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Appendix E - Thermodynamics

from Part VIII - Fundaments

Published online by Cambridge University Press:  26 October 2017

David E. Loper
Affiliation:
Florida State University
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Summary

Thermodynamics is concerned with the amounts of energy stored in – and transferred to and from – a thermodynamic system (i.e., a specified portion of the Universe). The behavior of energy is codified in three laws:

  • • The zeroth law defines the concept of temperature. Temperature is an intensive thermodynamic state variable.1

  • • The first law quantifies conservation of energy; it is entirely bookkeeping – keeping track of the types and amounts of energy stored in a system and transferred into or from it.

  • • The second law restricts the possible changes of forms of energy. In a nutshell, changes of energy from organized to disorganized are unconstrained, but transfers of energy from disorganized to organized are severely limited2 and are quantified by the thermodynamic efficiency; see Appendix E.11. An unavoidable consequence of the second law is the degradation of the kinetic energy of a flowing fluid to heat due to the action of viscous forces.

  • A thermodynamic system consists of any clearly defined portion of the universe. A system is assumed to be composed of a vast number3 of massive particles (i.e., particles having a rest mass). These particles may be atoms, electrons, ions, molecules and/or larger aggregations of matter, provided that the system consists of a vast number of them. (It is simplest to think of the particles as atoms.) A system may be categorized as closed or open; transfers of energy and matter into or out of a closed system are not permitted, while these transfers are permitted if the system is open.

    The following fundaments of thermodynamics include:

  • • E.1: a discussion of storage and transfers of energy;

  • • E.2: an introduction to the mole, which is a way to count atoms or molecules;

  • • E.3: an introduction to the first law of thermodynamics;

  • • E.4: a discussion and categorization of thermodynamic potentials, variables and parameters;

  • • E.5: the equations of state for density and entropy, including an alternate form for the first law and the equation of state for sea water;

  • • E.6: an introduction to ideal mixtures;

  • • E.7: development of the energy equation;

  • • E.8: a brief introduction to the thermodynamic behavior of ideal gases;

  • • E.9: a summary of the thermodynamics of the atmosphere;

  • • E.10: a discussion of phase equilibrium; and

  • • E.11: quantification of thermodynamic efficiency.

  • Type
    Chapter
    Information
    Geophysical Waves and Flows
    Theory and Applications in the Atmosphere, Hydrosphere and Geosphere
    , pp. 445 - 476
    Publisher: Cambridge University Press
    Print publication year: 2017

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    • Thermodynamics
    • David E. Loper, Florida State University
    • Book: Geophysical Waves and Flows
    • Online publication: 26 October 2017
    • Chapter DOI: https://doi.org/10.1017/9781316888858.049
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    • Thermodynamics
    • David E. Loper, Florida State University
    • Book: Geophysical Waves and Flows
    • Online publication: 26 October 2017
    • Chapter DOI: https://doi.org/10.1017/9781316888858.049
    Available formats
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    • Thermodynamics
    • David E. Loper, Florida State University
    • Book: Geophysical Waves and Flows
    • Online publication: 26 October 2017
    • Chapter DOI: https://doi.org/10.1017/9781316888858.049
    Available formats
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