A new calibration curve for the conversion of radiocarbon ages to calibrated (cal) ages has been constructed and internationally ratified to replace IntCal98, which extended from 0–24 cal kyr BP (Before Present, 0 cal BP = AD 1950). The new calibration data set for terrestrial samples extends from 0–26 cal kyr BP, but with much higher resolution beyond 11.4 cal kyr BP than IntCal98. Dendrochronologically-dated tree-ring samples cover the period from 0–12.4 cal kyr BP. Beyond the end of the tree rings, data from marine records (corals and foraminifera) are converted to the atmospheric equivalent with a site-specific marine reservoir correction to provide terrestrial calibration from 12.4–26.0 cal kyr B P. A substantial enhancement relative to IntCal98 is the introduction of a coherent statistical approach based on a random walk model, which takes into account the uncertainty in both the calendar age and the 14C age to calculate the underlying calibration curve (Buck and Blackwell, this issue). The tree-ring data sets, sources of uncertainty, and regional offsets are discussed here. The marine data sets and calibration curve for marine samples from the surface mixed layer (Marine04) are discussed in brief, but details are presented in Hughen et al. (this issue a). We do not make a recommendation for calibration beyond 26 cal kyr BP at this time; however, potential calibration data sets are compared in another paper (van der Plicht et al., this issue).

New radiocarbon calibration curves, IntCal04 and Marine04, have been constructed and internationally ratified to replace the terrestrial and marine components of IntCal98. The new calibration data sets extend an additional 2000 yr, from 0–26 cal kyr BP (Before Present, 0 cal BP = AD 1950), and provide much higher resolution, greater precision, and more detailed structure than IntCal98. For the Marine04 curve, dendrochronologically-dated tree-ring samples, converted with a box diffusion model to marine mixed-layer ages, cover the period from 0–10.5 cal kyr BP. Beyond 10.5 cal kyr BP, high-resolution marine data become available from foraminifera in varved sediments and U/Th-dated corals. The marine records are corrected with site-specific 14C reservoir age information to provide a single global marine mixed-layer calibration from 10.5–26.0 cal kyr BP. A substantial enhancement relative to IntCal98 is the introduction of a random walk model, which takes into account the uncertainty in both the calendar age and the 14C age to calculate the underlying calibration curve (Buck and Blackwell, this issue). The marine data sets and calibration curve for marine samples from the surface mixed layer (Marine04) are discussed here. The tree-ring data sets, sources of uncertainty, and regional offsets are presented in detail in a companion paper by Reimer et al. (this issue).

Recent measurements on dendrochronologically-dated wood from the Southern Hemisphere have shown that there are differences between the structural form of the radiocarbon calibration curves from each hemisphere. Thus, it is desirable, when possible, to use calibration data obtained from secure dendrochronologically-dated wood from the corresponding hemisphere. In this paper, we outline the recent work and point the reader to the internationally recommended data set that should be used for future calibration of Southern Hemisphere 14C dates.

We report on the development and implementation of a model-based statistical method for the estimation of radiocarbon calibration curves using diverse data. The method takes account of uncertainty on both the 14C and calendar scales, coherently integrating data, the calendar age estimates of which arise from different dating methods. It also allows for correlation between observations, if they have particular sources of uncertainty in common. We adopt an approach based on a random walk model, tailoring it to take account of possible calendar age offsets between different data sources by adding a random effect component. The latter allows us to use the same modeling framework for constructing the new calibration curve IntCal04, the comparison curve NotCal04, the Southern Hemisphere curve SHCal04, and the marine calibration curve Marine04.

Confidence in the precisions of accelerator mass spectrometry (AMS) and decay measurements must be comparable for the application of the radiocarbon calibration to age determinations using both technologies. We confirmed the random nature of the temporal distribution of 14C ions in an AMS spectrometer for a number of sample counting rates and properties of the sputtering process. The temporal distribution of ion counts was also measured to confirm the applicability of traditional counting statistics.

The combined oak and pine tree-ring chronologies of Hohenheim University are the backbone of the Holocene radiocarbon calibration for central Europe. Here, we present the revised Holocene oak chronology (HOC) and the Preboreal pine chronology (PPC) with respect to revisions, critical links, and extensions. Since 1998, the HOC has been strengthened by new trees starting at 10,429 BP (8480 BC). Oaks affected by cockchafer have been identified and discarded from the chronology. The formerly floating PPC has been cross-matched dendrochronologically to the absolutely dated oak chronology, which revealed a difference of only 8 yr to the published 14C wiggle-match position used for IntCal98. The 2 parts of the PPC, which were linked tentatively at 11,250 BP, have been revised and strengthened by new trees, which enabled us to link both parts of the PPC dendrochronologically. Including the 8-yr shift of the oak-pine link, the older part of the PPC (pre-11,250 BP) needs to be shifted 70 yr to older ages with respect to the published data (Spurk 1998). The southern German part of the PPC now covers 2103 yr from 11,993–9891 BP (10,044–7942 BC). In addition, the PPC was extended significantly by new pine chronologies from other regions. A pine chronology from Avenches and Zürich, Switzerland, and another from the Younger Dryas forest of Cottbus, eastern Germany, could be crossdated and dendrochronologically matched to the PPC. The absolutely dated tree-ring chronology now extends back to 12,410 cal BP (10,461 BC). Therefore, the tree-ring-based 14C calibration now reaches back into the Central Younger Dryas. With respect to the Younger Dryas-Preboreal transition identified in the ring width of our pines at 11,590 BP, the absolute tree-ring chronology now covers the entire Holocene and 820 yr of the Younger Dryas.

Radiocarbon dating has been rarely used for chronological problems relating to the Anglo-Saxon period. The “flatness” of the calibration curve and the resultant wide range in calendrical dates provide little advantage over traditional archaeological dating in this period. Recent advances in Bayesian methodology have, however, created the possibility of refining and checking the established chronologies, based on typology of artifacts, against 14C dates. The calibration process, within such a confined age range, however, relies heavily on the structural accuracy of the calibration curve. We have therefore re-measured, at decadal intervals, a section of the Irish oak chronology for the period AD 495–725. These measurements have been included in IntCal04.

We calibrated portions of the radiocarbon time scale with combined 230Th, 231Pa, 14C measurements of corals collected from Espiritu Santo, Vanuatu and the Huon Peninsula, Papua New Guinea. The new data map 14C variations ranging from the current limit of the tree-ring calibration [11,900 calendar years before present (cal BP), Kromer and Spurk 1998, now updated to 12,400 cal B P, see Kromer et al., this issue], to the 14C-dating limit of 50,000 cal BP, with detailed structure between 14 to 16 cal kyr BP and 19 to 24 cal kyr BP. Samples older than 25,000 cal BP were analyzed with high-precision 231Pa dating methods (Pickett et al. 1994; Edwards et al. 1997) as a rigorous second check on the accuracy of the 230Th ages. These are the first coral calibration data to receive this additional check, adding confidence to the age data forming the older portion of the calibration. Our results, in general, show that the offset between calibrated and 14C ages generally increases with age until about 28,000 cal BP, when the recorded 14C age is nearly 6800 yr too young. The gap between ages before this time is less; at 50,000 cal BP, the recorded 14C age is 4600 yr too young. Two major 14C-age plateaus result from a 130 drop in Δ14C between 14–15 cal kyr BP and a 700 drop in Δ14C between 22–25 cal kyr BP. In addition, a large atmospheric Δ14C excursion to values over 1000 occurs at 28 cal kyr BP. Between 20 and 10 cal kyr BP, a component of atmospheric Δ14C anti-correlates with Greenland ice δ18O, indicating that some portion of the variability in atmospheric Δ14C is related to climate change, most likely through climate-related changes in the carbon cycle. Furthermore, the 28-kyr excursion occurs at about the time of significant climate shifts. Taken as a whole, our data indicate that in addition to a terrestrial magnetic field, factors related to climate change have affected the history of atmospheric 14C.

This paper describes the methods used to develop the Cariaco Basin PL07-58PC marine radiocarbon calibration data set. Background measurements are provided for the period when Cariaco samples were run, as well as revisions leading to the most recent version of the floating varve chronology. The floating Cariaco chronology has been anchored to an updated and expanded Preboreal pine tree-ring data set, with better estimates of uncertainty in the wiggle-match. Pending any further changes to the dendrochronology, these results represent the final Cariaco 58PC calibration data set.

In this paper, we present updated information and results of the radiocarbon records based on Polynesian corals and on Iberian Margin planktonic foraminifera. The latter record was first published by Bard et al. (2004a,b), with the subsequent addition of some data by Shackleton et al. (2004). These data sets are compared with the IntCal98 record (Stuiver et al. 1998) and with data sets based on other archives, such as varves of Lake Suigetsu (Kitagawa and van der Plicht 1998, 2000), speleothems from the Bahamas (Beck et al. 2001), and Cariaco sediments (Hughen et al. 2004). Up to 26,000 cal BP, the Iberian Margin data agree within the errors of the other records. By contrast, in the interval between 33,000 and 41,000 cal BP, the Iberian Margin record runs between the Lake Suigetsu and Bahamian speleothem data sets, but it agrees with the few IntCal98 coral data and the Cariaco record.

We built a floating, 1382-ring pine chronology covering the radiocarbon age interval of 12,000 to 10,650 BP. Based on the strong rise of Δ14C at the onset of the Younger Dryas (YD) and wiggle-matching of the decadal-scale Δ14C fluctuations, we can anchor the floating chronology to the Cariaco varve chronology. We observe a marine reservoir correction higher than hitherto assumed for the Cariaco site, of up to 650 yr instead of 400 yr, for the full length of the comparison interval. The tree-ring Δ14C shows several strong fluctuations of short duration (a few decades) at 13,800; 13,600; and 13,350 cal BP. The amplitude of the strong Δ14C rise at the onset of the YD is about 40, whereas in the marine data set the signal appears stronger due to a re-adjustment of the marine mixed-layer Δ14C towards the atmospheric level.

This paper presents radiocarbon results from a single Goniastrea favulus coral from Papua New Guinea which lived continuously between 13.0 and 13.1 kyr BP. The specimen was collected from a drill core on the Huon Peninsula and has been independently dated with 230Th. A site-specific reservoir correction has been applied to the results, and coral growth bands were used to calibrate individual growth years. Alternating density bands, which are the result of seasonal growth variations, were subsampled to provide 2 integrated 6-month 14C measurements per year. This allows for 20 independent measurements to be averaged for each decadal value of the 14C calibration, making these results the highest resolution data set available for this brief time range. The finestructure of the data set exhibits 14C oscillations with frequencies on the order of 4 to 10 yr, similar to those observed in modern coral 14C records.

The radiocarbon calibration curve IntCal04 extends back to 26 cal kyr B P. While several high-resolution records exist beyond this limit, these data sets exhibit discrepancies of up to several millennia. As a result, no calibration curve for the time range 26–50 cal kyr BP can be recommended as yet, but in this paper the IntCal04 working group compares the available data sets and offers a discussion of the information that they hold.

Some of the most valuable paleoclimate archives yet recovered are the multi-proxy records from the Greenland GISP2 and GRIP ice cores. The crucial importance of these data arises in part from the strong correlations that exist between the Greenland δ18O records and isotopic or other proxies in numerous other Northern Hemisphere paleoclimate sequences. These correlations could, in principle, allow layer-counted ice-core chronologies to be transferred to radiocarbon-dated paleoclimate archives, thus providing a 14C calibration for the Last Glacial Maximum and Isotope Stage 3, back to the instrumental limits of the 14C technique. However, this possibility is confounded by the existence of numerous different chronologies, as opposed to a single (or even a “best”) ice-core time scale. This paper reviews how the various chronologies were developed, summarizes the differences between them, and examines ways in which further research may allow a 14C calibration to be established.

A comprehensive tropospheric 14CO2 data set of quasi-continuous observations covering the time span from 1959 to 2003 is presented. Samples were collected at 3 European mountain sites at height levels of 1205 m (Schauinsland), 1800 m (Vermunt), and 3450 m asl (Jungfraujoch), and analyzed in the Heidelberg Radiocarbon Laboratory. The data set from Jungfraujoch (1986–2003) is considered to represent the free tropospheric background level at mid-latitudes of the Northern Hemisphere, as it compares well with recent (yet unpublished) measurements made at the marine baseline station Mace Head (west coast of Ireland). The Vermunt and Schauinsland records are significantly influenced by regional European fossil fuel CO2 emissions. The respective Δ14CO2 depletions, on an annual mean basis, are, however, only 5 less than at Jungfraujoch. Vermunt and Schauinsland both represent the mean continental European troposphere.

Comprehensive published radiocarbon data from selected atmospheric records, tree rings, and recent organic matter were analyzed and grouped into 4 different zones (three for the Northern Hemisphere and one for the whole Southern Hemisphere). These 14C data for the summer season of each hemisphere were employed to construct zonal, hemispheric, and global data sets for use in regional and global carbon model calculations including calibrating and comparing carbon cycle models. In addition, extended monthly atmospheric 14C data sets for 4 different zones were compiled for age calibration purposes. This is the first time these data sets were constructed to facilitate the dating of recent organic material using the bomb 14C curves. The distribution of bomb 14C reflects the major zones of atmospheric circulation.

The definitive paper by Stuiver and Polach (1977) established the conventions for reporting of radiocarbon data for chronological and geophysical studies based on the radioactive decay of 14C in the sample since the year of sample death or formation. Several ways of reporting 14C activity levels relative to a standard were also established, but no specific instructions were given for reporting nuclear weapons-testing (post-bomb) 14C levels in samples. Because the use of post-bomb 14C is becoming more prevalent in forensics, biology, and geosciences, a convention needs to be adopted. We advocate the use of fraction modern with a new symbol F14C to prevent confusion with the previously used Fm, which may or may not have been fractionation-corrected. We also discuss the calibration of post-bomb 14C samples and the available data sets and compilations, but do not give a recommendation for a particular data set.