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Sensor Response of Stilbite Single Crystals Under “in Situ” Conditions

Published online by Cambridge University Press:  11 February 2011

O. Schäf ,
H. Ghobarkar  and
P. Knauth
O. Schäf
Affiliation:
Laboratory MADIREL, University of Provence-CNRS (UMR 6121) Centre St-Jérôme, 13397 Marseille Cedex 20, France.
H. Ghobarkar
Affiliation:
Free University of Berlin, Institute for Mineralogy, Berlin, Germany
P. Knauth
Affiliation:
Laboratory MADIREL, University of Provence-CNRS (UMR 6121) Centre St-Jérôme, 13397 Marseille Cedex 20, France.
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Abstract

The isothermal conductivity of natural stilbite single crystals depends on water content, polar organic molecule concentration and charge compensating cation species. The observed interaction processes are almost completely adsorptive at temperatures below 110°C; catalytic oxidation of the organic molecules is taking place at much higher temperatures, where zeolitic water is almost completely desorbed. A schematic model describing the observed conductivity modifications is developed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 756: Symposia EE/FF – Solid-State Ionics – Materials for Fuel Cells and Fuel Processors , 2002 , EE9.6
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

[1] Meier, W.M., Olson, D.H. and Baerlocher, C., eds. Atlas of Zeolite Structure Types, 4threv. edn., Elsevier, London, Boston, Singapore, Sidney, Toronto, Wellington (1996)Google Scholar
[2] Gottardi, G., Galli, E., Natural Zeolites. Springer, Heidelberg, N.Y., Tokyo (1985)Google Scholar
[3] Karge, H.G., Weitkamp, J. (eds.), Molecular Sieves, Science and Technology Vol. 1, Synthesis. Springer, Berlin, Heidelberg, N.Y. (1998)Google Scholar
[4] Weitkamp, J., Puppe, L. (eds.), Catalysis and Zeolites, Fundamentals and Application, Springer Verlag, Berlin, Heidelberg, N.Y., London, Paris, Tokyo (1999)Google Scholar
[5] Simonot-Grange, M.H., Clays and Clay Minerals 27(6) (1979) 423–428 Google Scholar
[6] Ghobarkar, H., Schäf, O. and Guth, U., Progr. Solid State Chem. 27 (1999) 29–73 Google Scholar
[7] Beattie, I.R., Trans. Faraday Soc. 50 (1954) 581–587 Google Scholar
[8] Freeman, D.C., Stamires, D.N., J. Chem. Physics 35(3) 1961) 799–806 Google Scholar
[9] Jansen, F.J., Schoonheydt, R., J. Chem. Soc. Farad. Trans. I (1973) 1338–1355 Google Scholar
[10] Mortier, W.J., Schoonheydt, R., Prog. Solid State Chem. 16 (1985) 1–125 Google Scholar
[11] Galli, E., Acta Cryst. B 27 (1971) 833–841 Google Scholar
[12] Schäf, O., Ghobarkar, H. and Guth, U., Ionics 3 (1997) 282–288 Google Scholar
[13] Schäf, O., Ghobarkar, H., Steinbach, A.C., Guth, U., Fresenius J. Anal. Chem. 367 (2000) 388–392 Google Scholar
[14] Schäf, O., Ghobarkar, H., Adolf, F., Knauth, P., Solid State Ionics 143(3/4) (2001) 433–444 Google Scholar
[15] Schäf, O., Ghobarkar, H., Proceedings Conference on Basic Science and Advanced Technology, BSAT-II, Nov. 5–7, 2000 Assiut, Egypt, Vol.1, 35–64 Google Scholar
[16] Kelemen, G., Lortz, W., Schön, G., J. Mat. Sci. 24 (1989) 333–338 Google Scholar
[17] Krogh-Andersen, E., Krogh Andersen, I.G., Skou, E., Proton Conduction in Zeolites in: Proton Conductors, Columban, P. (ed), Cambridge University Press, Cambridge (1992)Google Scholar
[18] Resing, H.A., Thomson, J.K. in: Molecular Sieve Zeolites I, Flanigen, M. et al. (eds). Adv. Chem. Series 101, American Chemical Society (1971)Google Scholar