, 857 (1969)Google Scholar
35) Vucht, J.H.N. van, Kuijpers, F.A. and Bruning, H.A.G.M., Philips Res. Repts. 25, 133 (1970)Google Scholar
36) Reilly, J.J. and Wiswall, R.H., Inorg. Chem. 13 218 (1974)CrossRefGoogle Scholar
37) Akiba, E. et al. , “Effect of Al Substitution on the Properties of the LaNi5−xAlx-H2 System”, to be published in the Proceedings of the Symposium on Hydrogen -Absorbing Materials, Materials Research Society (1988).Google Scholar
38) Toma, H. et al. , “Hydrogen Absorption - Desorption Characteristics of MmNi3.75Co0.75”, to be published in the Proceedings of the Symposium on Hydrogen - Absorbing Materials, Materials Research Society (1988).Google Scholar
39) Willems, J.J.G., Ph.D. Thesis, Technische Hogeschool Eindhoven, HollandGoogle Scholar
40) Buchner, H., “Energiespeicherung in Metallhydriden”, Springer-Verlag, Wien, New York (1982)Google Scholar
41) Vankatesan, S., Fetcenko, M., Reichman, B., Magnuson, D., Dhar, S., Proc. of the “2nd Internat. Rechargeable Battery SymposiumFlorida (1988)Google Scholar
42) Schreiber, M. M. and Huggins, R.A., “Recent Experimental Work on Titanium -Nickel Hydrides and Related Materials”, to be published in the Proceedings of the Symposium on Hydrogen - Absorbing Materials, Materials Research Society (1988).Google Scholar
43) Deublein, G., Liaw, B.Y. and Huggins, R.A., to be published in Solid State IonicsGoogle Scholar
44) Schreiber, M. and Huggins, R.A., “Mixed Conducting Membranes for Hydrogen -Transporting S/LUS Solid Electrolyte Configurations”, presented at the Meeting of the Electrochemical Society, Chicago, Oct. 1988 Google Scholar
45) Roy, P., “New Concept for a Thermally Regenerative Electrochemical Cell”, presented at the 33rd International Power Sources Symposium, Cherry Hill, NJ (1988)Google Scholar
46) Roy, P., Amijo, J.S. and Gerrels, E.E., “Hydrogen Thermoelectrochemical Converter”, presented at the IECEC, Denver Colorado, July 1988 Google Scholar