Hostname: page-component-f554764f5-68cz6 Total loading time: 0 Render date: 2025-04-10T20:21:52.663Z Has data issue: false hasContentIssue false
  • English
  • Français

Molecular Design of Carboxylic Precursors for Zirconia

Published online by Cambridge University Press:  25 February 2011

Allen W. Apblett ,
Jin Lei  and
Galina D. Georgeva
Allen W. Apblett
Affiliation:
Tulane University, Department of Chemistry, New Orleans, LA 70118
Jin Lei
Affiliation:
Tulane University, Department of Chemistry, New Orleans, LA 70118
Galina D. Georgeva
Affiliation:
Tulane University, Department of Chemistry, New Orleans, LA 70118
Get access

Abstract

Several carboxylic acid derivatives of zirconium were investigated for their potential utility as precursors for zirconia fibers and thin films. The reactions of ZrOCl2· 8H2O and ZrCl4 with succinic acid, oxalic acid, maleic acid, benzene tetracarboxylic acid, 2-hydroxyiminopropionic acid, 3-hydroxybutyric acid, and β-alanine were performed and the thermal behavior of the products was investigated by thermal gravimetric analysis. The objective was to find preceramic compounds with low pyrolysis temperatures and physical properties suitable for materials processing.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 271: Symposium N – Better Ceramics Through Chemistry V , 1992 , 77
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1. Sanchez, C., Livage, J., Henry, M., and Babonneau, F., J. Non-cryst Solids, 100, 65 (1988)Google Scholar
2. Doeuff, S., Henry, M., Sanchez, C., and Livage, J., J. Non-cryst Solids, 89, 206 (1987)Google Scholar
3. Mantese, J. V., Micheli, A. L., Hamdi, A. H., and Vest, R. W., M.R.S. Bull, 1989 (XIV), 1173.Google Scholar
4. Xu, J. J., Shaikh, A. S., and Vest, R. W., IEEE Trans UFFC 36, 307 (1989).Google Scholar
5. Xu, J. J., Shaikh, A. S., and Vest, R. W., Thin Solid Films 161, 273 (1988).Google Scholar
6. Maruyama, T. and Kitamura, K., Jpn. J. Appl. Phys. 28, L312 (1989).Google Scholar
7. Hamdi, A. H., Mantese, J. V., Micheli, A. L., Laugal, R.C.O., Dungan, D.F., Zhang, Z. H., and Padmanabhan, K. R., Appl. Phys. Lett. 51, 2152 (1987).Google Scholar
8. Hebert, V., His, C., Guille, J., and Vilminot, S., J. Mat. Sci. 26, 5184 (1991).Google Scholar
9. Miller, K. T., Lange, F.F., and Marshall, D. B., J. Mat. Res. 5, 151 (1990).CrossRefGoogle Scholar
10. Mehrotra, R. C. and Bohra, R., Metal Carboxylates, (Academic Press: New York, 1983) and references therein.Google Scholar
11. Lowenstein, E., Z. Anorg. Allgm. Chem., 63, 92 (1909).Google Scholar
12. Gable, H. S., J. Am. Chem. Soc, 53, 1276 (1931).Google Scholar
13. Meyer, V. and Janny, A., Ber. 15, 1525 (1882).Google Scholar
14. The product was identified as outlined in the general experimental section. The results of the analyis were consistent with the given formulation; agreement between calculated and experimental compositions were similar to those reported for the maleate.Google Scholar
15. Glazebrook, R. T., Rosenhein, W., and Rodd, E. H., British Patent No. 112,973 (29 January, 1917)Google Scholar