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Ethylenediamine as a bridging ligand: structure solution of two cadmium(II)-based coordination polymers from powder diffraction data

Published online by Cambridge University Press:  23 April 2013

Piotr Putaj ,
Bartłomiej Gaweł  and
Wiesław Łasocha
Piotr Putaj
Affiliation:
Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Kraków, Poland
Bartłomiej Gaweł
Affiliation:
Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Kraków, Poland
Wiesław Łasocha*
Affiliation:
Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Kraków, Poland Jerzy Haber Institute of Catalysis and Surface Chemistry PAS, ul. Niezapominajek 8, 30-239 Kraków, Poland
*
a)Author to whom correspondence should be addressed. Electronic mail: lasocha@chemica.uj.edu.pl
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Abstract

Structures of [Cd(C2H8N2)Cl2]n(1) and [Cd(C2H8N2)Br2]n(2) were solved from powder diffraction data. Compound (1) crystallizes in the space group Pbam (No. 55), a = 9.9021(7) Å, b = 7.8186(6) Å, c = 4.0705(3) Å, V = 315.13(3) Å3, Z = 2. (2) is isostructural: space group Pbam (No. 55), a = 10.405(2) Å, b = 7.8634(8) Å, c = 4.2079(5) Å, V = 344.28(6) Å3, Z = 2. The investigated compounds are examples of two-dimensional hybrid coordination polymers, in which neighboring metal centers are bridged via both organic and inorganic moieties: ethylenediamine molecules and halide anions. Both crystal structures were solved ab initio from powder data using direct methods.

Keywords

cadmium(II) diamine complexescoordination polymersRietveld methodpowder diffractionethylenediamine
Type
Technical Articles
Information
Powder Diffraction , Volume 28 , Issue 3 , September 2013 , pp. 207 - 211
Copyright
Copyright © International Centre for Diffraction Data 2013 

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