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Surface Absorption Below the Band Gap in a-Si:H Using Photoluminescence Absorption Spectroscopy
Published online by Cambridge University Press: 21 February 2011
Abstract
Photoluminescence absorption spectroscopy or PLAS has been used to measure the below gap absorption in a-Si:H at 77 K. As the absorption probed by this technique is composed of contributions from the bulk and the surfaces of the a-Si:H, we have developed an improved sample structure to separate these two contributions. Two kinds of interface have been investigated: a-Si1−xNx:H/a-Si:H and a-Si1−xOx:H/a-si:H. For the studies ofa-Si1−xNx:H/a-Si:H.x, two samples have been employed. The first sample consisted of an a-Si1−xNx:H/a-Si:H/a-Si:H/a-Si1−xNx:H/NiCr layered structure; the second one had a similar structure except that the a-Si:H layer was interrupted periodically by two thin (100 A°) a-Si1−xNx:H layers to increase the contribution of the interface absorption. A shoulder of the absorption around 1.2 eV for the second sample, which was not found in the first one, is probably due to the interfaces between a-Si:H and a-Si1−xNx:H. All samples were light-soaked using an Ar+ laser (5145 A°). The increases in the absorption measured by PLAS at 77 K are essentially the same as the results of PDS at 300 K, which suggests that the interfaces do not contribute to the light-induced absorption.
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- Copyright © Materials Research Society 1991