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Molecular Design of Carboxylic Precursors for Zirconia

Published online by Cambridge University Press:  25 February 2011

Allen W. Apblett ,
Jin Lei  and
Galina D. Georgeva
Allen W. Apblett
Affiliation:
Tulane University, Department of Chemistry, New Orleans, LA 70118
Jin Lei
Affiliation:
Tulane University, Department of Chemistry, New Orleans, LA 70118
Galina D. Georgeva
Affiliation:
Tulane University, Department of Chemistry, New Orleans, LA 70118
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Abstract

Several carboxylic acid derivatives of zirconium were investigated for their potential utility as precursors for zirconia fibers and thin films. The reactions of ZrOCl2· 8H2O and ZrCl4 with succinic acid, oxalic acid, maleic acid, benzene tetracarboxylic acid, 2-hydroxyiminopropionic acid, 3-hydroxybutyric acid, and β-alanine were performed and the thermal behavior of the products was investigated by thermal gravimetric analysis. The objective was to find preceramic compounds with low pyrolysis temperatures and physical properties suitable for materials processing.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 271: Symposium N – Better Ceramics Through Chemistry V , 1992 , 77
Copyright
Copyright © Materials Research Society 1992

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References

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