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Study of Large Area a-Si:H and nc-Si:H Based Multijunction Solar Cells and Materials

Published online by Cambridge University Press:  01 February 2011

Xixiang Xu
Affiliation:
xxu@uni-solar.com, United Solar Ovonic, R&D, 1100 W. Maple Road, Troy, MI, 48084, United States, 248-519-5308, 248-362-4442
Baojie Yan
Affiliation:
byan@uni-solar.com, United Solar Ovonic LLC, 1100 West Maple Road, Troy, MI, 48084, United States
Dave Beglau
Affiliation:
dbeglau@uni-solar.com, United Solar Ovonic LLC, 1100 West Maple Road, Troy, MI, 48084, United States
Yang Li
Affiliation:
yli@uni-solar.com, United Solar Ovonic LLC, 1100 West Maple Road, Troy, MI, 48084, United States
Greg DeMaggio
Affiliation:
gdemaggio@uni-solar.com, United Solar Ovonic LLC, 1100 West Maple Road, Troy, MI, 48084, United States
Guozhen Yue
Affiliation:
gyue@uni-solar.com, United Solar Ovonic LLC, 1100 West Maple Road, Troy, MI, 48084, United States
Arindam Banerjee
Affiliation:
abanerjee@uni-solar.com, United Solar Ovonic LLC, 1100 West Maple Road, Troy, MI, 48084, United States
Jeff Yang
Affiliation:
jyang@uni-solar.com, United Solar Ovonic LLC, 1100 West Maple Road, Troy, MI, 48084, United States
Subhendu Guha
Affiliation:
sguha@uni-solar.com, United Solar Ovonic LLC, 1100 West Maple Road, Troy, MI, 48084, United States
Peter G. Hugger
Affiliation:
phugger@uoregon.edu, University of Oregon, Department of Physics, Eugene, OR, 97403, United States
J. David Cohen
Affiliation:
dcohen@uoregon.edu, University of Oregon, Department of Physics, Eugene, OR, 97403, United States
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Abstract

Solar cells based on hydrogenated nanocrystalline silicon (nc-Si:H) have demonstrated significant improvement in the last few years. From the standpoint of commercial viability, good quality nc-Si:H films must be deposited at a high rate. In this paper, we present the results of our investigations on obtaining high quality nc-Si:H and a-Si:H films and solar cells over large areas using high deposition rate. We have employed the modified very high frequency (MVHF) glow discharge technique to realize high-rate deposition. Modeling studies were conducted to attain good spatial uniformity of electric field over a large area (15”×1”) MVHF cathode for nc-Si:H deposition. A comparative study has been carried out between the RF and MVHF plasma deposited a-Si:H and nc-Si:H single-junction and a-Si:H/nc-Si:H double-junction solar cells. By optimizing the nc-Si:H cell and the tunnel/recombination junctions, we have obtained an initial aperture-area (460 cm2) efficiency of 11.9% for a-Si:H/nc-Si:H double-junction cells using conventional RF (13.56 MHz) plasma deposition. The deposition rate was 3 Å/sec. Results on solar cells made with MVHF will also be presented.

Type
Research Article
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

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