Book contents
- Frontmatter
- Contents
- Preface
- Introduction
- 1 Radiometry
- 2 Geometrical Optics
- 3 Maxwell's Equations
- 4 Properties of Electromagnetic Waves
- 5 Propagation and Applications of Polarized Light
- 6 Interference Effects and Their Applications
- 7 Diffraction Effects and Their Applications
- 8 Introduction to the Principles of Quantum Mechanics
- 9 Atomic and Molecular Energy Levels
- 10 Radiative Transfer between Quantum States
- 11 Spectroscopic Techniques for Thermodynamic Measurements
- 12 Optical Gain and Lasers
- 13 Propagation of Laser Beams
- Appendix A
- Appendix B
- Index
10 - Radiative Transfer between Quantum States
Published online by Cambridge University Press: 05 June 2012
- Frontmatter
- Contents
- Preface
- Introduction
- 1 Radiometry
- 2 Geometrical Optics
- 3 Maxwell's Equations
- 4 Properties of Electromagnetic Waves
- 5 Propagation and Applications of Polarized Light
- 6 Interference Effects and Their Applications
- 7 Diffraction Effects and Their Applications
- 8 Introduction to the Principles of Quantum Mechanics
- 9 Atomic and Molecular Energy Levels
- 10 Radiative Transfer between Quantum States
- 11 Spectroscopic Techniques for Thermodynamic Measurements
- 12 Optical Gain and Lasers
- 13 Propagation of Laser Beams
- Appendix A
- Appendix B
- Index
Summary
Introduction
Until now, our discussion of the interaction between radiation and matter has concentrated only on the spectral aspects of radiation. The results could determine the wavelengths for absorption and emission or the selection rules for such transitions, but could not be used to determine the actual extent of emission or absorption. These too are important considerations which are needed to fully quantify radiative energy transfer. Unfortunately, none of the classical theories can predict the extent of emission from an excited medium, or even the extent of absorption. Although the discussion in Section 4.9 (on the propagation of electromagnetic waves through lossy media) touched briefly on the concept of attenuation by absorption, it failed to show the reasons for the spectral properties of the absorption or to accurately predict its extent. We will see later that the classical results are useful only as a benchmark against which the actual absorber is compared. The objective of this chapter is therefore to present an introduction to quantum mechanical processes that control the emission and absorption by microscopic systems consisting of atoms and molecules. The results will then be used to predict the extent of emission by media when excited by an external energy source and to evaluate the absorption of incident radiation.
It is now well recognized that all emission or absorption processes are the result of transitions between quantum mechanical energy levels.
- Type
- Chapter
- Information
- Introduction to Optics and Lasers in Engineering , pp. 293 - 343Publisher: Cambridge University PressPrint publication year: 1996