Hostname: page-component-cd9895bd7-gbm5v Total loading time: 0 Render date: 2024-12-27T17:01:58.205Z Has data issue: false hasContentIssue false
  • English
  • Français

Molecular Scale Electronics. Critical Nanolithography Issues of Synthesis and Addressing

Published online by Cambridge University Press:  10 February 2011

S. Huang ,
E. T. Mickelson ,
A. M. Rawlett ,
C. L. Asplund ,
A. M. Cassell ,
M. Kozaki ,
T. P. Burgin ,
l. Jones II ,
J. M. Tour  and
M. L. Myrick
...Show all authors
S. Huang
Affiliation:
Department of Chemistry and Center for Nanoscale Science and Technology, MS 222, Rice University, Houston, TX 77005, USA, tour@rice.edu
E. T. Mickelson
Affiliation:
Department of Chemistry and Center for Nanoscale Science and Technology, MS 222, Rice University, Houston, TX 77005, USA, tour@rice.edu
A. M. Rawlett
Affiliation:
Department of Chemistry and Center for Nanoscale Science and Technology, MS 222, Rice University, Houston, TX 77005, USA, tour@rice.edu
C. L. Asplund
Affiliation:
Department of Chemistry and Center for Nanoscale Science and Technology, MS 222, Rice University, Houston, TX 77005, USA, tour@rice.edu
A. M. Cassell
Affiliation:
Department of Chemistry and Center for Nanoscale Science and Technology, MS 222, Rice University, Houston, TX 77005, USA, tour@rice.edu
M. Kozaki
Affiliation:
Department of Chemistry and Center for Nanoscale Science and Technology, MS 222, Rice University, Houston, TX 77005, USA, tour@rice.edu
T. P. Burgin
Affiliation:
Department of Chemistry and Center for Nanoscale Science and Technology, MS 222, Rice University, Houston, TX 77005, USA, tour@rice.edu
l. Jones II
Affiliation:
Department of Chemistry and Center for Nanoscale Science and Technology, MS 222, Rice University, Houston, TX 77005, USA, tour@rice.edu
J. M. Tour
Affiliation:
Department of Chemistry and Center for Nanoscale Science and Technology, MS 222, Rice University, Houston, TX 77005, USA, tour@rice.edu
M. L. Myrick
Affiliation:
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA
P. G. Van Patten
Affiliation:
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA
J. Chen
Affiliation:
Department of Electrical Engineering, Yale University, New Haven, CT 06520, USA, Email: mark.reed@yale.edu
C.-W. Zhou
Affiliation:
Department of Electrical Engineering, Yale University, New Haven, CT 06520, USA, Email: mark.reed@yale.edu
C. J. Muller
Affiliation:
Department of Electrical Engineering, Yale University, New Haven, CT 06520, USA, Email: mark.reed@yale.edu
M. R. Deshpande
Affiliation:
Department of Electrical Engineering, Yale University, New Haven, CT 06520, USA, Email: mark.reed@yale.edu
M. A. Reed
Affiliation:
Department of Electrical Engineering, Yale University, New Haven, CT 06520, USA, Email: mark.reed@yale.edu
L. A. Bumm
Affiliation:
Department of Chemistry, Pennsylvania State University, University Park, PA 16802, USA, Email: stm@psu.edu (Weiss)dla3@psu.edu (Allara)
M. T. Cygan
Affiliation:
Department of Chemistry, Pennsylvania State University, University Park, PA 16802, USA, Email: stm@psu.edu (Weiss)dla3@psu.edu (Allara)
T. D. Dunbar
Affiliation:
Department of Chemistry, Pennsylvania State University, University Park, PA 16802, USA, Email: stm@psu.edu (Weiss)dla3@psu.edu (Allara)
P. S. Weiss
Affiliation:
Department of Chemistry, Pennsylvania State University, University Park, PA 16802, USA, Email: stm@psu.edu (Weiss)dla3@psu.edu (Allara)
D. L. Allara
Affiliation:
Department of Chemistry, Pennsylvania State University, University Park, PA 16802, USA, Email: stm@psu.edu (Weiss)dla3@psu.edu (Allara)
Get access

Abstract

As we rapidly approach the point at which solid-state electronic devices cease to be made any smaller, molecular scale electronics offers, perhaps, the best chance for a continued miniaturization of computational devices. We must, however, completely re-think our approach to lithography. Presented in this paper are our solution-phase and solid-support based syntheses of molecular wires of precise length and dimensions, and our methods of addressing these wires via molecular “alligator clips” to gold and platinum electrodes of macroscale dimensions.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 584 , 1999 , 45
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Packan, P., Science 285, 2079 (1999).Google Scholar
2.Aviram, A., Ed. Molecular Electronics: Science and Technology, Conference Proceedings No. 262 (American Institute of Physics, New York, 1992).Google Scholar
3.Mujica, V., Kemp, M., Roitberg, A., and Ratner, M., J. Phys. Chem. 104, 7296 (1996).Google Scholar
4.Farazdel, A., Dupuis, M., Clementi, E., and Aviram, A., J. Am. Chem. Soc. 112, 4206 (1990).Google Scholar
5.Dai, H., Wong, E.W., and Lieber, C.M., Science 272, 523 (1996).Google Scholar
6.Ward, M.D., Chem. Ind. 568 (1996).Google Scholar
7.Purcell, S.T., Garcia, N., Binh, V.T., Jones, L. II, and Tour, J.M., J. Am. Chem. Soc. 116, 11985 (1994).Google Scholar
8.Pascual, J.I., Mendez, J., Gomez-Herrero, J., Baro, A.M., Garcia, N., Landman, U., Luedtke, W.D., Bogachek, E.N., and Cheng, H.-P., Science 267, 1793 (1995).Google Scholar
9.Joachim, C., and Vinuesa, J.F., Europhys. Lett. 33, 1100 (1996).Google Scholar
10.Aviram, A. and Ratner, M., Eds., Molecular Electronics: Science and Technology, Vol. 852 (Ann. N.Y. Acad. Sci., 1998).Google Scholar
11.Collier, C.P., Wong, W.W., Belohradsky, M., Raymo, F.M., Stoddart, J.F., Kuekes, P.J., Williams, R.S., and Heath, J.R., Science 285, 391 (1999).Google Scholar
12.Reed, M.A., Zhou, C., Muller, C.J., Burgin, T.P., and Tour, J.M., Science 278, 252 (1997).Google Scholar
13.Bumm, L.A., Arnold, J.J., Cygan, M.T., Dunbar, T.D., Burgin, T. P., Jones, L. II, Allara, D.L., Tour, J.M., and Weiss, P.S., Science 271, 1705 (1996).Google Scholar
14.Tour, J.M., Chem. Rev. 96, 537 (1996).Google Scholar
15.Hodge, P. and Sherrington, D.C., Eds. Polymer-Supported Reactions in Organic Synthesis (J. Wiley and Sons, New York, 1980).Google Scholar
16.Huang, S. and Tour, J.M., J. Org. Chem. (In press).Google Scholar
17.Pearson, D.L. and Tour, J.M., J. Org. Chem. 62, 1376 (1997).Google Scholar
18.Jones, L. II, Schumm, J.S., and Tour, J.M., J. Org. Chem. 62, 1388 (1997).Google Scholar
19.Huang, S. and Tour, J.M., J. Am. Chem. Soc. 121, 4908 (1999).Google Scholar
20.Zacarias, A.G., Castro, M., Tour, J.M., and Seminario, J.M., J. Phys. Chem. A. 103, 7692 (1999).Google Scholar
21.Schumm, J.S., Jones, L. II, Pearson, D.L., Hara, R., and Tour, J.M., Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 35(2), 687 (1994).Google Scholar
22.Muller, C.J., Vleeming, B.J., Reed, M.A., Lamba, J.S., Hara, R., Jones, L. II, and Tour, J.M., Nanotechnology 7, 409 (1996).Google Scholar
23.Schumm, J.S., Pearson, D.L., Jones, L. II, Hara, R., and Tour, J.M., Nanotechnology 7, 430 (1996).Google Scholar
24.Reinerth, W.A., Burgin, T.P., Dunbar, T.D., Bumm, L.A., Arnold, J.J., Jackiw, J. J., Zhou, C.-w., Deshpande, M.R., Allara, D.L., Weiss, P.S., Reed, M.A., and Tour, J.M., Polym. Mater., Sci. Engin. (Am. Chem. Soc., Div. Polym. Mater.) 78, 178 (1998).Google Scholar
25.Cygan, M.T., Dunbar, T.D., Arnold, J.J., Bumm, L.A., Shedlock, N.F., Burgin, T.P., Jones, L. II, Allara, D.L., Tour, J.M., and Weiss, P.S.J. Am. Chem. Soc. 120, 2721 (1998).Google Scholar
26.Tour, J.M., Reinerth, W.A., Jones, L. II, Burgin, T.P., Zhou, C.-w., Muller, C.J., Deshpande, M.R., and Reed, M.A., Molecular Electronics: Science and Technology Vol. 852, edited by Aviram, A. and Ratner, M. (Ann. N.Y. Acad. Sci., 1998) pp. 197–.Google Scholar
27.Allara, D.L., Dunbar, T.D., Weiss, P.S., Bumm, L.A., Cygan, M.T., Tour, J.M., Reinerth, W.A., Yao, Y., Kozaki, M., and Jones, L. II, Molecular Electronics: Science and Technology Vol. 852, edited by Aviram, A. and Ratner, M. (Ann. N.Y. Acad. Sci., 1998) pp. 349–.Google Scholar
28.Seminario, J.M., Zacarias, A.G., and Tour, J.M., J. Am. Chem. Soc. 121, 411 (1999).Google Scholar
29.Tour, J.M., Jones, L. II, Pearson, D.L., Lamba, J.S., Burgin, T.P., Whitesides, G.W., Allara, D.L., Parikh, A.N., and Atre, S., J. Am. Chem. Soc. 117, 9529 (1995).Google Scholar
30.Weiss, P.A., Bumm, L.A., Dunbar, T.D., Burgin, T.P., Tour, J.M., and Allara, D.L., Molecular Electronics: Science and Technology Vol. 852, edited by Aviram, A. and Ratner, M. (Ann. N.Y. Acad. Sci., 1998) pp. 145–.Google Scholar
31.Reed, M.A., Zhou, C., Deshpande, M.R., Muller, C.J., Burgin, T.P., Jones, L. II, and Tour, J.M., Molecular Electronics: Science and Technology Vol. 852, edited by Aviram, A. and Ratner, M. (Ann. N.Y. Acad. Sci., 1998) pp. 133–.Google Scholar
32.Zhou, C., Muller, C.J., Reed, M.A., Burgin, T.P., and Tour, J.M., in Molecular Electronics, edited by Jortner, J. and Ratner, M. (Blackwell Science, Oxford, 1997) pp. 191–.Google Scholar
33.Zhou, C., Deshpande, M.R., Reed, M.A., Jones, L. II, and Tour, J.M., Appl. Phys. Lett. 71, 611 (1997).Google Scholar
34.Chen, J., Reed, M.A., Asplund, C.L., Cassell, A.M., Myrick, M.L., Rawlett, A.M., Tour, J.M., and Van Patten, P.G., Appl. Phys. Lett. 75, 624 (1999).Google Scholar
35.Muller, C.J., van Ruitenbeck, J.M., and Jough, L.J. de, Physica C 191, 485 (1992).Google Scholar