Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-25T19:33:43.386Z Has data issue: false hasContentIssue false

Synthesis of Transition-Metal-Oxides Meso-Structured Thin Films

Published online by Cambridge University Press:  15 February 2011

H.S. Zhou
Affiliation:
Energy Division, Electrotechnical Laboratory (ETL), Umezono, Tsukuba, Ibaraki 305, JapanE-mail: hszhou@etlrips.etl.go.jp
I. Honma
Affiliation:
Energy Division, Electrotechnical Laboratory (ETL), Umezono, Tsukuba, Ibaraki 305, JapanE-mail: hszhou@etlrips.etl.go.jp
Get access

Abstract

Highly ordered self-assembly organized silica meso-structured architectures have attracted increasing attention because these materials provide a rich source for scientific research and technological applications. This approach to meso-structured materials has been extended to non-silica oxides, especially transition-metal-oxides which might promise applications involving electron transfer or magnetic interactions. We report the syntheses of transition-metal-oxides meso-structured thin films (MSTF), such as TiO2, V2O5, Fe2O3 and Nb2O5, using a surfactant templating processing with spin coating method. X-ray diffraction patterns of the films showed that the films generally oriented in a lamellar structure. The phase transferring in V205 MSTF was also investigated.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Kresge, C.T., Leonowicz, M.E., Vartuli, J.C., and Beck, J.S., Nature, 1992, 359, 710.Google Scholar
2. Beck, J.S., Vartuli, J.C., Roth, W.J., Leonowicz, M.E., Kresge, C.T., Schmitt, K.D., Chu, C.T-W., Olson, D.H., Sheppard, E.W., McCullen, S.B., Higgins, J.B. and Schlenker, J.L., J. Am. Chem. Soc., 1992, 114, 10834.Google Scholar
3. Wu, Chun-Guey and Bein, Thomas, Science, 1994, 264, 1757,Google Scholar
4. Ogawa, M., J. Amer. Chem. Soc. 1994, 116, 7941.Google Scholar
5. Yang, H., Kuperman, A., Coombs, N., Mamiche-Afra, S., Ozin, A, Nature, 1996, 379, 703 Google Scholar
6. Aksay, I.A., Trau, M., Manne, S., Honma, I., Yao, N., Zhou, L., Fenter, P., Eisenberger, P.M. and Gruner, S.M., Science, 1996, 273, 892.Google Scholar
7. Trau, M., Yao, N., Kim, E., Xia, Y., Whitesides, G.M. and Aksay, I.A., Nature, 1997, 390, 674.Google Scholar
8. Honma, I., Zhou, H.S., Kundu, D., submitted Langmuir.Google Scholar
9. Luca, V., MacLachlan, D.J., Hook, J.M., Withers, Ray, Chem. Mater. 1995, 7, 2220.Google Scholar
10. Luca, V., Hook, J.M., Chem. Mater. 1997, 9, 2731.Google Scholar
11. Antonelli, D.M., Ying, J.Y., Angew. Chem. Int. Ed. Engl. 1995, 34, 2014.Google Scholar
12. Putnam, R.L., nakagawa, N., McGrath, K.M., Yao, N., Aksay, I.A., Gruner, S.M., Navrotsky, A., Chem. Mater. 1997, 9, 2690.Google Scholar
13. Zhou, H.S., Honma, I., in preparation.Google Scholar
14. Tolbert, S.H., Sieger, P., Stucky, G.D., Aubin, S.M.J., Wu, C.C., Hendrickson, D.N., J. Am. Chem. Soc. 1997, 119, 8652.Google Scholar
15. Antonelli, D.M., Ying, J.Y., Chem. Int. Ed. Engl. 1996, 35, 426.Google Scholar
16. Kundu, D., Zhou, H.S., Honma, I., J. Mater. Sci. Lett. in press.Google Scholar
17. Misawa, T., Hashimoto, K., Shimodaira, S., Corrosion Sci. 1974, 14, 131 Google Scholar
18. Yang, P., Zhao, D., Margolese, D., Chmelka, B.F., Stucky, G.D., Nature, 396, 152 Google Scholar