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Optimization of Savannah River M-Area Mixed Waste for Vitrification

Published online by Cambridge University Press:  03 September 2012

Sabrina S. Fu ,
Hao Gan ,
Isabelle S. Muller ,
Ian L. Pegg  and
Pedro B. Macedo
Sabrina S. Fu
Affiliation:
Vitreous State Laboratory, The Catholic University of America, Washington, D.C. 20064.
Hao Gan
Affiliation:
Vitreous State Laboratory, The Catholic University of America, Washington, D.C. 20064.
Isabelle S. Muller
Affiliation:
Vitreous State Laboratory, The Catholic University of America, Washington, D.C. 20064.
Ian L. Pegg
Affiliation:
Vitreous State Laboratory, The Catholic University of America, Washington, D.C. 20064.
Pedro B. Macedo
Affiliation:
Vitreous State Laboratory, The Catholic University of America, Washington, D.C. 20064.
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Abstract

Vitrification studies of actual Savannah River M-Area mixed wastes have shown that the limiting factor for high waste loading of this waste stream is its chemical durability as defined by the toxicity characteristics leaching procedure (TCLP). As part of the optimization study of Savannah River M-Area wastes, a number of additives were examined including Na2O, Li2O, B2O3, ZrO2, and TiO2. This paper reports on the effect of varying the boron to total alkali ratio and on the effect of substitutions such as ZrO2 for waste and TiO2 for SiO2 on the chemical durability and processability of M-Area waste glasses.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 465: Symposium II – Scienfific Basis for Nuclear Waste Management XX , 1996 , 139
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1. Piekert, J.B., Musall, J.C., and Martin, H.L., Proceedings of the Second International Symposium on Mixed Waste, edited by Alan Moghissi, A., Blauvelt, R.K., Benda, G.A., and Rothermich, N.E., 1993.Google Scholar
2. Proposal to Savannah River from CUA/GTS Duratek, March 1993.Google Scholar
3. Fu, S.S., Characterization Studies in Support of Savannah River M-Area Engineering, Report to GTS Duratek, May 1994.Google Scholar
4. Fu, S.S. and Matlack, K.S., Savannah River DuraMelter™ 10 Runs Using VSL Composition, Report to GTS Duratek, October 1994.Google Scholar
5. Fu, S.S., Savannah River DuraMelter™ 10 OTD Runs, Report to GTS Duratek, November 1994.Google Scholar
6. Bowen, B.W. and Brandys, M.M., Ceramic Transactions, 61, 213 (1995).Google Scholar
7. EPA SW-846 Method 1311, Toxicity Characteristic Leaching Procedure.Google Scholar
8. Yan, Q., Buechele, A.C., Hu, S., Wang, E., and Fu, S.S., Ceramic Transactions, 61, 221 (1995).Google Scholar
9. Fu, S.S., Physics and Chemistry of Glasses, 38 (2), 100 (1997).Google Scholar
10. Dimbleby, V., and Turner, W.E.S., J. Soc. Glass-Technol., 10, 304 (1926).Google Scholar
11. Xing, S., Lin, Y., Mohr, R.K., and Pegg, I.L., Proceedings to the Materials Research Society Meeting, Fall of 1995.Google Scholar
12. Farges, F., Brown, G.E. Jr., Navrotsky, A., Gan, H., and Rehr, J.J., Geochimica et Cosmochimica Acta., 60, 3039 (1996).10.1016/0016-7037(96)00145-7Google Scholar