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Determination of carbon spices formed by decomposition of acetate in Japanese paddy soil

Published online by Cambridge University Press:  09 January 2012

J. Barescut ,
D. Lariviere ,
T. Stocki ,
N. Ishii ,
H. Koiso  and
S. Uchida
N. Ishii
Affiliation:
Office of Biospheric Assessment for Waste Disposal, National Institute of Radiological Sciences, Anagawa 4-9-1, Inage-ku, Chiba-shi, Chiba 263-8555, Japan
H. Koiso
Affiliation:
Office of Biospheric Assessment for Waste Disposal, National Institute of Radiological Sciences, Anagawa 4-9-1, Inage-ku, Chiba-shi, Chiba 263-8555, Japan
S. Uchida
Affiliation:
Office of Biospheric Assessment for Waste Disposal, National Institute of Radiological Sciences, Anagawa 4-9-1, Inage-ku, Chiba-shi, Chiba 263-8555, Japan
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Abstract

For appropriate safety assessment of TRU waste disposal, the dominant chemical species of 14C-gas was studied. [1,2-14C] sodium acetate was added to flooded paddy soil samples, and the content of 14C in the soil, solution, and the emitted CO2 gas during incubation period was determined. Recovery ratios of the total 14C activity to the initial 14C activity were 97.9% at day 1, 86.4% at day 3, and 83.5% at day 7 of incubation. The result of the day 1 means that the emitted 14C-gas was almost 14CO2. At day 7 of incubation, about 16.5% of 14C was failed to recover. Even if the unknown 14C was gases other than 14CO2, the dominant chemical species of the emitted 14C-gas will be 14CO2, because the recovery ratio of the 14CO2 was 48.9% (¿16.5%). Sodium 2-bromoethane-sulfonate was used to ensure the emission of CH4, but there was no effect of the regent to the recovery ratio of 14CO2. Methane emission may be little under our experimental conditions. These results suggest that the dominant chemical species of the emitted 14C-gas from the flooded paddy soil samples was 14CO2.

Type
Research Article
Information
Radioprotection , Volume 46 , Issue 6: ICRER 2011 – International Conference on Radioecology & Environmental Radioactivity: Environment & Nuclear Renaissance , 2011 , pp. S483 - S486
Copyright
© Owned by the authors, published by EDP Sciences, 2011

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References

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