Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-25T20:26:54.818Z Has data issue: false hasContentIssue false

Surface Modification of Polymers, Paints and Composite Materials Used in the Low Earth Orbit Space Environment

Published online by Cambridge University Press:  01 February 2011

Jacob I. Kleiman*
Affiliation:
Integrity Testing Laboratory Inc. 80. Esna Park Drive, U#7–9, Markham, Ontario, L3R 2R7, Canada
Get access

Abstract

Many organic-based materials exposed to low Earth orbit (LEO) environment undergo dramatic changes and irreversible degradation of physical characteristics. While many protective schemes are used to reduce the effects of LEO environment, protection of such materials in LEO still remains a major challenge, especially for future long duration missions or space stations.

In addition to the traditional protective coating approaches, surface modification processes were proposed and successfully used as an approach to protect polymers, thermal control paints and other components and structures from LEO environment. Among them two surface modification processes, the Photosil™ and the Implantox™ that used new approaches in silicon functionalization, as in the Photosil™, and a modified ion implantation process, as in the Implantox™ allowed to incorporate up to 36 at.% of Si into the upper surface layer regions of the treated polymers, composite materials, thermal control paints and other high-performance organic materials.

The tests conducted in plasma and fast atomic oxygen (FAO) beam facilities at comparable to LEO fluencies (∼ (1–2)·1020 at.O/cm2 ) demonstrated erosion yields lower than −10−26 cm3at, unchanged thermal optical properties, where important, and excellent thermal match between the treated layers and the bulk of the treated materials. After FAO testing, the Implantox™ treated samples were clear and transparent, with a glassy-like shiny surface with no signs of any surface erosion.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Tennyson, R.C., in “The Behaviour of Systems in the Space Environment,” DeWitt, R.N. et al., Eds., Kluwer Acad. Publ., (1993). p.233.Google Scholar
2. Banks, B.A., “LDEF Materials Data Analysis Workshop,” compiled by Stein, B.A. and Young, Ph. R., NASA CP 10046, (1990), p.191.Google Scholar
3. Tennyson, R.C., Canadian J. Phys., 69, (1991), p. 1190.Google Scholar
4. Cross, J.B., Koontz, S.L., Gregory, J.C., and Edgell, M.J., in “Materials Degradation in Low Earth Orbit (LEO),” Srinivasan, V. and Banks, B.A., Eds., TMS Minerals, Metals and Materials, Warrendale, PA (1990), p. 1.Google Scholar
5. Iskanderova, Z.A., Gudimenko, Yu. I., Kleiman, J. and Tennyson, R.C., Spacecraft, J. Rockets, 32, 5, (1995), pp. 878884.Google Scholar
6. Koontz, S.L., Leger, L.J., Albin, K., and Cross, J., Spacecraft, J. Rockets, 27, (1990), p. 346.Google Scholar
7. Minton, T, K., Seale, J.W., Garton, D.J. and Frandsen, A.K., “Dynamics of Atomic-oxygen Degradation of Materials”. In Proceedings of ICPMSE-4, “Protection of Space Materials from Space Environment”, Toronto, May 1–3, 2002, Kluwer Academic Publishers, Space Technology Proceedings, v.4, eds. Kleiman, J.I. and Tennyson, R.C., (2001), pp. 1531.Google Scholar
8. Pascual, R.Z., Schatz, G.C. and Garton, D.J., “A Direct Trjectory Dymnamics Investigation of Fast O+ Alkane Reactions”, In Proceedings of ICPMSE-6, “Protection of Materials and Structures from the Space Environment”, Toronto, April 23–24, 1998, Kluwer Academic Publishers, Space Technology Proceedings, v.5, eds. Kleiman, J.I. and Iskanderova, Z.I., (2003), pp. 537541.Google Scholar
9. Zimcik, D. G., Wertheimer, M. R., Balmain, K. B. and Tennyson, R. C., J. Spacecraft and Rockets, vol. 28, No.6, (1991), pp. 652657.Google Scholar
10. Kleiman, J., “Surface Modification of Polymers Used in the Low Earth Orbit Space Environment”, in Metallized Plastics 5/6, Fundamental and Applied Science, ed. Mittal, K., (1998) pp. 331351.Google Scholar
11. Freeland, A., Fink, J., Meinke, G., Grieser, J., and Takeo, H., Proceedings of International Forum “Protection of Materials and Surface Finishes from the Low Earth Orbit Environment,” Toronto, (February 1992) (unpublished, available from Kleiman, J., ).Google Scholar
12. Silverman, E.M., Space Environmental Effects on Spacecraft: LEO Materials Selection Guide, NASA CR 4661, part 1, 810 (1995).Google Scholar
13. Petraitis, D., CSRU/NASA Materials on Space Meeting, Cleveland, Ohio, May 25, 1993.Google Scholar
14. Banks, B.A., Mirtich, M.J., Rutledge, S.K., and Nahra, H.K., AIAA Paper 85–0420, (1985).Google Scholar
15. Reddy, M.R., “Review: Effects of Low Earth Orbit Atomic Oxygen on Spacecraft Materials”, J. of Mat. Sci., vol.30, (1995), pp. 281307.Google Scholar
16. Rutledge, S.K., Cooper, J.M., and Olle, R.M., The Effect of Atomic Oxygen on Polysiloxane-Polyimide for Spacecraft Applications in Low Earth Orbit, NASA CP-3103, Pt.2, 755762 (1991).Google Scholar
17. Connell, J.W., Polyimides Containing Pendent Siloxane Group, NASA CP-3136, Vol. 1, (1991), pp.330338.Google Scholar
18. Oldham, S.L., “Proceedings of the EOIM-3 BMDO Experiment Workshop”, June 22–23, Arcadia, California, (1993).Google Scholar
19. Dever, J.A., Bruckner, E.J., and Rodriguez, E., AIAA paper 92–0794, 19 (1992).Google Scholar
20. Gonzalez, Rene I., Tomczak, Sandra J., Minton, Timothy K., Brunsvold, Amy L. and Hoflund, Gar B., “Synthesis and Atomic Oxygen Erosion Testing of Space-survivable POSS (Polyhedral Oligomeric Silsesquioxane) Polyimldes“, in: Proceedings of the 9th International Symposium on Materials in a Space Environment, Noordwijk, The Netherlands, 16–20 June 2003 (ESA SP-540, September 2003), pp.113120.Google Scholar
21. Gudimenko, Yu., Kleiman, J. I., Iskanderova, Z.A., Tennyson, R.C., Cool, G.R., U.S. Patent #5, 948, 484, issued September 7, 1999.Google Scholar
22. Iskanderova, Z.A., Kleiman, J.I., Gudimenko, Y., Morison, D., and Tennyson, R.C., “Surface Modification of Polymer-bsed Materials by Ion Implantation: A new Approach for Protection in LEO”, in Proceedings of ICPMSE-3, “Protection of Materials and Structures from the LEO Space Environment”, Toronto, 25–26 April, 1996, Kluwer Academic Publishers, Space Technology Proceedings, v.2, eds. Kleiman, J.I. and Tennyson, R.C., (1999), pp. 225234.Google Scholar
23. Iskanderova, Z.A., Kleiman, J.I., Gudimenko, Y., Tennyson, R.C., and Cool, G., US Patent #5683757, issued 11 April, 1997.Google Scholar
24. Gudimenko, Yu., Ng, R., Kleiman, J., Iskanderova, Z., Milligan, D., Tennyson, R. C. and Hughes, P. C., J. of Spacecraft and Rockets, Vol. 41, No.3, May-June 2004 pp. 326334.Google Scholar
25. Kleiman, J.I., Iskanderova, Z.A., Gudimenko, Y.I., Morison, W.D., and Tennyson, R.C., Canadian Aeronautic and Space Journal, v.45, No.2, (June 1999), pp. 148160.Google Scholar
26. Gudimenko, Y., Ng, R., Kleiman, J.I., Iskanderova, Z. A., Tennyson, R.C., Hughes, P.C., Milligan, D., Grigorevski, A., Shuiski, M., Kiseleva, L., Edwards, D., Finckenor, M., “Enhancement of Surface Durability of Space Materials and Structures in LEO Environment”, in: Proceedings of the 9th International Symposium on Materials in a Space Environment, Noordwijk, The Netherlands. 16–20 June 2003 (ESA SP-540. September 2003), pp. 95106.Google Scholar
27. Iskanderova, Z., Kleiman, J., Mojazza, B., Sotto, M., “Erosion Protection and Surface Conductivity Enhancement of TOR Polymers by Implantox™ Technology” in” Proceedings of the 9th International Symposium on Materials in a Space Environment, Noordwijk, The Netherlands. 16–20 June 2003 (ESA SP-540. September 2003, pp. 473478.Google Scholar
28. Coopmans, F. and Roland, B., SPIE Proc. 631, (1986), pp. 3436.Google Scholar
29. Strobel, M., Lyons, C.S. and Mittal, K.L., editors, “Plasma Surface Modification of Polymers: Relevance to Adhesion,” VSP, Utrecht, The Netherlands, (1994).Google Scholar
30. Hubler, G.K. et al., Eds., “Ion Implantation and Ion Beam Processing of Materials,” Mater. Res. Soc. Symp. Proc, vol.27, North Holland, (1984).Google Scholar