Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-24T15:53:01.297Z Has data issue: false hasContentIssue false
  • English
  • Français

Solid State Chemistry Approach to Advanced Thermoelectrics. Ternary and Quaternary Alkali Metal Bismuth Chalcogenides as Thermoelectric Materials

Published online by Cambridge University Press:  10 February 2011

Mercouri G. Kanatzidis ,
Duck-Young Chung ,
Lykourgos Iordanidis ,
Kyoung-Shin Choi ,
Paul Brazis ,
Melissa Rocci ,
Tim Hogan  and
Carl Kannewurt
Mercouri G. Kanatzidis
Affiliation:
Dept of Chemistry, Michigan State University and Center for Fundamental Materials Research, East Lansing, MI 48824.
Duck-Young Chung
Affiliation:
Dept of Chemistry, Michigan State University and Center for Fundamental Materials Research, East Lansing, MI 48824.
Lykourgos Iordanidis
Affiliation:
Dept of Chemistry, Michigan State University and Center for Fundamental Materials Research, East Lansing, MI 48824.
Kyoung-Shin Choi
Affiliation:
Dept of Chemistry, Michigan State University and Center for Fundamental Materials Research, East Lansing, MI 48824.
Paul Brazis
Affiliation:
Dept. of Electrical Engineering and Computer Science Northwestern University, Evanston, Illinois, 60208.
Melissa Rocci
Affiliation:
Dept. of Electrical Engineering and Computer Science Northwestern University, Evanston, Illinois, 60208.
Tim Hogan
Affiliation:
Dept of Electrical Engineering, Michigan State University, East Lansing, Ml 48824
Carl Kannewurt
Affiliation:
Dept. of Electrical Engineering and Computer Science Northwestern University, Evanston, Illinois, 60208.
Get access

Abstract

Our exploratory research to identify new promising candidates for next generation thermoelectric applications has produced several interesting new materials which are briefly described here. We present their compositions, solid state structures, properties and charge transport behavior. The compounds CsBi4Te6, β-K2Bi8Se13, Ba4Bi6Se13, Eu2Pb2Bi6Se13, KBi6.33S10, Eu2Pb2Bi4Se10, Ba2Pb2Bi6S13 and K1.25 Pb3.5Bi7.25Se15 are particularly noteworthy.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 545: Symposium Z – Thermoelectric Materials 1998 - The Next Generation… , 1998 , 233
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Thermoelectric Materials - New Directions and Approaches, Tritt, T. M.; Kanatzidis, M. G.; Lyon, H. B.; Mahan, G. D. Ed., Mat. Res. Soc. Symp. Proc. 1997, 478, and references therein.Google Scholar
2 Kanatzidis, M. G.; DiSalvo, F. J. “Thermoelectric Materials:Solid State Synthesis”, ONR Quarterly Review 1996, XXVII, 14–22.Google Scholar
3 (a) Sales, B. C. Mater. Res. Bull.. 1998, 23, 15–21. (b) Sales, B. C.; Mandrus, D; Williams, R. K. Science 1996, 272, 1325–1328. (c) Sales, B. C.; Mandrus, D; Chakoumakos, B. C.; Keppens, V.; Thompson, J. R. Phys. Rev. B. 1997, 56, 15081–15089.CrossRefGoogle Scholar
4 (a) Caillat, T; Fleurial, J. P. J. Phys. Chem. Solids 1998, 59, 1139-1144. (b) Roche, C.; Pecheur, P.; Toussaint, G.; Jenny, A.; Scherrer, H., Scherrer, S. J. Phys. B. 1998, 10, L333-L339.Google Scholar
5 Tritt, T. M. Science 1996, 272, 1276-1277.CrossRefGoogle Scholar
6 Sellinschegg, H.; Stuckmeyer, S. L.; Hornbostel, M. D.; Johnson, D. C. Chem. Mater. 1998, 10, 1096–1101.CrossRefGoogle Scholar
7 Littleton, R. T.; Tritt, T. M.; Feger, C. R.; Kolis, J.; Wilson, M. L.; Marone, M.; Payne, J.; Verebeli, D.; Levy, F. Appl. Phys. Lett. 1998, 72, 2056–2058.CrossRefGoogle Scholar
8 (a) Karpinsky, O. G.; Shelimova, L. E.; Kretova, M. A. J. Alloys Compd. 1998, 268, 112–117. (b) Karpinskii, O. G.; Shelimova, L. E.; Kretova, M. A. Inorg. Mater. 1998, 34, 225–232. (c) Karpinsky, O. G.; Shelimova, L. E.; Kretova M. A. J. Alloys Compd. 1998, 265, 170–175. (d) Caillat, T.; Fleurial, J. P.; Borshchevsky, A. J. Phys. Chem. Solids 1997, 58, 1119–1125.CrossRefGoogle Scholar
9 Chung, D. -Y.; Hogan, T.; Schindler, J.; lordanidis, L.; Brazis, P.; Kannewurf, C. R.; Chen, B.; Uher, C.; Kanatzidis, M. G. “Searching for New Thermoelectrics in Chemically and Structurally Complex Bismuth Chalcogenides” in Thermoelectric Materials - New Directions and Approaches, Tritt, T. M.; Kanatzidis, M. G.; Lyon, H. B.; Mahan, G. D. Ed., Mat. Res. Soc. Symp. Proc. 1997, 478, 333–344.CrossRefGoogle Scholar
10 Kanatzidis, M. G.; Sutorik, A. “The Application of Polychalcogenide Salts to the Exploratory Synthesis of Solid State Multinary Chalcogenides at Intermediate Temperatures”, Prog. Inorg. Chem. 1995, 43, 151–265.Google Scholar
11 CRC Handbook of Thermoelectrics; D. M., Rowe Ed., CRC Press, Inc.: Boca Raton, FL, 1995; references therein.Google Scholar
12 Kittel, C. Introduction to Solid State Physics, 6th Eds.; John Wiley & Sons, Inc.: New York, 1986; p 150.Google Scholar
13 Encyclopedia of Materials Science and Engineering, Thermoelectric Semiconductors; MIT Press: Cambridge, MA; Pergamon Press: Oxford, 1986; p 4968.Google Scholar
14 Sales, B. C. “Novel thermoelectric materials”, Curr. Opin. Solid St. Mater. 1997, 2, 284–289.CrossRefGoogle Scholar
15 (a) Nolas, G. S.; Cohn, J. L.; Slack, G. A.; Schujman, S. B. Appl. Phys. Lett. 1998, 73, 178–180. (b) Nolas G. S.; Slack, G. A.; Morelli, D. T.; Tritt, T. M.; Ehrlich, A. C. J. Appl. Phys. 1996, 79, 4002–4008.CrossRefGoogle Scholar
16 (a) Slack, G. A. “New Materials and Performance Limits for Thermoelectric Cooling” in CRC Handbook of Thermoelectrics, D. M., Rowe Ed., CRC Press, Inc.: Boca Raton, FL, 1995; p 407–440. (b) Slack, G. A., in Solid State Physics, Ehrenreich, H.; Seitz, F.; Turnbull, D. Ed., Academic Press, New York, 1997; vol.34, p 1.Google Scholar
17 Chung, D.-Y.; Hogan, T.; Schindler, J. L.; lordanidis, L.; Brazis, P. W.; Kannewurf, C. R.; Chen, B.; Uher, C.; Kanatzidis, M. G. “Complex Bismuth Chalcogenides as Thermoelectrics”, Proc. Inter. Conf. Thermoelect. 1997, Aug. (7th), pp. 459, Dresden, Germany.Google Scholar
18 Schindler, J. L.; Hogan, T. P.; Brazis, P. W.; Kannewurf, C. R.; Chung, D.-Y.; Kanatzidis, M. G. “Electrical Properties and Figures of Merit for New Chalcogenide-Based Thermoelectric Materials” in Thermoelectric Materials - New Directions and Approaches, Tritt, T. M.; Kanatzidis, M. G.; Lyon, H. B.; Mahan, G. D. Ed., Mat. Res. Soc. Symp. Proc. 1997, 478, 327–332.CrossRefGoogle Scholar
19 Brazis, P. W., Rocci, M., Chung, D.-Y., Kanatzidis, M. G., Kannewurf, C. R. “Transport Properties of Doped CsBi4Te6 Thermoelectric Materials”, see elsewhere in this volume.Google Scholar
20 Cordier, G.; SchAfer, H.; Schwidetzky, C. Rev. Chim. Miner., 1985, 22, 631–638 Google Scholar
21 Brown, S.; Chung, D.-Y.; Kanatzidis, M. G. work in progress.Google Scholar
22 Srikrishnan, T.; Nowacki, W. Z. Z. Kristallogr. 1974, 140, 114–136.CrossRefGoogle Scholar
23 Chen, B.; Uher, C.; Lordanidis, L.; Kanatzidis, M. G. Chem. Mater. 1997, 9, 1655–1658.CrossRefGoogle Scholar
24 Choi, K-S.; Chung, D. -Y.; Rocci, M.; Brazis, P.; Kannewurf, C. R.; Kanatzidis, M. G.; work in progress.Google Scholar
25 Choi, K. -S.; lordanidis, L.; Chondroudis, K.; Kanatzidis, M. G. Inorg. Chem. 1997, 36, 3804–3805.CrossRefGoogle Scholar
26 lordanidis, L.; Schindler, J. L.; Kannewurf, C. R.; Kanatzidis, M. G. J. Solid State Chem., in press.Google Scholar