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Variation of structural parameters in dimethylammonium manganese formate [(CH3)2NH2]Mn(HCOO)3 by substitution of transition metals (M = Zn, Co and Ni): by powder XRD method

Published online by Cambridge University Press:  22 May 2019

D. Sornadurai ,
R. M. Sarguna  and
V. Sridharan
D. Sornadurai*
Affiliation:
Condensed Matter Physics Division, Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam, Tamil Nadu, India
R. M. Sarguna
Affiliation:
Condensed Matter Physics Division, Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam, Tamil Nadu, India
V. Sridharan
Affiliation:
Condensed Matter Physics Division, Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam, Tamil Nadu, India HBNI, Kalpakkam, Tamil Nadu, India
*
a)Author to whom correspondence should be addressed. Electronic mail: sorna@igcar.gov.in
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Abstract

Variation of structural parameters of dimethylammonium manganese formate [(CH3)2NH2]Mn[(HCOO)3] upon substitution by the transition elements Zn, Co, and Ni is studied by powder X-ray diffraction (PXRD) technique. These metal–organic framework (MOF) crystals were grown by solvothermal method. The PXRD patterns of all MOFs exhibited rhombohedral structure. PXRD patterns of MOFs were analyzed using Rietveld refinement method. While the parent Mn-MOF and Mn0.9Zn0.1MOF are found to have similar structural parameters, Co and Ni substituted Mn-MOFs have smaller structural parameters than that of parent Mn-MOF. The reason for this variation in the lattice parameters is explained based on the Shannon ionic radii.

Keywords

Metal Organic FrameworksCrystal StructureLaue diffractionPowder XRD methodRietveld refinementShannon ionic radius
Type
Technical Article
Information
Powder Diffraction , Volume 34 , Issue 2 , June 2019 , pp. 124 - 129
Copyright
Copyright © International Centre for Diffraction Data 2019 

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