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In Situ Spectroscopy and Modeling of Deformation Behavior of Nanoscale Interfacial Materials

Published online by Cambridge University Press:  21 March 2011

Takakazu Suzuki
Affiliation:
Nano-System Research Institute, AIST, Tsukuba, Ibaraki 305-8563, Japan
W. Suetaka
Affiliation:
TSS Research Lab, Ibaraki, 305-0041, Japan
A. Suzuki
Affiliation:
TSS Research Lab, Ibaraki, 305-0041, Japan
T. Sato
Affiliation:
TSS Research Lab, Ibaraki, 305-0041, Japan
T. Suzuki
Affiliation:
TSS Research Lab, Ibaraki, 305-0041, Japan
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Abstract

In this work, the behavior of molecules in thin-film lubricants, several tens of nanometers thick, is studied by in situ reflection infrared spectroscopy and by molecular dynamics simulations. The effect of fatty acid additives on the properties of these interfacial films is also studied. The results of these experiments are presented and interpreted, and the latest outcomes of molecular dynamics simulations are discussed. It is concluded that the molecular orientation in thin films of interfacial materials is markedly affected by the use of additives.

Type
Research Article
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1. Suzuki, T., presented at the STLE 64th Annual Meeting & Exhibition, Lake Buena Vista, FL 2009 (unpublished)Google Scholar
2. Nakano, K. and Akiyama, Y., Tribo.Lett. 22 (2006) 127 Google Scholar
3. berro, Hassan, Fillot, Nicolas, and Vergne, Phillippo, Tribol. Lett., 37 (2010) 1 Google Scholar
4. Martini, Ashilie and Vadakkepatt, Ajay, Tribol. Lett., 38 (2010) 33 Google Scholar
5. Cann, P. M., MRS Bulletin, 33 (2008) 1151 Google Scholar
6. Sawyer, W. Gregory and Wahl, Kathryn J., MRS Bulletin, 33 (2008) 1145 Google Scholar
7. Legros, M., Gianola, D.S., and Motz, C., MRS Bulletin, 35 (2010) 354 Google Scholar
8. Suetaka, W., New Experiment Chemistry Course, Vol. 18, Interface and Colloid, edited by The Chemical Society of Japan (Maruzen, Tokyo 1977) 175 Google Scholar
9. Jones, R. N. & Sandorfy, C., Chemical Applications of Spectroscopy, Interscience (1956) 341 Google Scholar
10. Materials Studio 5.5, Accelrys Corporate Headquarters, San Diego, CA (2010)Google Scholar
11. Kuhn, H. and Rehage, H., Colloid Polym. Sci., 278 (2000) 114 Google Scholar