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14 - Anharmonic vibrators

Published online by Cambridge University Press:  13 January 2010

A. B. Pippard
Affiliation:
University of Cambridge
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Summary

We begin with some examples of one-dimensional vibration in a nonparabolic potential chosen to permit complete analytical solution of Schrödinger's time-independent equation. These examples are of isochronous vibrators which classically have a frequency independent of amplitude, and which might be expected therefore to have energy levels equally spaced at a separation of ħω0. This expectation turns out to be very nearly right and inspires a certain confidence in the semi-classical procedure developed by (among others) Bohr, Wilson and Sommerfeld. We therefore apply this procedure to some non-isochronous systems and find once more rather good agreement with the results of exact quantum mechanics. Periodic systems in fact can often be treated semi-classically with adequate accuracy, and significant economy of effort in comparison with strict quantum-mechanical analysis. This approach pays handsomely when we turn in the next chapter to the quantization of electron cyclotron orbits which, as already discussed in chapter 8, are closely related to harmonic oscillators. Conduction electrons in semi-conductors, and still more in metals, have their behaviour modified by the lattice through which they move, and a complete quantal treatment has never been achieved. It is clear, however, from approximate calculations, often of great complexity, that the semiclassical method describes most of the interesting physical processes correctly and very simply. In chapter 15 we shall describe in outline some of the effects which can be treated quite well enough for most purposes without even writing down Schrödinger's equation.

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Publisher: Cambridge University Press
Print publication year: 1989

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  • Anharmonic vibrators
  • A. B. Pippard, University of Cambridge
  • Book: The Physics of Vibration
  • Online publication: 13 January 2010
  • Chapter DOI: https://doi.org/10.1017/CBO9780511622908.017
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  • Anharmonic vibrators
  • A. B. Pippard, University of Cambridge
  • Book: The Physics of Vibration
  • Online publication: 13 January 2010
  • Chapter DOI: https://doi.org/10.1017/CBO9780511622908.017
Available formats
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To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

  • Anharmonic vibrators
  • A. B. Pippard, University of Cambridge
  • Book: The Physics of Vibration
  • Online publication: 13 January 2010
  • Chapter DOI: https://doi.org/10.1017/CBO9780511622908.017
Available formats
×