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11 - Industrial applications of LIBS

Published online by Cambridge University Press:  08 August 2009

Reinhard Noll
Affiliation:
Fraunhofer-Institut für Lasertechnik (ILT), Germany
Volker Sturm
Affiliation:
Fraunhofer-Institut für Lasertechnik (ILT), Germany
Michael Stepputat
Affiliation:
Fraunhofer-Institut für Lasertechnik (ILT), Germany
Andrew Whitehouse
Affiliation:
Applied Photonics Ltd, Skipton, North Yorkshire, UK
James Young
Affiliation:
Applied Photonics Ltd, Skipton, North Yorkshire, UK
Philip Evans
Affiliation:
Applied Photonics Ltd, Skipton, North Yorkshire, UK
Andrzej W. Miziolek
Affiliation:
U.S. Army Research Laboratory, USA
Vincenzo Palleschi
Affiliation:
Istituto per I Processi Chimico-Fisici, Italy
Israel Schechter
Affiliation:
Technion - Israel Institute of Technology, Haifa
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Summary

Introduction

The availability of compact and reliable laser sources, sensitive optical detectors, and powerful computers has helped to stimulate significant growth in industrial applications of LIBS during the past decade. This, together with a better understanding of the physical processes involved when intense laser radiation interacts with a material, has helped researchers to exploit the LIBS technique for various industrial applications ranging from process control of materials during manufacturing to rapid sorting of scrap materials during recycling and remote characterization of highly radioactive nuclear waste. LIBS is still regarded as an emerging technology and there remain many technological barriers that must be overcome before widespread industrial use becomes a reality.

This chapter aims to provide the reader with a general overview of industrial applications of LIBS and is not meant to provide an exhaustive review of the field. The scope has been restricted to applications of LIBS in an industrial rather than laboratory environment. Accordingly, the various laboratory-based LIBS instruments that are now available from a number of manufacturers are not discussed here. The chapter has been written in four sections relating to the following general areas of industry: (ⅰ) metals and alloys processing, (ⅱ) scrap sorting and recycling, (ⅲ) nuclear power generation and spent fuel reprocessing, and (ⅳ) miscellaneous industrial applications.

Metals and alloys processing

Background

The continuously increasing requirements for productivity and product quality in the metal producing and processing industries initiate the demand for measuring methods having the potential to analyze the chemical composition of the processed materials at high speed and – if possible – on-line.

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Publisher: Cambridge University Press
Print publication year: 2006

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References

Mönch, I., Noll, R., Buchholz, R. and Worringer, J., Laser identifies steel grades, Stainless Steel World, 12(4) (2000), 25–29Google Scholar
Kraushaar, M., R. Noll and H.-U. Schmitz, Multi-elemental analysis of slag from steel production using laser-induced breakdown spectroscopy, in International Meeting on Chemical Engineering, Environmental Protection and Biotechnology, ACHEMA 2000, Laboratory and Analysis Accreditation, Certification and QM (2000), pp. 117–119
Sattmann, R., Sturm, V. and Noll, R., Laser-induced breakdown spectroscopy of steel samples using multiple Q-switch Nd:YAG laser pulses. J. Phys. D: Appl. Phys., 28 (1995), 2181–2187CrossRefGoogle Scholar
Runge, E. F., Bonfiglio, S. and Bryan, F. R., Spectrochemical analysis of molten metal using a pulsed laser source. Spectrochim. Acta, 22 (1966), 1678–1680CrossRefGoogle Scholar
Cremers, D. A., The analysis of metals at a distance using laser-induced breakdown spectroscopy. Appl. Spectrosc., 41 (1987), 572–579CrossRefGoogle Scholar
R. Jowitt, Direct analysis of molten steel, in Proceedings of the 38th Chemists' Conference, Scarborough (June 1985), p. 19
R. Jowitt, Laser analysis of liquid steel, in Proceedings of the International Conference on Progress Analysis in the Chemical Iron and Steel Industry, Luxembourg (May 1991)
Carlhoff, C. and Kirchhoff, S., Direct analysis in steelmaking converters using laser-induced emission spectrometry, in Proceedings of the 3rd International Conference on Progress Analysis in the Chemical Iron and Steel Industry, R. Nauche (editor), ECSC-EEC-EAEC, Brussels, Luxembourg (1992), pp. 150–153
Aragon, C., Aguilera, A. and Campos, J., Determination of carbon content in molten steel using laser-induced breakdown spectroscopy. Appl. Spectrosc., 47 (1993), 606–608CrossRefGoogle Scholar
Moencke-Blankenburg, L., Möglichkeiten und Grenzen der Analytik flüssigen Stahls mittels laserinduzierter Atomemissionsspektrometrie, in CANAS '93 Colloquium Analytische Atomspektroskopie, Klaus Dittrich and Bernhard Walz (editors), Universität Leipzig, Germany (1993), pp. 165–180 (in German)Google Scholar
R. Noll, V. Sturm, L. Peter and I. R. C. Whiteside, Analysis using lasers, in 49th Chemists' Conference, Scarborough (Oct. 14–16, 1997), pp. 22–27
Noll, R., Sattmann, R., Sturm, V., Lüngen, S. and Wachtendonk, H.-J., Schnelle Multielement-Analyse in der Stahlschmelze mit laserinduzierter Emissionsspektrometrie. Stahl und Eisen, 117 (1) (1997), pp. 57–62 (in German)Google Scholar
Cabalín, L. M., Romero, D., Lucena, P., Baena, J. M. and Laserna, J. J.. Laser induced breakdown spectrometry for stainless steel characterization, in Proceedings of the 5th International Conference on Progress Analysis in the Chemical Steel and Metals Industries, European Commission, Luxembourg (1999), p. 336Google Scholar
Gruber, J., Heitz, J., Strasser, H., Bäuerle, D. and Ramaseder, N., Rapid in-situ analysis of liquid steel by laser-induced breakdown spectroscopy. Spectrochim. Acta Part B, 56 (2001), 685–693CrossRefGoogle Scholar
Sturm, V., Peter, L. and Noll, R., Steel analysis with laser-induced breakdown spectrometry in the vacuum ultraviolet. Appl. Spectrosc., 54 (2000), 1275–1278CrossRefGoogle Scholar
Hemmerlin, M., Meilland, R., Falk, H., Wintjens, P. and Paulard, L., Application of vacuum ultraviolet laser-induced breakdown spectrometry for steel analysis. Spectrochim. Acta, Part B, 56 (2001), pp. 661–669CrossRefGoogle Scholar
Sturm, V., Peter, L., Noll, R.et al., Elemental analysis of liquid steel by means of laser technology, in International Meeting on Chemical Engineering, Environmental Protection and Biotechnology, ACHEMA 2000, Materials Technology and Testing (May 2000), pp. 9–11
Ullmann's Encyclopedia of Industrial Chemistry, A20 (VCH Publishers Inc., 1992)
Brite Euram III project, Development of multipurpose industrial units for recycling of plastic wastes by on-line pattern recognition of polymer feature (Sure-Plast), contract number BRPR-CT98-0783
Marshall, J., Carrol, J., Crighton, J. S. and Barnard, C., Industrial analysis: metals, chemicals and advanced materials. J. Anal. Atom. Spectrom., 9 (1994), 319–356CrossRefGoogle Scholar
Grant, K. J., Paul, G. L. and O'Neill, J. A., Quantitative elemental analysis of iron ore by laser-induced breakdown spectroscopy. Appl. Spectrosc., 45 (1991), 701–705CrossRefGoogle Scholar
Zenobi, R., Modern laser mass spectrometry. Fresenius J. Anal. Chem., 348 (1994), 506–509CrossRefGoogle Scholar
Weiss, Z., New method of calibration for glow-discharge optical emission spectrometry, J. Anal. Atom. Spectrom., 9 (1994), 351–354CrossRefGoogle Scholar
Golloch, A. and Siegmung, D., Sliding spark spectroscopy – rapid survey analysis of flame retardants and other additives in polymers. Fresenius J. Anal. Chem., 358 (1997), 804–811CrossRefGoogle Scholar
Gijbels, R., Elemental analysis of high-purity solids by mass spectrometry. Tantala, 37 (4) (1990), 363CrossRefGoogle ScholarPubMed
Sattmann, R., Mönch, I., Krause, H.et al., Laser-induced breakdown spectroscopy for polymer identification. Appl. Spectrosc., 52 (1998), 456CrossRefGoogle Scholar
Anzano, J. M., Gornushkin, I. B., Smith, B. W. and Winefordner, J. D., Laser-induced plasma spectroscopy for plastic identification. Polymer Eng. Sci., 40 (2000), 2423–2429CrossRefGoogle Scholar
Fink, H., Panne, U. and Niessner, R., Analysis of recycled thermoplastics from consumer electronics by laser-induced plasma spectroscopy. Anal. Chim. Acta, 440 (2001), 17–25CrossRefGoogle Scholar
Tran, M., Sun, Q., Smith, B. W. and Winefordner, J. D., Determination of F, Cl, and Br in solid organic compounds by laser-induced plasma spectroscopy. Appl. Spectrosc., 55 (2001), 739–744CrossRefGoogle Scholar
Noll, R., Bette, H., Brysch, A.et al., Laser-induced breakdown spectrometry – applications for production control and quality assurance in the steel industry, Spectrochim. Acta, Part B – Atom. Spectrosc., 56 (2001), 637–649CrossRefGoogle Scholar
LLA Instruments GmbH, Verfahren und Vorrichtung zur Bestimmung der Materialzusammensetzung von Stoffen, patent DE-4341462.1
Uhl, A., Loebe, K. and Kreuchwig, L., Fast analysis of wood preservers using laser breakdown spectroscopy. Spectrochim. Acta, Part B, 56, (2001), 795–806CrossRefGoogle Scholar
Löbe, K., Lucht, H., Handreck, B. and Dörfer, J., On-line Mineralstoffanalyse von Weizenkörnern und -mehlen mittels laserinduzierter Plasmaspektroskopie. Getreide Mehl und Brot., 51 (1997), 131–136Google Scholar
K. Loebe, H. Lucht and A. Uhl, Laser micro analysis of glass and tool steel, LIBS 2002 Technical Digest, Conference on Laser-Induced Plasma Spectroscopy and Applications, Orlando, Florida, September 25–28 (2002), pp. 206–208
Tozer, B. A., Remote measurement of oxide thickness and steel composition using laser techniques. Opt. Las. Technol., (1976), pp. 57–64CrossRefGoogle Scholar
Nyga, R. and Neu, W., Double-pulse technique for optical emission spectroscopy of ablation plasmas of samples in liquids. Opt. Lett., 18 (9) (1993), 747–749CrossRefGoogle ScholarPubMed
Duckworth, A., Remote metal analysis by laser-induced breakdown spectroscopy, British Nuclear Engineering Society (BNES) Conference Proceedings, Remote Techniques for Hazardous Environments (1995), pp. 259–263Google Scholar
Davies, C. M., Telle, H. H., Montgomery, D. J. and Corbett, R. E., Quantitative analysis using remote laser-induced breakdown spectroscopy (LIBS). Spectrochim. Acta, Part B, 50 (1995), 1059–1075CrossRefGoogle Scholar
Theriault, G. A. and Lieberman, S. H., Remote in-situ detection of heavy metal contamination in soils using a Fiber Optic Laser Induced Breakdown Spectroscopy (FOLIBS) System. SPIE, 2504 (1995), 75–83Google Scholar
Cremers, D. A., Barefield, J. E. II and Koskelo, A. C., Remote elemental analysis by laser-induced breakdown spectroscopy using a fibre-optic cable. Appl. Spectrosc., 49 (1995), 857–860CrossRefGoogle Scholar
Ernst, W. E., Farson, D. F. and Sames, D. J., Determination of copper in A533b steel for the assessment of radiation embrittlement using laser-induced breakdown spectroscopy. Appl. Spectrosc., 50 (1996), 306–309CrossRefGoogle Scholar
Young, J., Botheroyd, I. M. and Whitehouse, A. I., Remote analysis of nuclear and non-nuclear materials using laser-induced breakdown spectroscopy, in Conference on Electro-optics and Lasers (CLEO/Europe), Hamburg, Germany (1996), p. 152Google Scholar
Saggese, S. and Greenwell, R., LIBS fiber optic sensor for subsurface heavy metals detection. SPIE, 2836 (1996), 195–205Google Scholar
Theriault, G. A. and Lieberman, S. H., Field deployment of a LIBS probe for rapid delineation of metals in soils. SPIE, 2835 (1996), 83–88Google Scholar
Marquardt, B. J., Goode, S. R. and Angel, S. M., In-situ determination of lead in paint by laser-induced breakdown spectroscopy using a fibre-optic probe. Anal. Chem., 68 (1996), 977–981CrossRefGoogle Scholar
Davies, C. M., Telle, H. H. and Williams, A. W., Remote in situ analytical spectroscopy and its applications in the nuclear industry. J. Anal. Chem., 355 (1996), 895–899Google ScholarPubMed
Young, J., Botheroyd, I. M. and Whitehouse, A. I., Trace element analysis of uranium metal fuel using laser-induced breakdown spectroscopy, in Conference on Electro-optics and Lasers (CLEO/Europe), Glasgow, UK (1998), p. 201Google Scholar
Botheroyd, I. M., Young, J., Whitehouse, A. I. and Duckworth, A., Remote analysis of steels and other solid materials using laser-induced breakdown spectroscopy (LIBS), in Conference on Lasers and Electro-optics-Europe (CLEO/Europe), Glasgow, UK (1998), p. 198Google Scholar
Marquardt, B. J., Stratis, D. N., Cremers, D. A. and Angel, S. M., Novel probe for laser-induced breakdown spectroscopy and Raman measurements using an imaging optical fibre. Appl. Spectrosc., 52 (9) (1998), 1148–1153CrossRefGoogle Scholar
Theriault, G. A., Bodensteiner, S. and Lieberman, S. H., A real-time fibre-optic LIBS probe for the in situ delineation of metals in soils. Field Anal. Chem. Technol., 2 (2) (1998), 117–1253.0.CO;2-T>CrossRefGoogle Scholar
Neuhauser, R. E., Panne, U. and Niessner, R., Laser-induced plasma spectroscopy: a versatile tool for monitoring heavy metal aerosols. Anal. Chem. Acta, 392 (1999), pp. 47–54CrossRefGoogle Scholar
Stratis, D. N., Eland, K. L. and Angel, S. M., Characterisation of laser-induced plasmas for fiber optic probes. Proc. SPIE, 3534 (1999), 592–600CrossRefGoogle Scholar
Eland, K. L., Stratis, D. N., Carter, J. C. and Angel, S. M., Development of a dual-pulse fiber optic probe for in-situ elemental analyses. Proc. SPIE, 3853 (1999), pp. 288–294CrossRef
Neuhauser, R. E., Panne, U. and Niessner, R., Utilization of fibre optics for remote sensing by laser-induced plasma spectroscopy (LIPS). Appl. Spectrosc., 54 (6) (2000), p. 923CrossRefGoogle Scholar
Mosier-Boss, P. A. and Lieberman, S. H., Direct push fiber-optic laser induced breakdown spectroscopy (FO-LIBS) sensor probe for real-time, in-situ measurements of metals in soils. National Meeting (Chicago, Aug. 26–30, 2001) – American Chemical Society, Division of Environmental Chemistry, 41 (No. 2, Part 3) (2001), 603–609Google Scholar
Whitehouse, A. I., Young, J., Botheroyd, I. M.et al., Remote material analysis of nuclear power station steam generator tubes by laser-induced breakdown spectroscopy. Spectrochim. Acta, Part B, 56 (2001), 821–830CrossRefGoogle Scholar
Poulson, B., Complexities in predicting erosion-corrosion. Proc. Of Wear – Lausanne, 233–235 (1999), pp. 497–504CrossRef
Applied Photonics Ltd, Laser spectroscopic remote detection of surface contamination, International Patent Application No. PCT/GB01/00866
Cristoforetti, G.et al., In-situ LIBS analysis of steel pipes at high temperature, LIBS 2002 Technical Digest, Conference on Laser Induced Plasma Spectroscopy and Applications, Orlando, Florida, September 25–28 (2002), pp. 172–174

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