Hostname: page-component-78c5997874-dh8gc Total loading time: 0 Render date: 2024-11-17T18:04:27.582Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation and Characterization of Group 14 Element BIS(Thiolate) Compounds and Evaluation of Their Potential as Molecular Precursors in the Low Temperature Syntheses of Binary Metal Sulfides

Published online by Cambridge University Press:  22 February 2011

Gertrud KrÄuter ,
Philippe Favreau ,
Brian K. Nunnally  and
W. S. Rees JR.
Gertrud KrÄuter
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, F1 32306-3006
Philippe Favreau
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, F1 32306-3006
Brian K. Nunnally
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, F1 32306-3006
W. S. Rees JR.*
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, F1 32306-3006
*
address all correspondence to this author at: School of Chemistry and Biochemistry and School of Materials Research and Engineering, Georgia Instiute of Technology, Atlanta, Ga 30332-0400
Get access

Abstract

Three isomeric lead bis(butylthiolate) and tin bis(butylthiolate) compounds have been prepared and characterized. Their solid state decomposition, and in the case of the lead bis(thiolate) compounds, their thermolyses in suspension in a high boiling hydrocarbon, have been studied. X-ray powder diffraction patterns and scanning electron micrographs of the obtained solid state material are discussed. Volatile co-products of the decomposition have been isolated and characterized.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 327: Symposium N – Covalent Ceramics II: Non-Oxides , 1993 , 41
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Gmelin's Handbook der Anorganischen Chemie, 8th ed., edited by Hantke, G. (Verlag Chemie, Weinheim, 1969) 47C, pp. 414–426.Google Scholar
2. Leskelä, M., Niinistö, L., Niemela, P., Nykänen, E., Soininen, P., Tiita, M., Vähäkangas, J., Vacuum 41, 1459 (1990).Google Scholar
3. Stenhouse, J., Lieb. Ann. 149, 247 (1869).Google Scholar
4. Shaw, R. A., Woods, M., J. Chem. Soc. 1971, 1569.Google Scholar
5 a. Mont, W. W. Du, Grenz, M., Chem. Ber. 118, 1045 (1985).Google Scholar
5 b. Veith, M., Hobein, P., Rösler, R., Z. Naturforsch. 44B, 1067 (1989).Google Scholar
6. Kräuter, G., Favreau, P., Rees, W. S. Jr., Chem. Matls., submitted for publication.Google Scholar
7. Rees, W. S. Jr., and Kräuter, G., Abstract N6.1 presented at the 1993 MRS Fall Meeting, Boston, MA, 1993.Google Scholar
8. Rees, W. S. Jr., Kriuter, G., Goedken, V. L., MRS Symposiums Proceedings 283, (Materials Research Society, Pittsburgh, PA, 1993), pp. 859–864.Google Scholar
9. Rees, W. S. Jr., and Kriuter, G., Recent Advances in the Chemistry of Main Group Elements, Symposiums Proceedings, (Gordon and Breach, Langhorne, PA, 1994), accepted for publication.Google Scholar
10. Kräuter, G., Goedken, V. L., Neumüller, B., Rees, W. S. Jr., Abstract N4.7, presented at the 1993 MRS Fall Meeting, Boston, MA, 1993.Google Scholar