Hostname: page-component-78c5997874-94fs2 Total loading time: 0 Render date: 2024-11-10T18:16:44.544Z Has data issue: false hasContentIssue false
  • English
  • Français

High Level Radioactive Waste Glass Production and Product Description

Published online by Cambridge University Press:  25 February 2011

James F. Sproull ,
Sharon L. Marra  and
Carol M. Jantzen
James F. Sproull
Affiliation:
Westinghouse Savannah River Co., P.O. Box 616, Aiken, SC 29803
Sharon L. Marra
Affiliation:
Westinghouse Savannah River Co., P.O. Box 616, Aiken, SC 29803
Carol M. Jantzen
Affiliation:
Westinghouse Savannah River Co., P.O. Box 616, Aiken, SC 29803
Get access

Abstract

A summary of the current state of defense high-level radioactive waste in the U.S. is presented. Reasons for the selection of borosilicate glass as the matrix for the waste glass product over other glasses is enunciated. The product and processing requirements which the waste glass must meet are summarized. Finally the effects of crystallization and glass-in-glass phase separation on waste glass durability are discussed. Crystallization, under typical cooling conditions, has minimal effect on durability but glass-in-glass phase separation should be avoided.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 333: Symposium V – Scientific Basis for Nuclear Waste Management XVII , 1993 , 15
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Wicks, G.C. and Bickford, D.F., Savannah River Laboratory Report DP-1777 (1989).Google Scholar
2 Integrated Data Base for 1991: U.S. Spent Fuel and Radioactive Waste Inventories, Projections, and Characteristics, U.S. Dept. of Energy Report DOE/RW-006, Rev. 7 (1991).Google Scholar
3 Baxter, R.G., Defense Waste Processing Facility Wasteform and Canister Description, E.I. duPont de Nemours & Co. Report DP-1606, Rev. 2 (1988).Google Scholar
4 White, J.M. and LaHaie, G., Atomic Energy of Canada Ltd. Report CRCE-591 (1955).Google Scholar
5 Jantzen, C.M., J. Non-Cryst. Solids, 84, 215–225 (1984).CrossRefGoogle Scholar
6 Plodinec, M.J., Proc. Symp. on High Temp. Materials Chem., The Electrochem. Soc., 201–209 (1982).Google Scholar
7 Plodinec, M.J., Savannah River Report DPST-86-213m (1986).Google Scholar
8 Ramsey, W.G. and Schumacher, R.F., Westinghouse Savannah River Report WSRC-TR-92-484 (1992).Google Scholar
9 Waste Acceptance System Requirements Document, United States Department of Energy, DOE/RW-0351P, January (1993).Google Scholar
10 Waste Acceptance Product Specifications for Vitrified High-Level Waste Forms, U.S. Dept. of Energy, EM-WAPS, Rev. 0, February, (1993).Google Scholar
11 Jantzen, C.M., Bibler, N.E., Beam, D.C., Ramsey, W.G., and Waters, B.J., Westinghouse Savannah River Co. Report WSRC-TR-90-539, January (1992).Google Scholar
12 Jantzen, C.M., Nuc. Waste Mgt. IV, Ceram. Trans., 23, 37–51 (1992).Google Scholar
13 Jantzen, C.M., Bickford, D.F., and Karraker, D.G., Adv. Ceram. 8, 30–38 (1984).Google Scholar
14 Manara, A., Lanza, F., Ceccone, G., Delia Mea, G., and Salvagno, G., (Mater. Res. Soc. Proc. 44, Pittsburgh, PA, 1985), pp. 63–72.Google Scholar
15 Feng, X., Pegg, I.L., Saad, E., Cucinell, S., and Barkatt, A., Ceram. Trans. 9, 165–174 (1989).Google Scholar
16 Turcotte, R.P., Wald, J.W. and May, R.P., Sci. Basis for Nuc. Waste Mat. II. (Plenum Press, New York, 1979), pp. 141–146.Google Scholar
17 Robnett, B.M. and Wicks, G.G., Savannah River Laboratory Report DP-MS-81-60 (1981).Google Scholar
18 Bickford, D.F. and Jantzen, C.M., Mat. Res. Soc. Symp. Proc. 26, 557–566 (1984).CrossRefGoogle Scholar
19 Montrose, C.J., Barkatt, Aa., and Macedo, P.B., Mat. Res. Soc. Symp. Proc. 26, 741–754 (1984).Google Scholar
20 Jantzen, C.M. and Bickford, D.F., Mat. Res. Soc. Symp. Proc. 44, 135–146 (1985).Google Scholar
21 Buechele, A.C., Feng, X., Gu, H., and Pegg, I.L., Mat. Res. Soc. Symp. Proc. 176, 393–402 (1990).Google Scholar
22 Buechele, A.C., Feng, X., Gu, H., Muller, I.S., Wagner, W., and Pegg, I.L., (Mater. Res. Soc. Proc. 212, 1991), pp. 141–152.CrossRefGoogle Scholar
23 Buechele, A.C., Feng, X., Gu, H., and Pegg, I.L., Ceram. Trans. 23, 85–94 (1991).Google Scholar
24 Buechele, A.C., Feng, X., Gu, H., and Pegg, I.L., Nucl. Waste Mgt. IV, 85–94 (1991).Google Scholar
25 Palmiter, T.V., Joseph, I., and Pye, L.D., (Mater. Res. Soc. Proc. 212, 1991), pp. 153–158.Google Scholar
26 Marra, S.L., Edwards, R.E., and Jantzen, C.M., High Level Rad. Waste Mgt. Conf. 1, Las Vegas, NV, 917-924 (1992).Google Scholar
27 Marra, S.L. and Jantzen, C.M., Westinghouse Savannah River Co. Report WSRC-TR-92-142 (1992).Google Scholar
28 Hench, L.L., Werme, L., and Lodding, A., Sci. Basis for Nucl. Waste Mgt. V, 153–162 (1982).Google Scholar
29 Bickford, D.F. and Jantzen, C.M., J. Non-Crys. Sol., 84, 509–518 (1987).Google Scholar
30 Wald, J.W. and Westik, J.H., in Ceramics in Nucl. Waste Mgt., Pacific Northwest Laboratory Report CONF-790420 (1979).Google Scholar
31 Jain, V.J. and Barnes, S.M., Ceram. Trans. 23, 251–257 (1991).Google Scholar
32 Turner, W. and Winks, F., J. Glass Tech., 10, 102 (1926).Google Scholar
33 Nordberg, M.E. and Hood, H.P., U.S. Patent 2, 106, 744 (1934).Google Scholar
34 Howell, B.F., Simmons, J.H., and Haller, W., Ceram. Bull. 54 (8), 707–709 (1975).Google Scholar
35 Tomozawa, M., in Treatise on Materials Science and Technology, Vol.12, (Academic Press, New York, 1977), p. 283.Google Scholar
36 Takamori, T. and Tomozawa, M., J. Am. Ceram. Soc. 61 (11–12), 509–512 (1978).Google Scholar
37 Jantzen, C.M. and Schumacher, R.F., “Glass Phase Separation; Implications for Waste Glass Durability Modeling, Am. Ceram. Soc. National Meeting, Spring, Cincinnati, OH (1993) .Google Scholar
38 Tomozawa, M. and Obara, R., J. Am. Ceram. Soc. 56 (7), 378 (1980).CrossRefGoogle Scholar
39 Uhlmann, D.R. and Kreidl, N.J., Glass: Science and Technology, Vol. 1 Glass-Forming Systems, (Academic Press, 1983), p. 176.Google Scholar
40 Voldan, J., XIth International Congress on Glass, Vol. II, 57 (1977) .Google Scholar
41 Piepel, G.F., Hrma, P.R., Bates, S.O., Schweiger, M.J., and Smith, D.E., First-Order Study of Property/Composition Relationships for Hanford Waste Vitrification Plant Glasses, Rev. 0, Pacific Northwest Laboratory, Richland, WA, May (1991).Google Scholar
42 Hrma, P.R. and Piepel, G.F., Property/Composition Relationships for Hanford Waste Vitrification Plant Glasses-Preliminary Results Through CVS-II Phase 2, Pacific Northwest Laboratory, Richland, WA, p 12.45, Sept. (1992).Google Scholar
43 Engell, J.E. and Roed, G., Mat. Res. Soc. Proc. 6, 609–617 609–617 (1982).Google Scholar