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A Simple Model for Anomalous Relaxation in Porous Media
Published online by Cambridge University Press: 10 February 2011
Abstract
We present a simple model to explain anomalous relaxation in random porous media. The model, based on the properties of random walks on a disordered structure, is able to describe essential features of the relaxation process in terms of a one body picture, in which the many body effects are approximated by geometrical restrictions on the particles diffusion. Disorder is considered as a random variable (quenched and annealed) taken from a power-law distribution |μ|ξμ−1. Quantities relevant to relaxation phenomena, such as the characteristic function and the particle density are calculated. Different regimes are observed as a function of the disorder parameter μ. For μ > 1 the relaxation is of exponential or Debye type, and turns into a stretched exponential as μ decreases. We compare numerical predictions (based on Monte Carlo simulations) with experimental data from porous rocks obtained by Nuclear Magnetic Resonance, and numerical data from other disordered systems.
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- Copyright © Materials Research Society 1996