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6 - Gaseous Aerosol Precursors

from Part 2 - Fundamentals and Modeling: Production and Control

Published online by Cambridge University Press:  05 June 2013

By
Richard C. Miake-Lye
Edited by
Tim C. Lieuwen  and
Vigor Yang
Tim C. Lieuwen
Affiliation:
Georgia Institute of Technology
Vigor Yang
Affiliation:
Georgia Institute of Technology
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Summary

Introduction

Concerns about particle emissions from aircraft were first raised in the 1960s because of the visible smoke trails left behind by jet aircraft on takeoff. These concerns led to an emission certification requirement for aircraft engines in the 1970s that mandated a smoke number (SN) measurement, which served to control the visible opacity of the emitted exhaust. Understanding of the effects of particle emissions has progressed dramatically since the 1970s, and more knowledge now exists both about carbonaceous soot particles that contributed strongly to the black smoke trails of the 1960s and about how other emissions can condense and add to particle numbers and mass. These latter contributions arise because of gaseous emissions that are products of combustion and also have low-vapor pressures. Having low-vapor pressures, they are thermodynamically disposed to condense as the exhaust mixes and cools in the atmosphere. These condensable species are gaseous aerosol precursors and their contributions to particulate matter pollution are the subject of significant scientific research and regulatory interest.

Like all consumers of hydrocarbon fuels, gas turbine engines emit products of combustion dominated by carbon dioxide and water vapor. In addition to these major products of combustion, the exhaust emissions also include products of incomplete combustion, due to small combustion inefficiencies (very small for modern aircraft engines at cruise), and pollutants formed in the combustion process, like NOx and SOx. Beyond combustion-related emissions, recent work has identified emissions from the lubrication system that also contribute to particle emissions in the exhaust. These various emissions include gaseous species and particles.

Type
Chapter
Information
Gas Turbine Emissions , pp. 154 - 174
Publisher: Cambridge University Press
Print publication year: 2013

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References

Agrawal, H., Sawant, A. A., Jansen, K., Miller, J. W., and Cocker, D. R. (2008). “Characterization of Chemical and Particulate Emissions from Aircraft Engines.” Atmospheric Environment 42: 4380–92.CrossRefGoogle Scholar
Anderson, B. E., Beyersdorf, A. J., Hudgins, C. H., Plant, J. V., Thornhill, K. L., Winstead, E.L., Ziemba, L.D., Howard, R., Corporan, E., Miake-Lye, R.C., Herndon, S. C., Timko, M., Woods, E., Dodds, W., Lee, B., Santori, G., Whitefield, P., Hagen, D., Lobo, P., Knighton, W. B., Bulzan, D., Tacina, K., Wey, C., Vander Wal, R., Bhargava, A., Kinsey, J., and Liscinsky, D.S. (2011). “Alternative Aviation Fuel Experiment (AAFEX).” NASA/TM–2011–217059.
Anderson, B. E., Branham, H.-S., Hudgins, C. H., Plant, J. V., Ballenthin, J. O., Miller, T. M., Viggiano, A. A., Blake, D. R., Boudries, H., Canagaratna, M., Miake-Lye, R. C., Onasch, T. B., Wormhoudt, J. C., Worsnop, D. R., Brunik, K. E., Culler, C., Penko, P., Sanders, T., Han, H.-S., Lee, P., Pui, D. Y. H., Thornhill, K. L., and Winstead, E. L. (2005). “Experiment to Characterize Aircraft Volatile Aerosol and Trace-Species Emissions (EXCAVATE).” NASA Report No. NASA/TM-2005–213783.
Anderson, B. E., Cofer, W. R., Bagwell, D. R., Barrick, J. W., Hudgins, C. H., and Brunke, K. E. (1998). “Airborne Observations of Aircraft Aerosol Emissions 1: Total Nonvolatile Particle Emission Indices.” Geophysical Research Letters 25: 1689–92.CrossRefGoogle Scholar
Brown, R. C., Miake-Lye, R. C., Anderson, M. R., Kolb, C. E., and Resch, T. J. (1996). “Aerosol Dynamics in Near-Field Aircraft Plumes.” Journal of Geophysical Research (Atmospheres) 101(D17): 22939–53.CrossRefGoogle Scholar
Corporan, E., DeWitt, M. J., Belovich, V., Pawlik, R., Lynch, A. C., Gord, J. R., and Meyer, T. R. (2007). “Emissions Characteristics of a Turbine Engine and Research Combustor Burning a Fischer-Tropsch Jet Fuel.” Energy & Fuels 21: 2615–26.CrossRefGoogle Scholar
Fahey, D. W., Keim, E. R., Boering, K. A., Brock, C. A., Wilson, J. C., Jonsson, H. H., Anthony, S., Hanisco, T. F., Wennberg, P. O., Miake-Lye, R. C., Salawitch, R. J., Lousinard, N., Woodbridge, E. L., Gao, R. S., Donnelly, S. G., Wamsley, R. C., Del Negro, L. A., Solomon, S., Daube, B. C., Wofsy, S. C., Webster, C. R., May, R. D., Kelly, K. K., Loewenstein, M., Podolske, J. R., and Chan, K. R. (1995). “Emission Measurements of the Concorde Supersonic Aircraft in the Lower Stratosphere.” Science 270(5233): 70–4.CrossRefGoogle Scholar
Federal Aviation Administration (FAA) (2009). Office of Environment and Energy, and U.S. Environmental Protection Agency, Office of Transportation and Air Quality. “Recommended Best Practice for Quantifying Speciated Organic Gas Emissions from Aircraft Equipped with Turbofan, Turbojet, and Turboprop Engines.” Version 1.0, May 27. Also Knighton, W. B., Herndon, S. C., and Miake-Lye. R. C. “Aircraft Engine Speciated Organic Gases: Speciation of Unburned Organic Gases in Aircraft Exhaust.” Technical Support Document for Recommended Best Practice Version 1.0.
Jun, M. (2011). “Microphysical Modeling of Ultrafine Hydrocarbon-Containing Aerosols in Aircraft Emissions.” PhD Thesis, Department of Aeronautics and Astronautics, Massachusetts Institute of Technology, May.
Kärcher, B., Peter, T., and Ottmann, R. (1995). “Contrail Formation – Homogeneous Nucleation of H4SO4/ H2O Droplets.” Geophysical Research Letters 22(12): 1501–4.CrossRefGoogle Scholar
Kärcher, B., Turco, R. P., Yu, F., Danilin, M. Y., Weisenstein, D. K., Miake-Lye, R. C., and Busen, R. (2000). “A Unified Model for Ultrafine Aircraft Particle Emissions.” Journal of Geophysical Research (Atmospheres) 105(D24): 29379–86.CrossRefGoogle Scholar
Kärcher, B., and Yu, F. (2009). “Role of Aircraft Soot Emissions in Contrail Formation.” Geophysical Research Letters 36: L01804, doi:.CrossRefGoogle Scholar
Kinsey, J. S., Hays, M. D., Dong, Y., Williams, D. C., and Logan, R. (2011). “Chemical Characterization of the Fine Particle Emissions from Commercial Aircraft Engines during the Aircraft Particle Emissions eXperiment (APEX) 1 to 3.” Environmental Science Technology 45: 3415–21.CrossRefGoogle ScholarPubMed
Knighton, W. B., Rogers, T. M., Anderson, B. E., Herndon, S. C., Yelvington, P. E., and Miake-Lye, R. C. (2007). “Quantification of Aircraft Engine Hydrocarbon Emissions using Proton Transfer Reaction Mass Spectrometry.” Journal of Propulsion and Power 23(5): 949–58.CrossRefGoogle Scholar
Kolb, C. E., Jayne, J. T., Worsnop, D. R., Molina, M. J., Meads, R. F., and Viggiano, A. A. (1994). “Gas-Phase Reaction of Sulfur-Trioxide With Water-Vapor.” Journal of the American Chemical Society 116(22): 10314–15.CrossRefGoogle Scholar
Lee, D. S., Pitari, G., Grewe, V., Gierens, K., Penner, J. E., Petzold, A., Prather, M. J., Schumann, U., Bais, A., Berntsen, T., Iachetti, D., Lim, L. L., and Sausen, R. (2010). “Transport Impacts on Atmosphere and Climate: Aviation.” Atmospheric Environment 44: 4678–734.CrossRefGoogle Scholar
Lister, D. H., and Norman, P. D. (2003). “Aircraft Engine Emissions Certification: A Review of the Development of ICAO Aneex 16, Volume II.” EC-NEPAir: Work Package 1, QinetiQ/FST, CR030440, GRD-CT-2000–00182.
Lukachko, S. P., Waitz, I. A., Miake-Lye, R. C., and Brown, R. C. (2008). “Engine Design and Operational Impacts on Particulate Matter Precursor Emissions.” Journal of Engineering for Gas Turbines and Power 130(2): 021505.CrossRefGoogle Scholar
Miake-Lye, R. C., Brown, R. C., Anderson, M. R., and Kolb, C. E. (1994). “Calculations of Condensation and Chemistry in an Aircraft Contrail,” in Impact of Emissions from Aircraft and Spacecraft upon the Atmosphere, Schumann, U. and Wurzel, D. eds., Proceedings of an International Scientific Colloquium, Cologne, Germany, April 18–20, DLR-Mitteilung 94–06, Deutsches Zentrum für Luft- und Raumfahrt, Oberpfaffenhofen and Cologne, Germany.Google Scholar
Miracolo, M. A., Hennigan, C. J., Ranjan, M., Nguyen, N. T., Gordon, T. D., Lipsky, E. M., Presto, A. A., Donahue, N. M., and Robinson, A. L. (2011). “Secondary Aerosol Formation from Photochemical Aging of Aircraft Exhaust in a Smog Chamber.” Atmospheric Chemistry and Physics 11: 4135–47.CrossRefGoogle Scholar
Ng, N. L., Canagaratna, M. R., Zhang, Q., Jimenez, J. L., Tian, J., Ulbrich, I. M., Kroll, J. H., Docherty, K. S., Chhabra, P. S., Bahreini, R., Murphy, S. M., Seinfeld, J. H., Hildebrandt, L., Donahue, N. M., DeCarlo, P. F., Lanz, V. A., Prevot, A. S. H., Dinar, E., Rudich, Y., and Worsnop, D. R. (2010). “Organic Aerosol Components Observed in Northern Hemispheric Datasets Measured with Aerosol Mass Spectrometry.” Atmospheric Chemistry and Physics 10: 4625–41.CrossRefGoogle Scholar
Oberdörster, G., Oberdörster, E., and Oberdörster, J. (2005). “Nanotoxicology: An Emerging Discipline Evolving from Studies of Ultrafine Particles.” Environmental Health Perspectives 113(7): 823–39.CrossRefGoogle ScholarPubMed
Oluwole, O. O., Barton, P. I., and Green, W. H. (2007). “Obtaining Accurate Solutions Using Reduced Chemical Kinetic Models: A New Model Reduction Method for Models Rigorously Validated over Ranges.” Combustion Theory and Modelling 11: 127–46.CrossRefGoogle Scholar
Onasch, T. B., Jayne, J. T., Herndon, S., Worsnop, D. R., Miake-Lye, R. C., Mortimer, I. P., and Anderson, B. E. (2009). “Chemical Properties of Aircraft Engine Particulate Exhaust Emissions.” Journal of Propulsion and Power 25(5): 1121–37.CrossRefGoogle Scholar
Penner, J. E., Lister, D. H., Griggs, D. J., Dokken, D. J., and McFarland, M. (1999). “Aviation and the Global Atmosphere: A Special Report of the Intergovernmental Panel on Climate Change.” Cambridge University Press.
Presto, A. A., Nguyen, N. T., Ranjan, M., Reeder, A. J., Lipsky, E. M., Hennigan, C. J, Miracolo, M. A., Riemer, D. D., and Robinson, A. L. (2011). “Fine Particle and Organic Vapor Emissions from Staged Tests of an In-use Aircraft Engine.” Atmospheric Environment 45: 3603–12.CrossRefGoogle Scholar
Schumann, U., Arnold, F., Busen, R., Curtius, J., Kärcher, B., Kiendler, A., Petzold, A., Schlager, H., Schroder, F., and Wohlfrom, K. H. (2002). “Influence of Fuel Sulfur on the Composition of Aircraft Exhaust Plumes: The Experiments SULFUR 1–7.” Journal of Geophysical Research (Atmospheres) 107(D15): 4247.CrossRefGoogle Scholar
Spicer, C. W., Holdren, M. W., Riggin, R. M., and Lyon, T. F. (1994). “Chemical Composition and Photochemical Reactivity of Exhaust from Aircraft Turbine Engines.” Annales Geophysicae 12(10–11): 944–55.CrossRefGoogle Scholar
Spicer, C. W., Holdren, M. W., Smith, D. L., Hughes, D. P., and Smith, M. D. (1992). “Chemical Composition of Exhaust from Aircraft Turbine Engines.” Journal of Engineering for Gas Turbines and Power 114(1): 111–17.CrossRefGoogle Scholar
Timko, M. T., Onasch, T. B., Northway, M. J., Jayne, J. T., Canagaratna, M. R., Herndon, S. C., Wood, E. C., Miake-Lye, R. C., and Knighton, W. B. (2010). “Gas Turbine Engine Emissions – Part II: Chemical Properties of Particulate Matter.” Journal of Engineering for Gas Turbines and Power 132: 061505.CrossRefGoogle Scholar
Toon, O. B., and Miake-Lye, R. C. (1998). “Subsonic Aircraft: Contrail and Cloud Effects Special Study.” Geophysical Research Letters, 25(8): 1109–12.CrossRefGoogle Scholar
Tremmel, H. G., and Schumann, U. (1999). “Model Simulations of Fuel Sulfur Conversion Efficiencies in an Aircraft Engine: Dependence on Reaction Rate Constants and Initial Species Mixing Ratios.” Aerospace Science and Technology 7: 417–30.CrossRefGoogle Scholar
Wey, C. C., Anderson, B. E., Hudgins, C., Wey, C. C., Li-Jones, X., Winstead, E., Thornhill, L. K., Lobo, P., Hagen, D., Whitefield, P., Yelvington, P. E., Herndon, S. C., Onasch, T. B., Miake-Lye, R. C., Wormhoudt, J., Knighton, W. B., Howard, R., Bryant, D., Corporan, E., Moses, C., Holve, D., and Dodds, W. (2006). “Aircraft Particle Emissions Experiment (APEX).” Report No. NASA/ TM-2006–214382.
Wey, C. C., Anderson, B. E., Wey, C. C., Miake-Lye, R. C., Whitefield, P., and Howard, R. (2007). “Overview on the Aircraft Particle Emissions Experiment.” Journal of Propulsion and Power 23: 897–905.CrossRefGoogle Scholar
Wong, H.-W., and Miake-Lye, R. C. (2010). “Parametric Studies of Contrail Ice Particle Formation in Jet Regime Using Microphysical Parcel Modeling.” Atmospheric Chemistry and Physics 10: 3261–72.CrossRefGoogle Scholar
Wood, E., Herndon, S., Miake-Lye, R. C., Nelson, D., and Seeley, M. (2008). “Aircraft and Airport-Related Hazardous Air Pollutants: Research Needs and Analysis.” ACRP Project 02–03, ACRP Report 7, ISBN 978–0–309–11745–6, Transportation Research Board, Washington, DC.
Woody, M., Baek, B. H., Adelman, Z., Omary, M., Lam, Y. F., West, J. J., and Arunachalam, S. (2011). “An Assessment of Aviation’s Contribution to Current and Future Fine Particulate Matter in the United States.” Atmospheric Environment 45: 3424–33.CrossRefGoogle Scholar
Yelvington, P. E., Herndon, S. C., Wormhoudt, J. C., Jayne, J. T., Miake-Lye, R. C., Knighton, W. B., and Wey, C. (2007). “Chemical Speciation of Hydrocarbon Emissions from a Commercial Aircraft Engine.” Journal of Propulsion and Power 23: 912–18.CrossRefGoogle Scholar
Zhao, J., and Turco, R. P. (1995). “Nucleation Simulations in the Wake of a Jet Aircraft in Stratospheric Flight.” Journal of Aerosol Science 26(5): 779–95.CrossRefGoogle Scholar

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