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Phase Diagram Determination For Modifications Of The D Phase In The Al-AlCo-AINi System

Published online by Cambridge University Press:  10 February 2011

R. Lück ,
M. Scheffer ,
T. Gödecke ,
S. Ritschj  and
C. Beelif
R. Lück
Affiliation:
Max-Planck-Institut ffir Metallforschung, Seestraβe 92, D-70174 Stuttgart, Germany
M. Scheffer
Affiliation:
Max-Planck-Institut ffir Metallforschung, Seestraβe 92, D-70174 Stuttgart, Germany
T. Gödecke
Affiliation:
Max-Planck-Institut ffir Metallforschung, Seestraβe 92, D-70174 Stuttgart, Germany
S. Ritschj
Affiliation:
Lab. for Solid State Physics, ETH Zürich, Switzerland JST, Institute for Materials Research, Tohoku University, Sendai, Japan
C. Beelif
Affiliation:
Lab. for Solid State Physics, ETH Zürich, Switzerland CIME, EPFL, Lausanne, Switzerland
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Abstract

An extensive investigation into the At-AICo-AlNi ternary subsystem is presented. Observations have used the techniques of differential thermal analysis, magnetothermal analysis, dilatometry, metallography, X-ray diffraction, transmission electron microscopy, and high-resolution electron microscopy. Representative graphic documentation, as liquidus projection surface, isothermal sections, temperature-concentration section, and reaction scheme are presented. 11 phases from the binaries Al-Co and Al-Ni and the three ternary phases Y2 (Co2NiAl9), X and the decagonal phase D were found at room temperature. The decagonal phase is formed from the melt peritectically via a critical tie line and its primary formation area dominates at the liquidus projection surface. 45 three-phase regions are present according to the reaction scheme.

Several phase variants in the area of the decagonal phase were detected by transmission electron microscopy. Phase fields of the variants were determined from samples quenched from their respective temperatures. In-situ experiments on transformations of variants were performed by dilatometric measurements. The subdivision of the D phase area into the fields of the variants is discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 553: Symposium LL – Quasicrystals , 1998 , 25
Copyright
Copyright © Materials Research Society 1999

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