Hostname: page-component-586b7cd67f-g8jcs Total loading time: 0 Render date: 2024-11-25T17:57:23.479Z Has data issue: false hasContentIssue false

Ion Beam Injected Point Defects in Crystalline Silicon: Migration, Interaction and Trapping Phenomena

Published online by Cambridge University Press:  15 February 2011

F. Priolo
Affiliation:
INFM and Dipartimento di Fisica dell'Università, Corso Italia 57, 95129 Catania (Italy)
V. Privitera
Affiliation:
CNR-IMETEM, Stradale Primosole 50, 95100 Catania (Italy)
S. Coffa
Affiliation:
CNR-IMETEM, Stradale Primosole 50, 95100 Catania (Italy)
S. Libertino
Affiliation:
INFM and Dipartimento di Fisica dell'Università, Corso Italia 57, 95129 Catania (Italy)
Get access

Abstract

Our recent work on the room temperature migration and trapping phenomena of ion beam generated point defects in crystalline Si is reviewed. It is shown that a small fraction (˜10−6) of the defects generated at the surface by a shallow implant is injected into the bulk. These defects undergo a long range trap-limited diffusion and interact with both impurities, dopants and preexisting defects along their path. In particular, these interactions result in dopant deactivation and/or partial annihilation of pre-existing vacancy-type defect markers. It is found that in highly pure, epitaxial Si layers, these effects extend to several microns from the surface, demonstrating a long range migration of point defects at room temperature. By a detailed analysis of the experimental evidences we have identified the Si self-interstitials as the major responsible for the observed phenomena. This allowed us to give a lower limit of 6 × 10−11 cm2/s for the room temperature diffusion coefficient of the Si self-interstitials. Room temperature trap-limited migration of vacancies is also detected as a broadening in the divacancy profile of as implanted samples. In this case the room temperature diffusion coefficient of vacancies has been found to be ≥3 × 10−12 cm2/s. These data are presented and their implications discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Fahey, P. M., Griffin, P.B. and Plummer, J.D., Rev. Mod. Phys. 61, 289 (1989)Google Scholar
2. Taylor, W., Marioton, B. P. R., Tan, T. Y. and Gosele, U, Rad. Eff. And Defects in Solids 111–112, 131 (1989)Google Scholar
3. Gossmann, H. J., Rafferty, C.S., Luftman, H.S., Unterwald, F.C., Boone, T. and Poate, J.M., Appl. Phys. Lett. 63, 639 (1993).Google Scholar
4. Bronner, G. B. and Plummer, J. D., J. Appl. Phys. 61, 5286 (1987)Google Scholar
5. Watkins, G.D. and Corbett, J.W., Phys. Rev. 134, A1359 (1964)Google Scholar
6. Corbett, J.W. and Watkins, G.D., Phys. Rev. 138, A555 (1965)Google Scholar
7. Watkins, G. D., in Radiation Effects in Semiconductors, edited by Vook, F.L. (Plenum, New York, 1968) p.67 Google Scholar
8. Davies, G. and Newman, R. C., Carbon in mono-crystalline silicon in Handbook of Semiconductors, Vol.3b, Chapter 21, p. 15571636, North Holland, Amsterdam (1994)Google Scholar
9. Stolk, P. A., Eaglesham, D.J., Gossmann, H.J. and Poate, J.M., Appl. Phys. Lett. 66, 1370 (1995).Google Scholar
10. Larsen, K. Kyllesbech, Privitera, V., Coffa, S., Priolo, F., Campisano, S.U. and Carnera, A., Phys. Rev. Lett. 76, 1493 (1996).Google Scholar
11. Privitera, V., Coffa, S., Priolo, F. and Larsen, K. Kyllesbech, Appl. Phys. Lett. 68, 3422 (1996).Google Scholar
12. Svensson, B.G., Jagadish, C. and Williams, J.S., Phys. Rev. Lett. 71, 1860 (1993)Google Scholar
13. Christensen, C., Petersen, J.W. and Larsen, A. Nylandsted, Appl. Phys. Lett. 61, 1426 (1992)Google Scholar
14. Gilmer, G.H., Rubia, T. Diaz de la, Stock, D.M. and Jaraiz, M., Nucl. Instrum. Meth. B 102, 29 (1995).Google Scholar
15. Biersack, J.P., Haggmark, L.G., Nucl. Instr. Meth. 174, 257 (1980).Google Scholar
16. Brotherton, S.D. and Bradley, P., J. Appl. Phys. 53, 5720 (1982)Google Scholar
17. Cowern, N.E.B., Appl. Phys. Lett. 64, 2646 (1994).Google Scholar
18. Car, R., Kelly, P.J., Oshiyama, A., and Pantelides, S.T., Phys. Rev. Lett. 52, 1814 (1984)Google Scholar
19. Tang, M., Colombo, L., Zhu, J., and Rubia, T. Diaz de la, (to be published)Google Scholar
20. Coffa, S., Privitera, V., Priolo, F., Libertino, S., and Mannino, G., J. Appl. Phys. 81, 15 February issue (1997)Google Scholar
21. Libertino, S., Coffa, S., Privitera, V., and Priolo, F. (these proceedings)Google Scholar