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The Reactivity of C60 in Fuming Sulfuric and Chlorosulfonic Acids

Published online by Cambridge University Press:  22 February 2011

G.P. Miller ,
M.A. Buretea ,
J.W. Swirczewski  and
J.M. McConnachie
G.P. Miller
Affiliation:
Corporate Research Laboratory, Exxon Research & Engineering Company, Route 22 E, Annandale, N.J. 08801
M.A. Buretea
Affiliation:
Corporate Research Laboratory, Exxon Research & Engineering Company, Route 22 E, Annandale, N.J. 08801
J.W. Swirczewski
Affiliation:
Corporate Research Laboratory, Exxon Research & Engineering Company, Route 22 E, Annandale, N.J. 08801
J.M. McConnachie
Affiliation:
Corporate Research Laboratory, Exxon Research & Engineering Company, Route 22 E, Annandale, N.J. 08801
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Abstract

C60 is sultonated in fuming sulfuric acid and chlorinated in chlorosulfonic acid. Both reactions involve initial oxidation of C60 followed by in situ trapping of electrophilic C60 cation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 349: Symposium T – Novel Forms of Carbon II , 1994 , 115
Copyright
Copyright © Materials Research Society 1994

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References

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