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In situ Raman and UV-Vis spectroscopic analysis of lithium-ion batteries

Published online by Cambridge University Press:  22 June 2015

Marcel Heber ,
Christian Schilling ,
Toni Gross  and
Christian Hess
Marcel Heber
Affiliation:
Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, 64287 Darmstadt, Germany
Christian Schilling
Affiliation:
Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, 64287 Darmstadt, Germany
Toni Gross
Affiliation:
Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, 64287 Darmstadt, Germany
Christian Hess
Affiliation:
Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Str. 8, 64287 Darmstadt, Germany
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Abstract

The potential of Raman and UV-Vis diagnostics for spatially-resolved and in situ diagnostics of lithium-ion batteries is demonstrated. Regarding the use of in situ Raman diagnostics focus is put on LiCoO2 electrode materials, which were investigated in detail as composites of LiCoO2 with binder and conductive additives. The potential of in situ UV-Vis analysis is illustrated for carbon-based materials showing significant absorption changes during electrochemical cycling due to lithium de-/intercalation.

Keywords

energy storageintercalationRaman spectroscopy
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1773: Symposium G – Next Generation Electrochemical Energy Storage and Conversion Systems―Synthesis, Processing, Characterization and Manufacturing , 2015 , pp. 33 - 40
Copyright
Copyright © Materials Research Society 2015 

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