Hostname: page-component-cd9895bd7-8ctnn Total loading time: 0 Render date: 2024-12-22T05:34:20.954Z Has data issue: false hasContentIssue false

Interface Properties Between SrTiO3 Thin Films and Electrodes

Published online by Cambridge University Press:  10 February 2011

A. M. Clark
Affiliation:
Department of Physics, The Pennsylvania State University, University Park, PA 16802
Jianhua Hao
Affiliation:
Department of Physics, The Pennsylvania State University, University Park, PA 16802
Weidong Si
Affiliation:
Department of Physics, The Pennsylvania State University, University Park, PA 16802
X. X. Xi
Affiliation:
Department of Physics, The Pennsylvania State University, University Park, PA 16802
Get access

Abstract

SrTiO3 (STO) thin films were grown by pulsed laser deposition on single crystal STO substrates with a SrRuO3 buffer layer, which also serves as a bottom electrode. Measurements of the low frequency dielectric properties were performed in a parallel plate capacitor configuration for a range of temperatures using different top electrode materials. The contribution to the interfacial potential from Schottky barriers was investigated. In comparison to STO single crystals, thin films have continued dielectric non-linearity above T ∼ 70 K. This complicates conventional Schottky barrier height measurements using C-V curves because both Schottky barriers and dielectric non-linearity result in a decrease in dielectric constant under applied electric fields. However, by using I-V data, difficulties related to field dependence of the dielectric constant may be removed. Barrier height measurements for both metal and oxide electrodes were performed for T > 70 K. Calculated barrier heights from a modified Schottky equation were very low for an oxide electrode, and an order of magnitude higher for a normal metal electrode.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Findikoglu, A. T., Jia, Q. X., Wu, X. D., Chen, G. J., Venkatesan, T., and Reagor, D.. Tunable and adaptive bandpass filter using a nonlinear dielectric thin film of SrTiO3 . Appl. Phys. Lett., 68:1651, 1996.Google Scholar
[2] Dalberth, M. J., Stauber, R. E., Price, J. C., Rogers, C. T., and Galt, David. Improved low frequency and microwave dielectric response in strontium titanate thin films grown by pulsed laser ablation. Appl. Phys. Lett., 72:507, 1998.Google Scholar
[3] Chang, H., Gao, C., Takeuchi, I., Yoo, Y., Wang, J., Schultz, P. G., Xiang, X.-D., Sharma, R. P., Downes, M., and Venkatesan, T.. Combinatorial synthesis and high throughput evaluation of ferroelectric/dielectric thin-film libraries for microwave applications. Appl. Phys. Lett., 72:2185, 1998.Google Scholar
[4] Viana, R., Lunkenheimer, P., Hemberger, J., Böhmer, R. and Loidl, A.. Electric-fielddependent dielectric constant and nonlinear susceptibility in SrTiO3 Phys. Rev. B, 52:601, 1997.Google Scholar
[5] Li, Hong Cheng. Si, Weidong, West, Alexander D., and Xi, X. X.. Near single crystal-level dielectric loss and tunability in pulsed laser deposited SrTiO3 thin films Appl. Phys. Lett., 73:190, 1998.Google Scholar
[6] Li, Hong Cheng. Si, Weidong, West, Alexander D., and Xi, X. X.. Thickness dependence of dielectric loss in SrTiO3 thin films Appl. Phys. Lett. 73:464, 1998.Google Scholar
[7] Zhou, C. and Newns, D. M.. Intrinsic dead layer effect and the performance of ferroelectric thin films capacitors J. Appl. Phys., 82:3081, 1997.Google Scholar
[8] Zafar, S., Jones, R. E., Jang, B., White, B., Kaushik, V., and Gillespie, S.. The electronic conduction mechansim in barium strontium titanate thin films Appl. Phys. Lett., 73:3533, 1998.Google Scholar
[9] Dietz, G. W.. and Waser, R.. Charge injection in SrTiO3 thin films. Thin Solid Films 229:53, 1997.Google Scholar
[10] Dietz, G. W., Schumacher, M., and Waser, R.. Leakage currents inBa0.7Sr0.3TiO3 thin films for ultrahigh-density dynamic random access memories. J. Appl. Phys., 82:2359, 1997.Google Scholar