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Synthesis of Ceramics/Polymer Nanocomposites Protonic Conducting Membrane

Published online by Cambridge University Press:  10 February 2011

I. Honma
Affiliation:
Energy Division, ElectrotechnicalLaboratory, AIST, Tsukuba, Ibaraki, 305-8568, Japan, (tel: +81-298-54-5797, fax: +81-298-54-5805, e-mail: ihonma@etl.go.jp)
S. Hirakawa
Affiliation:
Tokyo University of Agriculture and Technology, Koganei, Tokyo, Japan
J.M. Bae
Affiliation:
New Energy and Industrial Technology Development Organization (NEDO), Japan
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Abstract

High temperature protonic conducting polymer membrane provides new technological applications in the electrochemical devices including electrochromic displays, chemical sensors, fuel cells and others. Organic/inorganiaianocomposites membrane consists of SiO2/PEO (Polyethylene Oxides) hybrid are remarkable family of isotropic, amorphous polymer materials, which has been synthesized through sol-gel processes. The hybrid membrane doped with acidic surfactant molecules shows good protonic conductivities at high temperatures above 100C. The membrane was found to be thermally stable at high temperatures because of the inorganic SiO2 framework in the composites matrix.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

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References

REFERENCES

1. Kreuer, K.D., Solid State Ionics, 97, 1 (1997).Google Scholar
2. Scherban, T. and Nowick, A.S., Solid State Ionics, 35, 189 (1989).Google Scholar
3. Gupta, B., Buchi, F.N. and Scherer, G.G., Solid State Ionics, 61, 213 (1993).Google Scholar
4. Nouel, M. and Fedkin, P.S., Electrochimica Acta, 43, 2381 (1998).Google Scholar
5. Ponomareva, V.G. and Lavrova, G.V., Solid State Ionics, 106, 137 (1998).Google Scholar
6. Kobayashi, T., Rikukawa, M., Sanui, K. and Ogata, N., Solid State Ionics, 106, 219 (1998).Google Scholar
7. Scherer, G.G., Solid State Ionics, 94, 249 (1997).Google Scholar
8. Giordano, N., Staiti, P., Hocevar, S. and Arico, A.S., Electrochimica Acta, 41, 397 (1996).Google Scholar
9. Popall, M. and Durand, H., Electrochimica Acta, 37, 1593 (1992).Google Scholar
10. Sanchez, J-Y., Denoyelle, A. and Poinsignon, C., Polymers for Adv. Technologies, 4, 99 (1993).Google Scholar