The diffuse interstellar bands (DIBs) have come to the fore as an important mystery. This paper presents the history of DIB discovery and research; their importance; a summary of their properties; constraints on proposed identifications; a survey of DIB papers (including graduate student's theses); and a web site that lists DIBs paper from 1922 to 2011 (to be extended to the present).

Since the discovery of the Diffuse Interstellar Bands (DIBs) in the early 1920s, numerous research groups have taken on the task to obtain as complete a census of the DIBs as observationally possible in order to unravel characteristics that would allow the community to tie the DIB carriers to known species. Here, I will briefly review the efforts and progress that were made for the past two decades in producing new, deeper, and more complete DIB surveys. In particular, I will review the important role that these modern surveys are playing in revealing main observational characteristics of the DIBs and their dependence on the local physical conditions in the Galactic Interstellar Medium.

The term “families of diffuse bands” (DIBs) appeared in 1986/87 when my collaborators: Gordon A.H. Walker, Bengt E. Westerlund and I found that the strength ratio of the major DIBs 5780 and 5797 is heavily variable. We proved that at the same E(B-V) the DIB intensities may vary by as much as a factor of three or more. A similar result was published by Karl Josafatsson and Ted Snow soon after. A decade later, we proved (with Chris Sneden) that certain DIB strength ratios seem to be related to intensities of the known features of simple molecular species; this led to the introduction of the so called σ and ζ type interstellar clouds. The former are characterized by very weak molecular features (but broad DIBs – very strong) while the latter by rather strong bands of simple radicals and weak broad DIBs. Currently we face a bunch of questions: are the DIB intensities related to those of certain molecular species, e.g. C2 as suggested by Lew Hobbs' and Ted Snow's group? Do the DIB profiles, found to be complex by Peter Sarre, depend on e.g. the rotational temperatures of simple, linear carbon species? Do the DIB profiles depend on the irradiation of interstellar clouds by nearby stars? The relative DIB strengths as well as those of the simple radicals seem to be related to the shapes of interstellar extinction curves. We thus face three players in the interstellar translucent clouds: dust particles, simple radicals and the DIB carriers. Apparently, their mutual relations depend on local physical parameters of intervening clouds; these relations are not clear yet.

A short review of the profiles of diffuse interstellar bands and their possible interpretation is given, largely from the perspective of absorption by gas-phase molecules. Potentially a crucial source of information on the nature of the diffuse band carriers, profile studies provide a promising avenue of research towards finding the solution to their identification. Detection and modelling of fine structure in particular offers a valuable benchmark against which any proposed carriers(s) can be tested.

The first extragalactic diffuse interstellar band (DIB) detections were of λ4430 in the Large and Small Magellanic Clouds (LMC and SMC) in the 1960s and 70s. Driven mainly by the increased sensitivity afforded by 8-10 m-class telescopes, the last 13 years have witnessed an explosion of DIB discoveries throughout the nearby and distant universe. This review focuses on the history of extragalactic DIB studies, including some of the important results that have come out of this field, and looks to the future for what can be learned about DIBs in external galaxies with the next generation of large telescopes. So far, DIBs have been observed in the Magellanic Clouds, starburst galaxies, DLAs, and nearby (≤30 Mpc distant) spiral galaxies, and are found to be ubiquitous in the diffuse interstellar medium (ISM) of extragalactic environments wherever dust is present. Important results include the finding that DIB carriers are significantly more closely related to dust than to neutral hydrogen, and that the λ6283 DIB tends to be anomalously weak in low-metallicity sightlines.

The status of DIB research (Herbig 1995) has strongly advanced since the DIB conference in Boulder in 1994. In the same year we reported the discovery of two near IR diffuse bands coincident with C60+, that was confirmed in subsequent years. Since then a number of DIB observational studies have been published such as DIB surveys, measurements of DIB families, correlations and environment dependences as well as DIBs in extra-galactic sources. Resolved substructures were measured and compared to predicted rotational contours of large molecules. Polarisation studies provided constraints on possible carrier molecules and upper limits. DIBs carriers have been linked with several classes of organic molecules observed in the interstellar medium, in particular to the UIR bands (assigned to PAHs), the Extended Red Emission (ERE) or the recently detected Anomalous Microwave Emission (AME, assigned to spinning dust). In particular fullerenes and PAHs have been proposed to explain some DIBs and specific molecules were searched for in DIB spectra. DIB carriers could be present in various dehydrogenation and ionization states. Experiments in the laboratory and in space contribute to our understanding of the photo-stability of possible DIB carriers. In summary, the status of DIB research in the last 20 years has strongly advanced. We review DIB observational results and their interpretation and introduce the relevant plenary discussion.

We present a comprehensive and sensitive unbiased survey of interstellar features in the near-UV range (3040-3700 Å). We combined a large number of VLT/UVES archival observations of a sample of highly reddened early type stars – typical diffuse interstellar band (DIB) targets. We stacked the individual observations to obtain a spectrum with a signal-to-noise ratio exceeding 1500. Careful inspection of this spectrum reveals tens of absorption features of interstellar nature, most of which can be identified with various atomic and molecular features. We furthermore detect four weak unidentified features, but we cannot establish their interstellar nature. Our sensitivity is limited by telluric and instrumental residuals; this precludes us from detecting broader features (e.g. DIBs). For each detected feature, we measured fundamental parameters (radial velocities, line widths, and equivalent widths). We also compare our co-added spectrum to cold gas-phase laboratory measurements of small, neutral polycyclic aromatic hydrocarbon (PAH) molecules.

This paper updates the recent discovery of over a dozen new diffuse interstellar bands (DIBs), first in H-band spectra of stars in the Galactic center (GC) and toward stars in the Cygnus OB2 Association. The H-band DIBs, which currently number 15, are the longest wavelength DIBs reported to date and are the first found on sightlines toward the Galactic center. K-band (2.0-2.5 μm) spectra of the GC stars do not reveal additional DIBs. Comparison of the velocity profile of the strongest of the new DIBs in the sightline toward GCS3-2 (in the GC) with that toward Cygnus OB2 No. 9 and also with the broad velocity profiles of H3+ lines toward GCS3-2 confirm that a significant fraction of the diffuse material producing the DIB absorptions on sightlines to the GC is located within the central few hundred parsecs of the Galaxy.

Using high resolution H-band spectra from first-year observations of the SDSS-III APOGEE survey, we have searched for the presence of Diffuse Interstellar Bands (DIBs) towards several thousand stars and obtained ~7 000 robust detections spanning a broad range of Galactic environments. This represents the largest homogeneous sample of DIB systems in terms of both size and sky coverage, which can be used for various statistical studies. For example, we find the strength of the most prominent near-IR DIB (at 1.5723 μm) to be strongly correlated with line-of-sight dust extinction, and its apparent velocity appears to trace that of the Galactic CO emission. The ability to work at near-IR wavelengths allows us to probe lines of sight penetrating through the dusty disk of the Galaxy, spanning a range of about 8 magnitudes of extinction. This preliminary investigation illustrates how a large sample of DIBs can serve as a useful tool to probe the structure of the Galaxy and the chemistry of the interstellar medium.

We present the first sample of diffuse interstellar bands (DIBs) in the nearby galaxy M33. Studying DIBs in other galaxies allows the behaviour of the carriers to be examined under interstellar conditions which can be quite different from those of the Milky Way, and to determine which DIB properties can be used as reliable probes of extragalactic interstellar media. Multi-object spectroscopy of 43 stars in M33 has been performed using Keck/DEIMOS. The stellar spectral types were determined and combined with literature photometry to determine the M33 reddenings E(B-V)M33. Equivalent widths or upper limits have been measured for the λ5780 DIB towards each star. DIBs were detected towards 20 stars, demonstrating that their carriers are abundant in M33. The relationship with reddening is found to be at the upper end of the range observed in the Milky Way. The line of sight towards one star has an unusually strong ratio of DIB equivalent width to E(B-V)M33, and a total of seven DIBs were detected towards this star.

In a quest to further our understanding of the diffuse interstellar medium (ISM) as well as the unidentified carriers of the diffuse interstellar bands (DIBs), we are mapping DIBs across the sky using hundreds of hot stars as background torches – globular clusters (in particular ω Centauri), nearby stars in and around the Local Bubble, and stars within the Magellanic Clouds. I describe the results so far obtained and our current experiments.

The Sun is located inside an enormous local cavity filled with a million degree, ionized hydrogen gas and surrounded by a wall of dense and cold gas, this cavity is known as the Local Bubble (LB). Since the tempreture of Local Bubble is high, the typical singly-ionized atoms or molecules can not survive at this high tempreture. To overcome this problem we should probe the Local Bubble using species which survive under this condition so we have done a whole sky survey in north hemisphere by observing absorptions in the Diffuse Interstellar Bands (DIBs) for sight-lines with distance >300 pc. We have done 30 nights observation and have observed 473 bright stars. We found that the correlations between 5780 Å DIBs and Na I D doublets inside of the LB is much more than carriers outside of the LB.

Anomalously broad diffuse interstellar bands (DIBs) at 5780.5, 5797.1, 6196.0, and 6613.6 Å are found in absorption along the line of sight to Herschel 36, an O star system next to the bright Hourglass nebula of the Hii region Messier 8. Excited lines of CH and CH+ are seen as well. We show that the region is very compact and itemize other anomalies of the gas. An infrared-bright star within 400 AU is noted. The combination of these effects produces anomalous DIBs, interpreted by Oka et al. (2013, see also this volume) as being caused predominantly by infrared pumping of rotational levels of relatively small molecules.

The extraordinary DIBs observed toward Herschel 36 (Dahlstrom et al. 2013) have been analyzed (Oka et al. 2013). The analysis led us to a new way to classify the carriers of DIBs depending on whether the molecules are polar or non-polar. The pronounced Extended Tails toward Red (ETR) observed for DIBs λ5780.5, λ5797.1, and λ6613.6 are explained as due to radiative excitation of high rotational levels of polar carrier molecules in an environment with high radiative temperature ~90 K. Other DIBs (e.g., λ5849.8, λ6196.0, and λ6379.3) which do not show ETR are likely due to non-polar molecules. Model calculations taking into account the interplay of radiative and collisional effects reproduce the observed ETR using realistic molecular parameters if the radiative temperature is sufficiently high (~90 K). The calculation suggests that the carriers of DIBs with ETR are likely medium size molecules with 3 - 6 heavy atoms unless the radiative temperature is much higher.

In addition to the hundreds of known visual-wavelength Diffuse Interstellar Bands (DIBs), a number of DIBs in the near-infrared (NIR) are now also known to exist. We present here high-resolution UKIRT echelle spectroscopy of two of the NIR DIBs toward sightlines exhibiting a range of visual extinctions. Variations in the strengths and profile shapes of the bands are considered in the context of known properties of the narrow DIBs at visual wavelengths.

We present the first results of an exploratory VLT/X-Shooter survey of near-infrared diffuse interstellar bands (DIBs) in diffuse to translucent interstellar clouds. These observations confirm the presence of recently discoved NIR DIBs and provide more accurate rest wavelengths and line widths. Example spectra are shown for the reddened, AV ~ 10 mag, line-of-sight towards the distant binary system 4U 1907+09.

We present and discuss recent results from observations of bright Type Ia supernovae as probes of physical and chemical condtions of extra-galactic interstellar clouds. To illustrate the case we present new results obtained for SN 2009ig.

We have developed a method allowing to extract DIBs from cool star spectra, based on combinations of stellar synthetic, telluric transmission (when necessary), and DIB profile models. It is applicable when the star temperature, surface gravity and metallicity have been previously estimated. Such a method aims at extracting extensive data from stellar spectroscopic surveys such as the Gaia-ESO Survey in progress at the VLT. The method has been applied to several strong DIBs detected towards stars from various programs and located at various distances from the solar neighborhood to the Galactic Bulge. Here we illustrate the extraction of the 8620 Å DIB, and compare its strength to the one of the 6284 Å band, both for nearby and bulge stars.

Medium to high-resolution stellar spectroscopic surveys can potentially be used to build DIB databases by means of automated methods of analysis. Multiplex spectrographs increase strongly those potentialities and allow small-scale variability studies. Because measurements of the stellar parameters are generally the primary goal of the surveys, synthetic spectra can be computed and used to extract DIBs from late-type star data. Large datasets should allow deeper investigations on the DIB variability in response to stellar radiation fields, DIB reddening relationships, and help localizing interstellar clouds. Here we describe our attempts to build and test automated methods adapted to both early and late type stars.

We are using five different surveys to compile the largest sample of diffuse interstellar band (DIB) measurements ever collected. GOSSS is obtaining intermediate-resolution blue-violet spectroscopy of ~2500 OB stars, of which 60% have already been observed and processed. The other four surveys have already collected multi-epoch high-resolution optical spectroscopy of 700 OB stars with different telescopes, including the 9 m Hobby-Eberly Telescope in McDonald Observatory. Some of our stars are highly-extinguished targets for which no good-quality optical spectra have ever been published. For all of the targets in our sample we have obtained accurate spectral types, measured non-DIB ISM lines, and compiled information from the literature to calculate the extinction. Here we present the first results of the project, the properties of twenty DIBs in the 4100-5500 Å range. We clearly detect a couple of previously elusive DIBs at 4170 Å and 4591 Å; the latter could have coronene and ovalene cations as carriers.