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Improved Stability Against Light-Exposure in Deuterated Amorphous Silicon Alloy Solar Cells

Published online by Cambridge University Press:  15 February 2011

S. Sugiyama ,
J. Yang  and
S. Guha
S. Sugiyama
Affiliation:
United Solar Systems Corp., 1100 W. Maple Road, Troy, MI 48084
J. Yang
Affiliation:
United Solar Systems Corp., 1100 W. Maple Road, Troy, MI 48084
S. Guha
Affiliation:
United Solar Systems Corp., 1100 W. Maple Road, Troy, MI 48084
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Abstract

We have studied light-induced degradation in hydrogenated and deuterated amorphous silicon alloy solar cells in which intrinsic layers were deposited by using SiH4+H2 and SiD4+D2 gas mixtures respectively. Replacing hydrogen with deuterium in the intrinsic layer of the cell improves stability against light exposure. On the other hand, cells in which intrinsic layers were deposited from SiD4+H2 and SiH4+D2 do not show any improvement in stability. This result shows that improved stability in deuterated cell does not originate from simple replacement of hydrogen with deuterium. From deuterium/hydrogen effusion measurements, we found similar effusion at low temperature (400 °C) in both deuterated film and hydrogenated film prepared with heavy dilution. The latter film was shown to have oriented microstructure which was correlated with higher stability. This correlation strongly indicates that microstructure of the material plays a key role in improving the stability.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 467: Symposium A – Amorphous and Microcrystalline Silicon Technology - 1997 , 1997 , 49
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1 For recent publications on this subject, see Amorphous Silicon Materials and Solar Cells, edited by Stafford, B. L. (American Institute of Physics, New York, 1991), Conf. Proc. 234.Google Scholar
2 Guha, S., Yang, J., Czubatyj, W., Hudgens, S. J., and Hack, M., Appl. Phys. Lett. 42, 588 (1983).Google Scholar
3 Wronski, C.R. and Maley, N., in Ref. 1, p. 11.Google Scholar
4 Stutzmann, M., Jackson, W. B., Smith, A. J., and Thomson, R., Appl. Phys. Lett. 48, 62 (1986).Google Scholar
5 Ganguly, G., Suzuki, A., Yamasaki, S., Nomoto, K., and Matsuda, A., J. Appl. Phys. 68, 3738 (1990).Google Scholar
6 Ganguly, G., Yamasaki, S., and Matsuda, A., Phil. Mag. B 63, 281 (1991)Google Scholar
7 Ganguly, G. and Matsuda, A., Phys. Rev. B 49, 10986 (1994).Google Scholar
8 Yang, J., Xu, X., and Guha, S., Mat. Res. Soc Symp. Proc. 336, 687 (1994).Google Scholar
9 Guha, S., Final Report, SERI/TP-211–3918, Solar Energy Research Institute, Golden, Colorado, 1990.Google Scholar
10 Lyding, J. W., Hess, K., and Kizilyalli, I. C., Appl. Phys. Lett. 68, 2526 (1996).Google Scholar
11 Xu, X., Yang, J., and Guha, S., J. Non-cryst. Solids, 198–200, 60 (1994).Google Scholar
12 Nevin, W. A., Yamagishi, H., Asaoka, K., Nishio, H., and Tawada, Y. Appl. Phys. Lett. 59, 3294 (1991).Google Scholar
13 McElheny, P. J., Suzuki, A., Mashima, S., Hasezaki, K., Yamasaki, S., and Matsuda, A., J. J. Appl. Phys. 30, L142 (1991).Google Scholar