Hostname: page-component-cd9895bd7-q99xh Total loading time: 0 Render date: 2024-12-27T18:50:36.221Z Has data issue: false hasContentIssue false
  • English
  • Français

Theory of Spinodal Decomposition in Very Viscous Binary Liquid Mixtures

Published online by Cambridge University Press:  16 February 2011

Josef Jäckle  and
M. Pieroth
Josef Jäckle
Affiliation:
University of Konstanz, Fakultät für Physik, D-7750 Konstanz, Germany
M. Pieroth
Affiliation:
University of Konstanz, Fakultät für Physik, D-7750 Konstanz, Germany
Get access

Abstract

We have developed a theory for the evolution of concentration fluctuations after a temperature quench which takes the effect of slow structural relaxation into account. In its linear and non-linear forms, it generalizes the theories of Cahn, Hilliard and Cook, and of Langer, Bar-on and Miller.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 215: Symposium R2 – Structure, Relaxation and Physical Aging of Glassy Polymers , 1990 , 49
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Pieroth, M., doctoral diss., University of Konstanz, 1990.Google Scholar
[2] Gunton, J.D., San Miguel, M., and Sahni, P., in Phase Transitions and Critical Phenomena Vol.8, edited by C., Domb and J.L., Lebowitz (Academic, New York, 1983), p. 267.Google Scholar
[3] Binder, K., in Materials Science and Technology Vol.5, edited by P., Haasen (VCH-Verlagsges., Weinheim, 1990).Google Scholar
[4] Komura, S, Phase Transitions 12, 3 (1988).CrossRefGoogle Scholar
[5] Jäckle, J. and Frisch, H.L., J. Polym. Sci., Polym. Phys. Edn. 23, 675 (1985); J. Chem. Phys. 85, 1621 (1986).CrossRefGoogle Scholar
[6] Durning, C.J., J. Polym. Sci., Polym. Phys. Edn. 23, 1831 (1985).CrossRefGoogle Scholar
[7] Binder, K., Frisch, H.L., and Jäckle, J., J. Chem. Phys. 85, 1505 (1986).CrossRefGoogle Scholar
[8] Kishimoto, A., Fujita, H., Odani, H., Kurata, M., and Tamura, M., J. Phys. Chem. 64, 594 (1960).CrossRefGoogle Scholar
[9] Crank, J., The Mathematics of Diffusion 2nd edn. (Clarendon, Oxford, 1975).Google Scholar
[10] Cook, H.E., Acta Metall. 18, 297 (1970).CrossRefGoogle Scholar
[11] Langer, J. S., Bar-on, M., and Miller, H.D., Phys. Rev. A 11, 1417 (1975).CrossRefGoogle Scholar
[12] Jäckle, J. and Pieroth, M., J. Phys.: Condens. Matter 2, 4963 (1990).Google Scholar
[13] Jäckle, J. and Pieroth, M., Z. Phys. 72, 25 (1988).CrossRefGoogle Scholar
[14] Strobl, G.R., Macromolecules 18, 558 (1985).CrossRefGoogle Scholar
[15] Schwahn, D., Hahn, K., Streib, J., and Springer, T. Google Scholar
[16] Pieroth, M. and Jäckle, J., to be publ.Google Scholar