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Non-Classfcal Kinetiics in Hydrogen-Deuterium Exchange Reaction on Metal Catalyst

Published online by Cambridge University Press:  15 February 2011

Inchan Choi  and
Raoul Kopelman
Inchan Choi
Affiliation:
Department of Chemistry, University of Michigan, Ann Arbor, MI 48109
Raoul Kopelman
Affiliation:
Department of Chemistry, University of Michigan, Ann Arbor, MI 48109
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Abstract

Monte Carlo simulations of the A2 + B2→ P (with P = AA, AB, and BB) reaction on various monodisperse island systems provided various models for the reaction H2 + D2→ HD on alumina supported platinum catalysts. Anomalous reaction kinetics and reaction orders due to the effects of diffusion, reactant correlation, and ensemble character of the catalyst in low dimensional systems are observed not only at early time but also at steady state. Concentration effects and spillover studies indicate that surface diffusion and hydrogen spillover may be responsible for the anomalous behaviors.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 290: Symposium N – Dynamics in Small Confining Systems , 1992 , 267
Copyright
Copyright © Materials Research Society 1993

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