Hostname: page-component-cd9895bd7-8ctnn Total loading time: 0 Render date: 2024-12-26T09:36:28.051Z Has data issue: false hasContentIssue false
  • English
  • Français

Resonant Raman Characterization of Polyparaphenylene Based Carbon Materials

Published online by Cambridge University Press:  10 February 2011

A. Marucci ,
S. D. M. Brown ,
M. A. Pimenta ,
M. J. Matthews ,
M. S. Dresselhaus  and
M. Endo
A. Marucci
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139
S. D. M. Brown
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139
M. A. Pimenta
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139
M. J. Matthews
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139
M. S. Dresselhaus
Affiliation:
Department of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139 Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology, Cambridge, MA 02139
M. Endo
Affiliation:
Faculty of Engineering, Shinshu University, Nagano, 380, Japan
Get access

Abstract

The structure of the polymer polyparaphenylene (PPP), heat-treated at temperatures (THT) between 650°C≤ THT ≤750°C and prepared according to either the Kovacic or the Yamamoto methods, is studied by the resonant Raman technique using five laser excitation energies Elaer in the range 1.92–3.05 eV. The resonant Raman analysis allows identification of the benzenoid and quinoid forms of PPP as well as the amorphous material associated with the onset of the carbonization process. The results enable us to follow the evolution of the PPP polymer with heat-treatment temperature and to determine the differences between the materials prepared using the two different methods.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 548: Symposia EE – Solid State Ionics V , 1998 , 15
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Megahed, S. and Scrosati, B., J. Power Sources 51, 79 (1994).Google Scholar
[2] Dahn, J. R., Sleigh, A. K., Shi, H., Way, B. M., Weydanz, W. J., Reimers, J. N., Zhong, Q., and Sacken, U. von. In Lithium batteries: New materials, developments and perspectives, edited by Pistoia, G., pages 1–49, Elsevier Science B. V., Amsterdam, 1994.Google Scholar
[3] Matthews, M. J.. Electronic and Optical Properties of Novel Carbon Structures. PhD thesis, Massachusetts Institute of Technology, May 1998. Department of Physics.Google Scholar
[4] Sato, K., Noguchi, M., Demachi, A., Oki, N., and Endo, M., Science 264, 556 (1994).Google Scholar
[5] Kovacic, P. and Kyriakis, A., J. Am. Chem. Soc. 85, 454 (1963).Google Scholar
[6] Endo, M., Ismail, R., Hiraoka, T., Karaki, T., Kasai, T., Matthews, M. J., Brown, S. D. M., and Dresselhaus, M. S.. In Extended Abstracts of the 23rd Biennial Conference on Carbon, page 146, 1997. July 18-23, 1997, Pennsylvania State University.Google Scholar
[7] Froyer, G., Goblot, J. Y., Guilbert, J. L., Maurice, F., and Pelous, Y., J. Phys. (Paris) Colloq. 44, C3–745 (1983).Google Scholar
[8] Yamamoto, T. and Yamamoto, A., Chem. Lett. page 353 (1977).Google Scholar
[9] Shacklette, L. W., Eckhardt, H., Chance, R. R., Miller, G. G., Ivory, D. M., and Baughman, R. H., J. Chem. Phys 73, 353 (1980).Google Scholar
[10] Bredas, J. L., Themans, B., Fripiat, J. G., Andre, J. M., and Chance, R. R., Phys. Rev. B 29, 6761 (1984).Google Scholar
[11] Matthews, M. J., Dresselhaus, M. S., Endo, M., Sasabe, Y., Takahashi, T., and Takeuchi, K., J. Mater. Res. 11, 3099 (1996).Google Scholar
[12] Cardona, M.. In Light-Scattering in Solids, edited by Cardona, M. and Giintherodt, G., page 19. Springer-Verlag, Berlin, 1982.Google Scholar
[13] Marucci, A., Brown, S. D. M., Pimenta, M. A., Matthews, M. J., Dresselhaus, M. S., Nishimura, K., and Endo, M., J. Mater. Res. 14, (in press) (1999).Google Scholar
[14] Zannoni, G. and Zerbi, G., J. Chem. Phys. 82, 31 (1985).Google Scholar
[15] Krichene, S., Buisson, J.P., and Lefrant, S., Synth. Met. 17, 589 (1987).Google Scholar
[16] Matthews, M. J., Pimenta, M. A., Dresselhaus, G., Dresselhaus, M. S., and Endo, M., Phys. Rev. B (in press).Google Scholar
[17] Marucci, A., Pimenta, M. A., Brown, S. D. M., Dresselhaus, M. S., and Endo, M., (unpublished).Google Scholar