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The preparation of Ni nano particles by the chemically controlled polyol process

Published online by Cambridge University Press:  01 February 2011

Seon-Mi Yoon ,
Jae-Young Choi ,
Yong Kyun Lee ,
Eun Sung Lee  and
Seul Ki Kim
Seon-Mi Yoon
Affiliation:
Materials Lab, Materials & Devices Research Center, Samsung Advanced Institute of Technology, P. O. Box 111, Suwon 440–600, Korea
Jae-Young Choi
Affiliation:
Materials Lab, Materials & Devices Research Center, Samsung Advanced Institute of Technology, P. O. Box 111, Suwon 440–600, Korea
Yong Kyun Lee
Affiliation:
Materials Lab, Materials & Devices Research Center, Samsung Advanced Institute of Technology, P. O. Box 111, Suwon 440–600, Korea
Eun Sung Lee
Affiliation:
Materials Lab, Materials & Devices Research Center, Samsung Advanced Institute of Technology, P. O. Box 111, Suwon 440–600, Korea
Seul Ki Kim
Affiliation:
Materials Lab, Materials & Devices Research Center, Samsung Advanced Institute of Technology, P. O. Box 111, Suwon 440–600, Korea
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Abstract

The chemically controlled polyol process, with TMAH and water as OH- donors in the nickel hydroxyglycolate intermediate phase, prepares the nickel nano particles. The water additive acts as the OH- donor and enhances the solubility of salt in polyol for efficient production and monodispersive particles. Water and TMAH, selected to decrease the contamination of alkali metal from inorganic base, as OH- donors control the intermediary solid phase as a reservoir for Ni2+ species. The particle is about 80 nm with a faceted shape when the reaction is controlled by a combination of TMAH and water,. The nucleating agent is powerful to decrease the particle size, but in this basic reaction condition, it is not effective enough to get a small size.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 848: Symposium FF – Solid-State Chemistry of Inorganic Materials V , 2004 , FF3.35
Copyright
Copyright © Materials Research Society 2005

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References

REFERENCES

1. Koltypin, Y., Katabi, G., Cao, X., Prozorov, R., Gedanken, Al., J. Non-Cryst. Solids, 201, 159 (1966)Google Scholar
2. Chen, D., Wu, S., Chem. Mater. 12, 1354 (2000)Google Scholar
3. Hwang, J.–H., Dravid, V. P., Teng, M. H., Host, J. J., Elliott, B. R., Joshnson, D. L., Mason, T. O., J. Mater. Res. 12, 1076 (1997)Google Scholar
4. Stopić, S., Nedeljković, J., Rakočević, S., Uskoković, D., J. Mater. Res. 1999, 14, 3059 Google Scholar
5. Fiévet, F., Lagier, J. P., Figlarz, M., MRS. Bull. 14, 29 (1989)Google Scholar
6. Viau, G., Fiévet-Vincent, F., and Fiévet, F., Solid State Ionics, 84, 259–270 (1996)Google Scholar
7. Chen, D.-H., Wu, S.–H., Chem. Mater. 12, 1354 (2000)Google Scholar
8. Degan, A., Maček, J., Nanostructured Materials, 12, 225 (1999)Google Scholar
9. Fievet, F., Lagier, J.P., Blin, B., Beaudoin, B. and Figlarz, M., Solid State Ionics, 32/33, 198(1989)Google Scholar
10. Ducamp-Sanguesa, C., Herrera-Urbina, R. and Figlarz, M., J. Solid State Chem., 10, 272 (1992)Google Scholar
11. Viau, G., Fievet-Vincent, F. and Fievet, F., J. Mater. Chem., 6, 1047 (1996)Google Scholar
12. Hegde, M.S., Larcher, D., Dupont, L., Beaudoin, B., Tekaia-Eihsissen, K., Tarascon, J.-M., Solid State Ionics, 93, 33∼50(1997)Google Scholar