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Formation, Structure, and Material Properties From the Reaction Product of M(OCHMe2)4 (M=Ti, Zr) And HOAc

Published online by Cambridge University Press:  21 February 2011

Todd M. Alam ,
Timothy J. Boyle ,
Catherine D. Buchheit ,
Robert W. Schwartz  and
Joseph W. Ziller
Todd M. Alam
Affiliation:
Dept. of Chem., U. of N.M., Albuquerque, NM Sandia National Laboratories, The Advanced Materials Laboratory, Albuquerque, NM
Timothy J. Boyle
Affiliation:
Dept. of Chem., U. of N.M., Albuquerque, NM
Catherine D. Buchheit
Affiliation:
Dept. of Chem., U. of N.M., Albuquerque, NM
Robert W. Schwartz
Affiliation:
Dept. of Chem., U. of N.M., Albuquerque, NM
Joseph W. Ziller
Affiliation:
Dept. of Chem., U. of N.M., Albuquerque, NM Dept. of Chem. U.C.‐Irvine, Irvine, CA
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Abstract

In attempt to ultimately control the characteristics of the PZT films, we have decided to investigate some of the basic chemistry associated with these solutions. Frequently, these solutions have been generated from Group IV metal alkoxides in acetic acid (HOAc). Therefore, studies of the simple reactivity between M(OCHMe2)4 (M = Ti, Zr) and HOAc have been undertaken. These reactions were monitored by 1H, 13C, 17O NMR, FT-IR, TGA/DTA, and single crystal X‐ray studies. Films were produced from spin‐coat deposition of crystalline material (from the titanium reaction) in toluene and aged solutions as well.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 346: Symposium N – Better Ceramics Through Chemistry VI , 1994 , 35
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

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