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Formation of Continuous Cubic Mesoporous Films by Spin Casting

Published online by Cambridge University Press:  10 February 2011

I. Honma ,
H.S. Zhou  and
D. Kundu
I. Honma
Affiliation:
Energy division, Electrotechnical laboratory, AIST, Umezono 1-1-4, Tsukuba, Ibaraki, 305, Japan, e9513@etl.go.jp, tel:+81-298-54-5797, fax:+81-298-54-5805
H.S. Zhou
Affiliation:
Energy division, Electrotechnical laboratory, AIST, Umezono 1-1-4, Tsukuba, Ibaraki, 305, Japan, e9513@etl.go.jp, tel:+81-298-54-5797, fax:+81-298-54-5805
D. Kundu
Affiliation:
Sol-Gel Division, Central Glass and Ceramic Research Institute, Calcutta, India
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Abstract

The simple spin casting technique has been successfully used for producing mesoporous thin films on glass substrate. The films are found to be homogeneous and continuous in a large size scale, however, the mesostructural phase of the film has been controlled systematically among amorphous (A), one-dimensional hexagonal (1-dH), cubic (C) and Lamellae (L) by increasing surfactant to TEOS concentration ratio in the casting solution. The 1-dH as well as cubic structure is thermally stable after the calcination so that a mesoporous thin film is obtained by surfactant removal. The solution additives of 1-propanol and 2-butanol might play a roll in the direct formation of the primitive cubic phase in the film form which has never been obtained.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 109
Copyright
Copyright © Materials Research Society 1998

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