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Properties of Solutions of Rodlike Chains from Dilute Solutions to the Nematic State

Published online by Cambridge University Press:  26 February 2011

Guy C. Berry
Guy C. Berry*
Affiliation:
Carnegie Mellon University, Department of Chemistry, 4400 Fifth Avenue, Pittsburgh, PA 15213
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Abstract

Certain aspects of the physical chemistry of solutions rodlike polymers are reviewed. The range of concentrations includes infinite dilution ([ŋ]c<<l), dilute solutions ([ŋ,]c<l), moderately concentrated solutions (l<[ŋ]c<[ŋ]cNI), and concentrated solutions (c<cN,), where [ŋ] is the intrinsic viscosity and cNI. is the concentration required for a stable nematic phase. Studies of chain conformation are emphasized at infinite dilution, and rheological behavior is emphasized for more concentrated isotropic and nematic solutions. Both theoretical and experimental considerations are included.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 134: Symposium J – Materials Science and Engineering of Rigid-Rod Polymers , 1988 , 181
Copyright
Copyright © Materials Research Society 1989

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References

REFERENCES

1. Wolfe, J. F., Loo, B. H., and Arnold, F. R., Macrmolecules, 14, 915 (1981).Google Scholar
2. Wolfe, J. F. and Arnold, F. E., Macromolecules, 14, 909 (1981).Google Scholar
3. Evers, R. C., Arnold, F. E., and Helminiak, T. E., Macromolecules, 14, 925 (1981).Google Scholar
4. Hwang, W. F., Wiff, D. R., Benner, C. L., and Helminiak, T. E., J. Macromol. Sci., Phys., B22, 231 (1983).Google Scholar
5. Bair, T. I., Morgan, P. W., and Killian, F. L., Macromolecules, 10, 1396 (1977).Google Scholar
6. Arnold, F. E., Private Communication.Google Scholar
7. Berry, G. C., J. Polym. Sci., Polyl. Syap., 65, 143 (1978).Google Scholar
8. Yamakawa, H., Modern Theory of Polymer Solutions, (Harper and Row, New York, 1971) (a) p.52, (b) p.334, (c) p.326, (d) p.314.Google Scholar
9. Berry, G. C., J. Polym. Sci., Pt. B: Polym. Phys., 26, 1137 (1988).Google Scholar
10. Wong, C. P., Ohnuma, H., and Berry, G. C., J. Polyw. Sci., Polym. Symp. 65, 173 (1978).Google Scholar
11. Berry, G. C. and Fox, T. G, J. Macromol. Sci., A3, 1125 (1969).Google Scholar
12. Berry, G. C. and Risaman, P. R., J. Polym. Sci., Polym. Phys., Ed. 12, 2253 (1974).Google Scholar
13. Volkenstein, M. V., Configurational Statistics of Polymer Chains, (Interscience Publ., New York, 1963), p. 188.Google Scholar
14. Fixman, M., J. Chem. Phys., 76, 6346 (1982).Google Scholar
15. Davis, R. M. and Russel, W. B., J. Polym. Sci., Pt. B: Polym. Phys., 24, 511 (1986).Google Scholar
16. Yamakawa, H. and Stockmayer, W. H., J. Chew. Phys., 57, 2843 (1972).Google Scholar
17. Muthukumar, M. and Nickel, B. G., J. Chem. Phys., 86, 460 (1987).Google Scholar
18. Berry, G. C. and Casassa, E. F., Macramol., Rev. 4, 1 (1970).Google Scholar
19. Fixman, M. and Skolnick, J., Macromolecules, 11, 863 (1978).Google Scholar
20. Berry, G. C., Disc. Faraday Soc., 49, 121 (1970).Google Scholar
21. Cotts, P. Metzger and Berry, G. C., J. Polym. Sci., Polym. Phys., Ed. 21, 1255 (1983).Google Scholar
22. Arpen, M. and Strazielle, C., Makramol. Chew., 177, 293 (1976).Google Scholar
23. Furukawa, R. and Berry, G. C., Pure Appi. Chem., 57, 913 (1985).Google Scholar
24. Berry, G. C., Wei-Berk, C. C., and Furukawa, R., Polym. Preprints, Am. Chew. Soc., 27(1), 228 (1986).Google Scholar
25. Wolfe, J. F., Private Communication.Google Scholar
26. Berry, G. C., in Encyclopedia of Polymer Science and Engineering, Vol. 8, Edited by Mark, H. et al. , (John Wiley & Sons, New York, 1987), p. 721.Google Scholar
27. Doi, M. and Edwards, S. F., The Theory of Polymer Dynamics, (Clarendon Press, Oxford, 1986), (a) p.295, (b) p.324, (c) p.334, (d) p.336, (e) p.350.Google Scholar
28. Doi, M., J. Phys. (Paris), 36, 607 (1975).Google Scholar
29. Berry, G. C., Faraday Discuss. Chew. Soc., 79, 141 (1985).Google Scholar
30. Odell, J. A., Atkins, E. D. T., and Keller, A., J. Polym. Sci., Polym. Lett., Ed. 21, 289 (1983).Google Scholar
31. Einaga, Y., Berry, G. C., and Chu, S-G, Polymer J., 17, 239 (1985).Google Scholar
32. Kuzuu, N. Y. and Doi, M., Polymer J., 12, 883 (1980).Google Scholar
33. Flory, P. J., Proc. R. Soc. London Ser. A, 234, 73 (1956).Google Scholar
34. Flory, P. J., Macromolecules, 11, 1141 (1978).CrossRefGoogle Scholar
35. Tsai, H. H., Phase Equilibrium and Rheological Studies of Solutions of Rodlike. Articulated Polymers and Their Mixtures, Ph.D. Thesis, Carnegie Mellon University, 1983.Google Scholar
36. Flory, P. J., Macromolecules, 11, 1138 (1978).CrossRefGoogle Scholar
37. Se, K. and Berry, G. C., Mol. Cryst. Liq. Cryst., 153, 133 (1987).Google Scholar
38. Se, K. and Berry, G. C., in Reversible Polymer Gels and Related Systems, Edited by Russo, P. S. (Am. Chem. Soc. Symp. Series, 1987), p. 129.Google Scholar
39. Marrucci, G., Mol. Cryst. Liq. Cryst. (Lett.), 72, 153 (1982).Google Scholar
40. Kuzuu, N. and Doi, M., J. Phys. Soc. Jpn., 52, 3489 (1983).Google Scholar
41. Leslie, F. M., Adv. Liq. Cryst., 4, 1 (1979).Google Scholar
42. Doi, M., J. Polym. Sci., Polym. Phys., Ed. 19, 229 (1981).Google Scholar
43. Berry, G. C., Mol. Cryst. Liq. Cryst., in press.Google Scholar
44. Papkov, S. P., Kulichikhin, U. G., Kalmykova, V. D., and Malken, A. Y., J. Polym. Sci., 12, 1753 (1974).Google Scholar
45. Currie, P. K., J. Physique, 40, 501 (1979).Google Scholar
46. Berry, G. C., Se, K., and Srinvasarao, M., in High Modulus Polymers, Ed. by Zachariades, A. R. and Porter, R. S. (Marcel Dekker, Inc., New York, 1988) p. 195.Google Scholar
47. Marrucci, G., Pure Appi. Chew., 57, 1545 (1985).Google Scholar
48. Kiss, G. and Porter, R. S., Mol. Cryst. Liq. Cryst., 60, 267 (1980).Google Scholar
49. Lee, C. C., Chu, S. G., and Berry, G. C., J. Polym. Sci., Polym. Phys., Ed., 21, 1573 (1983).Google Scholar
50. Flory, P. J., Adv. Polym. Sci., 59, 1 (1984).Google Scholar
51. Wenz, G., Muller, M. A., Schmidt, M., and Wegner, G., Macramolecules, 17, 837 (1984).Google Scholar
52. Cotts, P. Metzger, Maxka, J., and Miller, R. D., Polym. Preprints, Am. Chew. Soc., 28(1), 450 (1987).Google Scholar
53. Fixman, M., Phys. Rev. Lett., 54, 337 (1985); 55, 2429 (1985).Google Scholar
54. Keep, G. T. and Pecora, R., Macromolecules, 18, 1167 (1985); 21, 817 (1988).Google Scholar
55. Bitsanis, I., Tirrell, M., and Davis, H. T., this volume.Google Scholar
56. Kim, C. S., Sullivan, V. S., and Berry, G. C., Proceed, 46th. Tech Confr., Soc. Plastics Eng., 34, 990 (1988).Google Scholar
57. Dowell, F., Mol. Cryst. Liq. Cryst., 155, 457 (1988).Google Scholar
58. Ballauff, M. and Flory, P. J., Ber. Bunsen-Ges. Phys. Chew., 88, 530 (1984).Google Scholar
59. Russo, P. S. and Miller, W. G., Macromolecules, 17, 1324 (1984).Google Scholar
60. Taratuta, V., Hurd, A. J., and Meyer, R. B., Phys. Rev. Lett., 55, 246 (1985).Google Scholar
61. Vroege, G. J. and Odijk, T., J. Chew. Phys., 87, 4223 (1987).Google Scholar
62. Lee, S-D. and Meyer, R. B., Phys. Rev. Lett., 61, 2217 (1988).Google Scholar
63. deGennes, P. G, The Physics of Liquid Crystals, (Oxford University Press, Oxford, 1974), p. 85.Google Scholar
64. Lonberg, F., Fraden, S., Hurd, A. J., and Meyer, R. E., Phys. Rev. Lett., 52, 1903 (1984).Google Scholar
65. Mackley, M. R., Mol. Cryst. Liq. Cryst., 153, 249 (1987).Google Scholar